Skip to main content
Log in

Influence of Aging Treatment on the Microstructure and Properties of a Deformation-Processed Cu-Ni-Co-Si Alloy

  • Technical Article
  • Published:
Journal of Materials Engineering and Performance Aims and scope Submit manuscript

Abstract

We investigated the influence of aging on the microstructure and properties of a deformation-processed Cu-Ni-Co-Si alloy. Aging caused recovery and recrystallization in the Cu matrix and the precipitation of Ni2Si, Cu15Si4 and CoSi. At the temperature of 350 °C, increasing aging time caused the hardness to increase to a peak value at 0.5 h, and subsequently to decrease at longer aging times. At higher temperatures, the hardness decreased with increasing aging time. The conductivity and elongation to fracture increased with increasing aging time and tended to saturation at about 4 h. The hardness, conductivity and plasticity of the alloy cold rolled at 47% reduction, after the optimal aging treatments at (i) 350 °C for 0.5 h, (ii) 400 °C for 1 h, (iii) 500 °C for 0.5 h, were (i) 262 HV, 45.8%IACS and 3.6%; (ii) 249 HV, 48.1%IACS and 4.4%; (iii) 230 HV, 49.8%IACS and 5.5%, respectively. Based upon our results, we recommend the adoption of the optimized process.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

References

  1. Y.J. Ban, Y.F. Geng, J.R. Hou, Y. Zhang, M. Meng, Y.L. Jia, B.H. Tian, Y. Liu, X. Li, and A.A. Volinsky, Properties and Precipitates of the High Strength and Electrical Conductivity Cu-Ni-Co-Si-Cr Alloy, J. Mater. Sci. Technol., 2021, 93, p 1–6.

    Article  CAS  Google Scholar 

  2. Y.C. Cao, S.Z. Han, E.A. Choi, J.H. Ahn, X.J. Mi, S. Lee, H. Shin, S. Kim, and J. Lee, Effect of Inclusion on Strength and Conductivity of Cu-Ni-Si alloys with Discontinuous Precipitation, J. Alloys Compd., 2020, 843, p 156006.

    Article  CAS  Google Scholar 

  3. J. Zou, L. Lu, D.P. Lu, K.M. Liu, Z.B. Chen, and Q.J. Zhai, Effect of Boron and Cerium on Corrosion Resistance of Cu-Fe-P Alloy, J. Mater. Eng. Perform., 2016, 25(3), p 1062–1067.

    Article  CAS  Google Scholar 

  4. K.M. Liu, D.P. Lu, H.T. Zhou, Z.B. Chen, A. Atrens, and L. Lu, Influence of A High Magnetic Field on the Microstructure and Properties of a Cu-Fe-g in Situ Composite, Mater. Sci. Eng. A, 2013, 584, p 114–120.

    Article  CAS  Google Scholar 

  5. H. Fu, S. Xu, W. Li, J. Xie, H. Zhao, and Z. Pan, Effect of Rolling and Aging Processes on Microstructure and Properties of Cu-Cr-Zr Alloy, Mater. Sci. Eng. A, 2017, 700, p 107–115.

    Article  CAS  Google Scholar 

  6. K. Liu, Z. Jiang, J. Zhao, J. Zou, Z. Chen, and D. Lu, Effect of Directional Solidification Rate on the Microstructure and Properties of Deformation-Processed Cu-7Cr-0.1 Ag in Situ Composites, J. Alloys Comp., 2014, 612, p 221–226.

    Article  CAS  Google Scholar 

  7. B.L. An, Y. Xin, R.M. Niu, J. Lu, E.G. Wang, and K. Han, Hardening Cu-Ag Composite by Doping with Sc, Mater. Lett., 2019, 252, p 207–210.

    Article  CAS  Google Scholar 

  8. R. Zhang, Z. Li, X.F. Sheng, Y. Gao, and Q. Lei, Grain Refinement and Mechanical Properties Improvements in A High Strength Cu-Ni-Si Alloy During Multidirectional Forging, Fusion Eng. Des., 2020, 159, p 111766.

    Article  CAS  Google Scholar 

  9. W. Liao, X. Liu, Y. Yang, S. Wang, and M. Du, Effect of Cold Rolling Reduction Rate on Mechanical Properties and Electrical Conductivity of Cu-Ni-Si Alloy Prepared by Temperature Controlled Mold Continuous Casting, Mater. Sci. Eng. A, 2019, 763, p 138068.

    Article  CAS  Google Scholar 

  10. M. Goto, T. Yamamoto, S.Z. Han, T. Utsunomiya, S. Kim, J. Kitamura, J.H. Ahn, S.H. Lim, and J. Lee, Simultaneous Increase in Electrical Conductivity and Fatigue Strength of Cu-Ni-Si Alloy by Utilizing Discontinuous Precipitates, Mater. Lett., 2021, 288, p 129353.

    Article  CAS  Google Scholar 

  11. W. Liao, X. Liu, and Y. Yang, Relationship and Mechanism Between Double Cold Rolling-Aging Process, Microstructure and Properties of Cu–Ni–Si Alloy Prepared by Two-Phase Zone Continuous Casting, Mater. Sci. Eng. A, 2020, 797, p 140148.

    Article  CAS  Google Scholar 

  12. S. Lee, H. Matsunaga, X. Sauvage, and Z. Horita, Strengthening of Cu-Ni-Si Alloy Using High-Pressure Torsion and Aging, Mater. Charact., 2014, 90, p 62–70.

    Article  CAS  Google Scholar 

  13. Y. Wu, Y. Li, J. Lu, S. Tan, F. Jiang, and J. Sun, Effects of Pre-Deformation on Precipitation Behaviors and Properties in Cu-Ni-Si-Cr Alloy, Mater. Sci. Eng. A, 2019, 742, p 501–507.

    Article  CAS  Google Scholar 

  14. D.M. Li, Q. Wang, B.B. Jiang, X.N. Li, W.L. Zhou, C. Dong, H. Wang, and Q.X. Chen, Minor-Alloyed Cu-Ni-Si Alloys with High Hardness and Electric Conductivity Designed by A Cluster Formula Approach, Prog. Nat. Sci.-Mater., 2017, 27(4), p 467–473.

    Article  CAS  Google Scholar 

  15. W. Wang, H. Kang, Z. Chen, Z. Chen, C. Zou, R. Li, and T. Wang, Effects of Cr and Zr Additions on Microstructure and Properties of Cu-Ni-Si Alloys, Mater. Sci. Eng. A, 2016, 673, p 378–390.

    Article  CAS  Google Scholar 

  16. Q. Lei, Z. Li, C. Dai, J. Wang, X. Chen, J.M. Xie, and D.L. Chen, Effect of Aluminum on Microstructure and Property of Cu-Ni-Si Alloys, Mater. Sci. Eng. A, 2013, 572, p 65–74.

    Article  CAS  Google Scholar 

  17. H. Wei, Y. Chen, Z. Li, Q. Shan, W. Yu, and D. Tang, Microstructure Evolution and Dislocation Strengthening Mechanism of Cu-Ni-Co-Si Alloy, Mater. Sci. Eng. A, 2021, 826, p 142023.

    Article  CAS  Google Scholar 

  18. S.B. Pan, Y.J. Wang, J.X. Yu, M.J. Yang, Y.Q. Zhang, H.T. Wei, Y.C. Chen, J.W. Wu, J.J. Han, C.P. Wang, and X.J. Liu, Accelerated Discovery of High-Performance Cu-Ni-Co-Si alloys Through Machine Learning, Mater. Des., 2021, 209, p 109929.

    Article  CAS  Google Scholar 

  19. Y.J. Ban, Y. Zhang, B.H. Tian, K.X. Song, M. Zhou, X.H. Zhang, Y.L. Jia, X. Li, Y.F. Geng, Y. Liu, and A.A. Volinsky, EBSD Analysis of Hot Deformation Behavior of Cu-Ni-Co-Si-Cr Alloy, Mater. Charact., 2020, 169, p 110656.

    Article  CAS  Google Scholar 

  20. Z. Zhao, Y. Zhang, B.H. Tian, Y.L. Jia, Y. Liu, K.X. Song, and A.A. Volinsky, Co Effects on Cu-Ni-Si Alloys Microstructure and Physical Properties, J. Alloys Compd., 2019, 797, p 1327–1337.

    Article  CAS  Google Scholar 

  21. F. Liu, J. Li, L.J. Peng, G.J. Huang, H.F. Xie, J.M. Ma, and X.J. Mi, Simultaneously Enhanced Hardness and Electrical Conductivity in a Cu-Ni-Si Alloy by Addition of Cobalt, J. Alloys Compd., 2021, 862, p 158667.

    Article  CAS  Google Scholar 

  22. J. Li, G. Huang, X. Mi, L. Peng, H. Xie, and Y. Kang, Microstructure Evolution and Properties of A Quaternary Cu-Ni-Co-Si Alloy with High Strength and Conductivity, Mater. Sci. Eng. A, 2019, 766, p 138390.

    Article  CAS  Google Scholar 

  23. S. Suzuki, N. Shibutani, K. Mimura, M. Isshiki, and Y. Waseda, Improvement in Strength and Electrical Conductivity of Cu-Ni-Si Alloys by Aging and Cold Rolling, J. Alloys Compd., 2006, 417(1–2), p 116–120.

    Article  CAS  Google Scholar 

  24. Z. Zhao, Z. Xiao, Z. Li, W. Qiu, H. Jiang, Q. Lei, and S. Zhang, Microstructure and Properties of a Cu-Ni-Si-Co-Cr Alloy with High Strength and High Conductivity, Mater. Sci. Eng. A, 2019, 759, p 396–403.

    Article  CAS  Google Scholar 

  25. J. Huang, Z. Xiao, J. Dai, Z. Li, H. Jiang, W. Wang, and X. Zhang, Microstructure and Properties of a Novel Cu-Ni-Co-Si-Mg Alloy with Super-High Strength and Conductivity, Mater. Sci. Eng. A, 2019, 744, p 754–763.

    Article  CAS  Google Scholar 

  26. K. Liu, Z. Huang, X. Zhang, D. Lu, A. Atrens, H. Zhou, and W. Guo, Influence of Ag Micro-Alloying on the Thermal Stability and Ageing Characteristics of a Cu-14Fe in-Situ Composite, Mater. Sci. Eng. A, 2016, 673, p 1–7.

    Article  CAS  Google Scholar 

  27. J.Y. Cheng, B.B. Tang, F.X. Yu, and B. Shen, Evaluation of Nanoscaled Precipitates in a Cu-Ni-Si-Cr Alloy During Aging, J. Alloys Compd., 2014, 614, p 189–195.

    Article  CAS  Google Scholar 

  28. K.M. Liu, Z.Y. Jiang, J.W. Zhao, J. Zou, L. Lu, and D.P. Lu, Thermal Stability and Properties of Deformation-Processed Cu-Fe in Situ Composites, Metall. Mater. Trans. A, 2015, 46A(5), p 2255–2261.

    Article  Google Scholar 

  29. Y. Wu, Y. Li, J. Lu, S. Tan, F. Jiang, and J. Sun, Correlations Between Microstructures and Properties of Cu-Ni-Si-Cr Alloy, Mater. Sci. Eng. A, 2018, 731, p 403–412.

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (51861025), and the Provincial Natural Science Foundation of Jiangxi (20202ACBL20087, 20192BAB206001).

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Keming Liu.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sheng, X., Li, X., Liu, K. et al. Influence of Aging Treatment on the Microstructure and Properties of a Deformation-Processed Cu-Ni-Co-Si Alloy. J. of Materi Eng and Perform 32, 221–231 (2023). https://doi.org/10.1007/s11665-022-07497-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11665-022-07497-7

Keywords

Navigation