Abstract
Nanostructured WC-Co coating was deposited by cold spraying using a nanostructured WC-12Co powder. The critical velocity for the particle to deposit was measured. The coating microstructure was characterized by X-ray diffraction analysis, scanning electron microscopy, and transmission electron microscopy. The coating hardness was tested using a Vickers hardness tester. The deposition behavior of single WC-Co particle was examined. WC particle size was measured for comparison of deposit properties to that of sintered bulk. The result shows that the nanostructured WC-Co coating can be successfully deposited by cold spraying using nanostructured powders. The coating exhibited a dense microstructure with full retention of the original nanostructure in the powder to the coating. The test of microhardness of the coating yielded a value of over 1820 Hv0.3, which is comparable to that of sintered nanostructured WC-Co. The deposition behavior of WC-Co powders as superhard cermet materials in cold spraying and powder structure effects is discussed.
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References
C.-J. Li, A. Ohmori, Y. Harada 1996 Effect of Powder Structure on the Structure of Thermally Sprayed WC-Co Coatings. J. Mater. Sci. 31, 785–794
H. Lovelock 1998 Powder/Processing/Structure Relationships in WC-Co Thermal Spray Coatings: A Review of the Published Literature. J. Thermal Spray Technol., 7, 357–373
D.A. Stewart, P.H. Shipway, D.G. McCartney 1999 Abrasive Wear Behavior of Conventional and Nanocomposite HVOF-Sprayed WC-Co Coatings. Wear, 229, 789–798
M. E. Vinayo, F. Kassabji, J. Guyonnet, P. Fauchais, 1985 Plasam Sprayed WC-Co Coatings: Influence of Spray Conditions (Atmospheric and Low Pressure Plasma Spraying) on the Crystal Structure, Porosity, and Hardness. J. Vac. Sci. Technol. A, 3, 2483–2489
J. Subrahmanyam, M.P. Srivastava, R. Sivakumar, 1986 Characterization of Plasma-Sprayed WC-Co Coatings. Mater. Sci. Eng., 84, 209–214
S. Rangaswamy and H. Herman, Metallurgical Characterization of Plasma Sprayed WC-Co Coatings, Advances in Thermal Spraying (Proceedings of 11th International Thermal Spray Conference), September 8-12, 1986 (Montreal, Canada), Welding Institute of Canada, Pergamon Press Canada Ltd., 1986, p 101-110
A. Tronche, P. Fauchais 1987 Hard Coatings (Cr2O3, WC-Co) Properties on Aluminium or Steel Substrates. Mater. Sci. Eng., 92, 133–144
V. Ramnnath, N. Jayaraman 1989 Characterization and Wear Performance of Plasma Sprayed WC-Co Coatings. Mater. Sci. Technol., 5, 382–388
G. Barbezat, E. Muller, B. Walser 1988 Applying Tungsten Carbide Cobalt Coatings by High Velocity Combustion Spraying. Sulzer Tech. Rev., 4, 27–33
H. Kreye, D. Fandrich, H.-H. Muller, and G. Reiners, Microstructure and Bond Strength of WC-Co Coatings Deposited by Hypersonic Flame Spraying (Jet-Kote Process), Advances in Thermal Spraying (Proceedings of 11th International Thermal Spray Conference), September 8-12, 1986 (Montreal, Canada), Welding Institute of Canada, Pergamon Press Canada Ltd., 1986, p 121-128
H. Nakahira, Y. Harada, and K. Tani, Properties of Tungsten Cermet Coatings by High Energy Flame Spraying, Proceedings of International Symposium on Advanced Thermal Spray Technology and Allied Coatings, A. Ohmori, Ed., May 13-15, 1988 (Osaka, Japan), Japan High Temperature Society, 1988, p 79-88
C.-J. Li, A. Ohmori, Y. Harada 1996 Formation of an Amorphous Phase in Thermally Sprayed WC-Co. J. Thermal Spray Technol., 5(1), 69–73
Y. Ishikawa, J. Kawakita, S. Osawa, T. Itsukaichi, Y. Sakamoto, M. Takaya, S. Kuroda 2005 Evaluation of Corrosion and Wear Resistance of Hard Cermet Coatings Sprayed by Using an Improved HVOF Process. J. Thermal Spray Technol., 14(3), 384–395
C.-J. Li, Y.-Y. Wang, G.-J. Yang, A. Ohmori, K. A. Khor 2004 Effect of Solid Carbide Particle Size on Deposition Behavior, Microstructure and Wear Performance of HVOF Cermet Coatings. Mater. Sci. Technol., 20, 1087–1096
V. Richter, M.V. Ruthendorf 1999 On Hardness and Toughness of Ultrafine and Nanocrystalline Hard Materials. Int. J. Refractory Met. Hard Mater., 17, 141–152
K. Jia, T.E. Fischer 1996 Abrasion Resistance of Nanostructured and Conventional Cemented Carbides. Wear, 200, 206–214
J.H. He, M. Ice, S. Dallek, E.J. Lavernia 2000 Synthesis of Nanostructured WC-12 pct Co Coating Using Mechanical Milling and High-Velocity Oxygen Fuel Thermal Spraying. Metall. Mater. Trans. A, 31, 541–553
D.A. Steward, P.H. Shipway, D.G. McCartney 2000 Microstructural Evolution in Thermally Sprayed WC-Co Coatings: Comparison Between Nanocomposite and Conventional Starting Powders. ACTA Mater., 48, 1593–1604
Y.F. Qiao, Y.R. Liu, and T.E. Fischer (USA), Sliding and Abrasive Wear Resistance of Thermal-Sprayed WC-CO Coatings, J. Thermal Spray Technol., 2001, 10, p 118-125
J.H. He, L. Ajdelsztajn, E.J. Lavernia 2001 Thermal Stability of Nanocrystalline WC-Co Powder Synthesized by Using Mechanical Milling at Low Temperature. J. Mater. Res., 16, 478–488
J.H. He, Y.R. Liu, Y.F. Qiao, T.E. Fischer, E.J. Lavernia 2002 Near-Nanostructured WC-18 pct Co Coatings with Low Amounts of Non-WC Carbide Phase. Part I. Synthesis and Characterization. Metall. Mater. Trans. A, 33, 145–157
Z.G. Ban, L.L. Shaw 2002 Synthesis and Processing of Nanostructured WC-Co Materials. J. Mater. Sci., 37, 3397–3403
Z.G. Ban, L.L. Shaw 2003 Characterization of Thermal Sprayed Nanostructured WC-Co Coatings Derived from Nanocrystalline WC-18 wt.%Co Powders. J. Thermal Spray Technol., 12, 112–119
Y-.Y. Wang, C.-J. Li, J. Ma, G.-J. Yang 2004 Effect of Flame Conditions on the Abrasive Wear Performance of HVOF Sprayed Nanostructured WC-12Co Coatings. Trans. Nonferrous Met. Soc. China, 14(special 2), 72–76
J.H. He, J.M. Schoenung 2004 Nanostructured Coatings. Mater. Sci. Eng. A, 336, 274–319
P.H. Shipway, D.G. McCartney, T. Sudaprasert 2005 Sliding Wear Behaviour of Conventional and Nanostructured HVOF Sprayed WC-Co Coatings. Wear, 259, 820–827
J.M Guilemany, S. Dosta, J. Nin, J.R. Miguel 2005 Study of the Properties of WC-Co Nanostructured Coatings Sprayed by High-Velocity Oxyfuel. J Thermal Spray Technol., 14(3), 405–413
C. Bartuli, T. Valente, F. Cipri, E. Bemporad, M. Tului 2005 Parametric Study of an HVOF Process for the Deposition of Nanostructured WC-Co Coatings. J. Thermal Spray Technol., 14(2), 187–195
B.R. Marple, R. S. Lima 2005 Process Temperature/Velocity-Hardness-Wear Relationship for High-Velocity Oxyfuel Sprayed Nanostructured and Conventional Cermet Coatings. J. Thermal Spray Technol., 14(1), 67–76
J. O. Berghaus, B. Marple, C. Moreau 2006 Suspension Plasma Spraying of Nanostructured WC-12Co Coatings. J. Thermal Spray Technol., 15(4), 676–681
Y.-C. Zhu, K. Yukimura, C.-X. Ding, and P.-Y. Zhang, Tribological Properties of Nanostructured and Conventional WC-Co Coatings Deposited by Plasma Spraying, Thin Solid Films, 2001, 388, p 277-282
G. Skandan, R. Yao, R. Sadangi, B.H. Kear, Y. Qiao, L. Liu, T.E. Fischer 2000 Multimodal Coatings: A New Concept in Thermal Spraying. J. Thermal Spray Technol., 9(3), 329–331
D.A. Ateward, H.P. Shipway, D.C. McCartney 1999 Abrasive Wear Behaviour of Conventional And Nanocomposite HVOF-Sprayed WC-Co Coatings. Wear, 225-229, 789-798
C.-J. Li, A. Ohmori 2002 Relationship Between the Structure and Properties of Thermally Sprayed Deposits. J. Thermal Spray Technol., 11, 365–374
C.-J. Li, W.-Y. Li, W.-H. Ma, and H. Fukanuma, Characterization of Microstructure of Nanostructured Fe–Si Coating Deposited by Cold Spraying, Thermal Spray 2004: Advances in Technology and Application, May 10-12, 2004 (Osaka, Japan), DVS, 2004, p 371–377
H.-T. Wang, C.-J. Li, G.-J. Yang, and C.-X. Li, Formation of Fe–Al Intermetallic Compound Coating Through Cold Spraying, Building on 100 Years of Success: Proceedings of the 2006 International Thermal Spray Conference, B.R. Marple, M.M. Hyland, Y.C. Lau, R.S. Lima, and J. Voyer, Eds., May 15-18, 2006 (Seattle, WA, USA), ASM International, 2006
H.-T. Wang, C.-J. Li, G.-J. Yang, C.-X. Li, and Q. Zhang, Microstructural Characterization of Cold-sprayed FeAl Intermetallic Compound Coatings, J. Thermal Spray Technol., 2007, in this issue
Q. Zhang, C.-J. Li, C.-X. Li, G.-J. Yang, and X.-R. Wang, Preliminary Study of Oxidation Behavior of Cold Sprayed Nanostructure NiCrAlY Bond Coatings, Global Coating Solutions: Proceedings of the 2007 International Thermal Spray Conference, B.R. Marple, M.M. Hyland, Y.-C. Lau, C.-J. Li, R.S. Lima, and G. Montavon, Eds., May 14-16, 2007 (Beijing, China), ASM International, 2007
L. Ajdelsztajn, A.Zuniga, B. Jodoin, E.J. Lavernia 2006 Cold-Spray Processing of a Nanocrystalline Al-Cu-Mg-Fe-Ni Alloy with Sc. J. Thermal Spray Technol., 15, 184–190
R.S. Lima, J. Karthikeyan, C.M. Kay, J. Lindemann, C.C. Berndt 2002 Microstructural Characteristics of Cold-sprayed Nanostructured WC-Co Coating. Thin Solid Films, 416, 129–135
H.-J. Kim, C.-H. Lee, S.-Y. Hwang 2005 Superhard Nano WC-12%Co Coating by Cold Spray Deposition. Mater. Sci. Eng. A, 391, 243–248
H.-J. Kim, C.-H. Lee, S.-Y. Hwang 2005 Fabrication of WC-Co Coatings by Cold Spray Deposition. Surf. Coat. Technol., 191, 335–340
C.-J. Li, W.-Y. Li 2003 Deposition Characteristics of Titanium Coating in Cold Spraying. Surf. Coat. Technol., 167, 278–283
C.-J. Li, W.-Y. Li, H.-L. Liao 2006 Examination of the Critical Velocity for Deposition of Particles in Cold Spraying. J. Thermal Spray Technol., 15, 212–222
C.-J. Li, W.-Y. Li, Y.-Y. Wang, G.-J. Yang, H. Fukanuma 2005 A Theoretical Model for Prediction of Deposition Efficiency in Cold Spraying. Thin Solid Films, 489, 79–85
C.-J. Li, W.-Y. Li 2004 Optimization of Spray Conditions in Cold Spraying based on the Numerical Analysis of Particle Velocity. Trans. Nonferrous Met. Soc. China, 14(special 2), 43–48
S.-Q. Fan, G.-J. Yang, G.-J. Liu, C.-X. Li, C.-J. Li, L.-Z. Zhang, 2006 Characterization of Microstructure of TiO2 Coating Deposited by Vacuum Cold Spraying. J. Thermal Spray Technol., 15(4), 613–517
J. He, J. M. Schoenung 2002 A Review on Nanostructured WC-Co Coatings. Surf. Coat. Technol., 157, 72–79
Y. Qiao, T. E. Fischer, A. Dent 2003 The effects of Fuel Chemistry and Feedstock Powder Structure on the Mechanical and Tribological Properties of HVOF Thermal-Sprayed WC-Co Coatings with Very Fine Structure. Surf. Coat. Technol., 172, 24–41
D.A. Atewart, P.H. Shipway, D.G. McCartney 1998 Influence of Heat Treatment on the Abrasive Wear Behavior of HVOF Sprayed WC-Co Coatings. Surf. Coat. Technol., 105, 13–24
Acknowledgment
This work is supported by the National Natural Science Foundation of China (NSFC) (No. 50171052; No.50571080).
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This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.
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Li, CJ., Yang, GJ., Gao, PH. et al. Characterization of Nanostructured WC-Co Deposited by Cold Spraying. J Therm Spray Tech 16, 1011–1020 (2007). https://doi.org/10.1007/s11666-007-9096-6
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DOI: https://doi.org/10.1007/s11666-007-9096-6