Skip to main content
Log in

The Phase Equilibria of the 75 at.% Al-Zn-Ce-Fe Quaternary System at 600 °C

  • Published:
Journal of Phase Equilibria and Diffusion Aims and scope Submit manuscript

Abstract

The 600 °C isothermal section of the Al-Zn-Ce-Fe quaternary system with Al being fixed at 75 at.% has been studied experimentally by means of scanning electron microscopy coupled with energy dispersive x-ray spectroscopy and x-ray powder diffraction. Four four-phase regions have been identified in this section, namely, τ2+Liq.+α-Al+FeAl3, τ2+Ψ+α-Al+FeAl3, τ2+Ψ+α-Al+αAl11Ce3, τ2+Ψ+αAl11Ce3+αAl3Ce. One Al-Ce-Fe ternary phase Ψ (CeFe2Al10) and another Al-Zn-Ce ternary phase τ2 (Al2Zn2Ce) has been found in this section but no quaternary compound has been found.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig.1
Fig.2
Fig.3
Fig.4
Fig.5

Similar content being viewed by others

References

  1. A.R. Marder, The Metallurgy of Zinc-Coated Steel[J], Prog. Mater. Sci., 2000, 45(3), p 191-271

    Article  Google Scholar 

  2. Galvalume Coated Steel Sheet. Galvalume is a Trademark of BIEC, International, Inc. Rev 2.1, Aug-03

  3. R.P. Edavan and R. Kopinski, Corrosion Resistance of Painted Zinc Alloy Coated Steels[J], Corros. Sci., 2009, 51(10), p 2429-2442

    Article  Google Scholar 

  4. H.E. Towsend, L. Allegra, and R.J. Dutton, Hot-Dip Coated Sheet Steel-A Review, Mater. Perform., 1986, 25(8), p 36-46

    Google Scholar 

  5. K.L. Meissner, Some Examples of the Practical Use of the Clear-Cross Method[J], Metall und Erz, 1925, 22, p 243-247

    Google Scholar 

  6. O.S. Zarechnyuk, M.G. Mys’kiv and V.R. Ryabov, X-ray Diffraction Study of the Phase Composition of Ce-Fe-Al Alloys Containing up to 33.3 at.% Ce[J]. Translated from Izv. Akad. Nauk SSSR, Met, 1969, 2, p 164-166

  7. D.F. Franceschini and S.F. da Cunha, Magnetic Properties of Ce(Fe1−xAlx)2 for x ≤ 0.20[J], Magn. Magn. Mater., 1985, 51, p 280-290

    Article  ADS  Google Scholar 

  8. E.I. Gladyshevskii, P.I. Kripyakevich, M.Y. Teslyuk et al., Crystal Structures of Some Intermetallic Compounds[J], Sov. Phys.-Crystallogr., 1961, 6, p 207-208

    Google Scholar 

  9. O.S. Zarechnyuk, The Crystal Structure of Ternary Compounds in the System Ce-Transition Metal-Al, Kristallografiya, 1962, 7, p 543-554, in Russian

    Google Scholar 

  10. O.I. Vivchar and O.S. Zarechnyuk, Compounds with the ThMn12 Type Structure in R-Fe-Al Systems, Tezisy Dokl. Vses. Konf. Kristallokhim., “Intermetalicheskie Soedineniya”, ed. by R.M. Rykhal, 2nd, p 41, 1974, in Russian

  11. K.H.J. Buschow, J.H.N. van Vucht, and W.W. van den Hoogenhof, Note on the Crystal Structure of the Ternary Rare-Earth-3d Transition Metal Compounds of the Type RT4Al8, J. Less-Common Met., 1976, 50, p 145-150

    Article  Google Scholar 

  12. V.M.T. Thiede, T. Ebel, and W. Jeitschko, Ternary Aluminides LnT2Al10 (Ln=Y, La-Nd, Sm, Cd-Lu and T=Fe, Ru, Os) with YbFe2Al10 Type Structure and Magnetic Properties of the Iron-Coating Series, J. Mater. Chem., 1998, 8(1), p 125-130

    Article  Google Scholar 

  13. W. Koster and T. Godecke, Iron-Aluminium-Zinc Ternary System[J], Z. für Metallkunde, 1970, 61(9), p 649-658

    Google Scholar 

  14. P. Perrot, J.C. Tissier, and J.Y. Dauphin, Stable and Metastable Equilibria in the Fe-Zn-Al System at 450 °C[J], Z. für Metallkunde, 1992, 83(11), p 786-790

    Google Scholar 

  15. N.Y. Tang and X.P. Su, On the Ternary Phase in the Zinc Rich Corner of the Zn-Al-Fe System at Temperatures Below 450 °C, Metall. Mater. Trans. A, 2002, 33A(5), p 1559-1561

    Article  Google Scholar 

  16. J. Nakano, D.V. Malakhov, S. Yamaguchi, and G.R. Purdy, A Full Thermodynamic Optimization of the Zn-Fe-Al System Within the 420-500 °C Temperature Range[J], CALPHAD, 2007, 31, p 125-140

    Article  Google Scholar 

  17. O.N.C. Uwakweh and Z. Liu, Kinetics and Phase Transformation Evaluation of Fe-Zn-Al Mechanically Alloyed Phases[J], Metall. Mater. Trans. A, 1997, 28A(3), p 517-525

    Article  Google Scholar 

  18. E.H. Rennhack, Zinc-Rich Corner of the Zn-Fe-Al System[J], Trans. Metall. Soc. AIME, 1961, 221(4), p 775-779

    Google Scholar 

  19. Q. Luo, J.L. Chen, Y. Li, F. Yang, Q. Li, Y. Wu, J.Y. Zhang, and K.C. Chou, Experimental Study and Thermodynamic Assessment of the Al-Fe Rich Side of the Al-Zn-Fe System at 300 and 550 °C[J], CALPHAD, 2012, 37, p 116-125

    Article  Google Scholar 

  20. C.P. Wang, X. Chen, X.J. Liu and F.S. Pan, Thermodynamic Assessment of the Zn-Ce and Al-Zn-Ce Systems[C]. Proceeding of the 13th National Symposium on Phase Diagram. p 128-185, 2006

  21. A.Z. Ikromov, I.N. Ganiev, A.V. Vakhobov, and V.V. Kinzhibalo, Phase Equilibria in the Al-Zn-Ce System at 593K[J], Russ. Metall., 1991, 2, p 219-221

    Google Scholar 

  22. A. Griger, V. Syefaniay, and T. Turmezey, Crystallographic Data and Chemical Compositions of Aluminum-Rich Al-Fe Intermetallic Phases, Z. Metallkd., 1986, 77, p 30-35

    Google Scholar 

  23. H. Okamoto, Al-Ce (Aluminum-Cerium)[J], J. Phase Equilib. Diffus., 2011, 32(4), p 392-393

    Article  Google Scholar 

Download references

Acknowledgments

This investigation is supported by the National Science Foundation of the China (No. 51471140), the Ph.D. Programs Foundation of Ministry of Education of China (No. 20124301110006) and Scientific Research Found of Hunan Provincial Education Department (No. 14A143).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zhi Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Ji, L., Li, Z., Wu, Y. et al. The Phase Equilibria of the 75 at.% Al-Zn-Ce-Fe Quaternary System at 600 °C. J. Phase Equilib. Diffus. 36, 92–98 (2015). https://doi.org/10.1007/s11669-015-0363-9

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11669-015-0363-9

Keywords

Navigation