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Experimental Investigation and Thermodynamic Calculation of Phase Equilibria in the Mg-Pb-Sn Ternary System

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Abstract

The phase equilibria of the Mg-Pb-Sn ternary system were investigated using a combined method of electron probe microanalyzer and x-ray diffraction. Three isothermal sections of the Mg-Pb-Sn ternary system at 200, 300 and 400 °C were experimentally established. The phase equilibria of Mg-Pb-Sn ternary system were thermodynamically assessed by using CALPHAD (Calculation of Phase Diagrams) method on the basis of the presently determined experimental data. A consistent set of thermodynamic parameters has been derived for describing the Gibbs free energies of each solution phase and intermetallic compound in the Mg-Pb-Sn ternary system. The calculated phase diagrams and thermodynamic properties in the Mg-Pb-Sn ternary system are in good agreement with experimental data.

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Acknowledgments

This work was financially supported by the Science and Technology Bureau of Xiamen City (Project No. 3502Z20131153). This work was supported by the National Natural Science Foundation of China (Grant No. 51171159) and the Ministry of Education of China (Grant No. 20120121130004). The support from the Ministry of Science and Technology of China (Grant No. 2012CB825700 and 2014DFA53040) is also acknowledged.

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Authors and Affiliations

  1. Department of Materials Science and Engineering, Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen, 518055, People’s Republic of China

    Dong Wang, Hongtao Chen, Xingjun Liu & Cuiping Wang

  2. Department of Materials Science and Engineering, College of Materials, Xiamen University, Xiamen, 361005, People’s Republic of China

    Dong Wang

  3. Research Center, Shenzhen Zhenhua Fu Electronics Co., Ltd, Shenzhen, 518109, People’s Republic of China

    Dong Wang, Jianhua Zhu & Shangheng Wang

  4. Research Center of Materials Design and Applications, Xiamen University, Xiamen, 361005, People’s Republic of China

    Xingjun Liu & Cuiping Wang

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  1. Dong Wang
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Correspondence to Dong Wang.

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Wang, D., Zhu, J., Wang, S. et al. Experimental Investigation and Thermodynamic Calculation of Phase Equilibria in the Mg-Pb-Sn Ternary System. J. Phase Equilib. Diffus. 39, 324–343 (2018). https://doi.org/10.1007/s11669-018-0633-4

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  • DOI: https://doi.org/10.1007/s11669-018-0633-4

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