Abstract
In this study, Al2O3, Cr2O3, and Al2O3-Cr2O3 coatings were fabricated by plasma spraying. X-ray diffraction was employed to determine the phase composition of powders and coatings. The morphologies and microstructures of the coatings were characterized using electron probe microanalyzer and transmission electron microscopy. Vickers hardness, fracture toughness, and bending strength of the coatings were measured. Al2O3-Cr2O3 composite coatings show better comprehensive mechanical properties than the individual Al2O3 and Cr2O3 coatings, which are attributed to the former's larger intersplat adhesion or interlamellar cohesion and lower porosity. Solid solution strengthens the phase interfaces and grain boundaries, which is beneficial to improve the mechanical performance of the composite coatings.
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D. Zois, A. Lekatou, M. Vardavoulias, and A. Vazdirvanidis, Nanostructured Alumina Coatings Manufactured by Air Plasma Spraying: Correlation of Properties with the Raw Powder Microstructure, J. Alloy. Compd., 2010, 495(2), p 611-616
Ch.I. Sarafoglou, D.I. Pantelis, S. Beauvais, and M. Jeandin, Study of Al2O3 Coatings on AISI, 316 Stainless Steel Obtained by Controlled Atmosphere Plasma Spraying (CAPS), Surf. Coat. Technol., 2007, 202(1), p 155-161
K. Maiti and A. Sil, Relationship Between Fracture Toughness Characteristics and Morphology of Sintered Al2O3 Ceramics, Ceram. Int., 2010, 36(8), p 2337-2344
Z. Yin, S. Tao, X. Zhou, and C. Ding, Particle In-Flight Behavior and its Influence on the Microstructure and Mechanical Properties of Plasma-Sprayed Al2O3 Coatings, J. Eur. Ceram. Soc., 2008, 28(6), p 1143-1148
N.N. Ault, Characteristics of Refractory Oxide Coatings Produced by Flame-Spraying, J. Am. Ceram. Soc., 1957, 40(3), p 69-74
R. McPherson, Formation of Metastable Phases in Flame-Prepared and Plasma-Prepared Alumina, J. Mater. Sci., 1973, 8(6), p 851-858
R. McPherson, A Review of Microstructure and Properties of Plasma Sprayed Ceramic Coatings, Surf. Coat. Technol., 1989, 39(1-3), p 173-181
E. Celik, A.S. Demirkiran, and E. Avci, Effect of Grit Blasting of Substrate on the Corrosion Behaviour of Plasma-Sprayed Al2O3 Coatings, Surf. Coat. Technol., 1999, 116-119, p 1061-1064
D. Yan, J. He, J. Wu, W. Qiu, and J. Ma, The Corrosion Behaviour of a Plasma Spraying Al2O3 Ceramic Coating in Dilute HC1 Solution, Surf. Coat. Technol., 1997, 89(1-2), p 191-195
G.N. Heintze and S. Uematsu, Preparation and Structures of Plasma-Sprayed γ- and α-Al2O3 Coatings, Surf. Coat. Technol., 1992, 50(3), p 213-222
R. Krishnan, S. Dash, R. Kesavamoorthy, C. Babu Rao, A.K. Tyagi, and B. Raj, Laser Surface Modification and Characterization of Air Plasma Sprayed Alumina Coatings, Surf. Coat. Technol., 2006, 200(8), p 2791-2799
S. Liscano, L. Gil, and M.H. Staia, Effect of Sealing Treatment on the Corrosion Resistance of Thermal-Sprayed Ceramic Coatings, Surf. Coat. Technol., 2004, 188-189, p 135-139
P.K. Chu, Applications of Plasma-Based Technology to Microelectronics and Biomedical Engineering, Surf. Coat. Technol., 2009, 203(17-18), p 2793-2798
H. Ageorges and P. Ctibor, Comparison of the Structure and Wear Resistance of Al2O3-13wt.%TiO2 Coatings Made by GSP and WSP Plasma Process with Two Different Powders, Surf. Coat. Technol., 2008, 202(18), p 4362-4368
W. Tian, Y. Wang, Y. Yang, and C. Li, Toughening and Strengthening Mechanism of Plasma Sprayed Nanostructured Al2O3-13wt.%TiO2 Coatings, Surf. Coat. Technol., 2009, 204(5), p 642-649
R. Venkataraman and R. Krishnamurthy, Evaluation of Fracture Toughness of as Plasma Sprayed Alumina-13wt.% Titania Coatings by Micro-Indentation Techniques, J. Eur. Ceram. Soc., 2006, 26(15), p 3075-3081
P. Chraska, J. Dubsky, K. Neufuss, and J. Pisacka, Alumina-Base Plasma-Sprayed Materials Part I: Phase Stability of Alumina and Alumina-Chromia, J. Therm. Spray Technol., 1997, 6(3), p 320-326
B.R. Marple, J. Voyer, and P. Béchard, Sol Infiltration and Heat Treatment of Alumina-Chromia Plasma-Sprayed Coatings, J. Eur. Ceram. Soc., 2001, 21(7), p 861-868
C.C. Stahr, S. Saaro, L.-M. Berger, J. Dubský, K. Neufuss, and M. Herrmann, Dependence of the Stabilization of Alpha-Alumina on the Spray Process, J. Therm. Spray Technol., 2007, 16(5-6), p 822-830
P. Fauchais, M. Fukumoto, A. Vardelle, and M. Vardelle, Knowledge Concerning Splat Formation: An Invited Review, J. Therm. Spray Technol., 2004, 13(3), p 337-360
J.J. Kruzic and R.O. Ritchie, Determining the Toughness of Ceramics from Vickers Indentations Using the Crack-Opening Displacements: An Experimental Study, J. Am. Ceram. Soc., 2003, 86(8), p 1433-1436
G. Bolelli, V. Cannillo, L. Lusvarghi, and T. Manfredini, Wear Behaviour of Thermally Sprayed Ceramic Oxide Coatings, Wear, 2006, 261(11-12), p 1298-1315
R. Dhiman, A.G. McDonald, and S. Chandra, Predicting Splat Morphology in a Thermal Spray Process, Surf. Coat. Technol., 2007, 201(18), p 7789-7801
S. Widjaja, A.M. Limarga, and T.H. Yip, Modeling of Residual Stresses in a Plasma-Sprayed Zirconia/Alumina Functionally Graded-Thermal Barrier Coating, Thin Solid Films, 2003, 434(1-2), p 216-227
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The study is jointly supported by 2011 Innovation Fund of SICCAS (Y25ZC6160G), China Postdoctoral Science Foundation (20100480039), Shanghai Postdoctoral Science Foundation (11R21416800), and Chinese Academy of Sciences K.C.Wong Post-doctoral Fellowships.
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Yang, K., Feng, J., Zhou, X. et al. Microstructural Characterization and Strengthening-Toughening Mechanism of Plasma-Sprayed Al2O3-Cr2O3 Composite Coatings. J Therm Spray Tech 21, 1011–1024 (2012). https://doi.org/10.1007/s11666-012-9796-4
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DOI: https://doi.org/10.1007/s11666-012-9796-4