Abstract
Water-atomized powders of M3:2 high-speed steel (HSS) were blended with B4C and consolidated by cold press sintering. With the addition of B4C (~ 0.2 vol.%), satisfactory mechanical properties were achieved for HSS by sintering at a temperature as low as 1190 °C [e.g., 53.2 ± 0.2 in the Rockwell hardness (HRC) and 3074 ± 56 MPa in bending strength]. High relative density (98.5%) and good strength were attributed to the mechanism described as follows: First, the atoms of boron and carbon escaped after the reaction between B4C and iron matrix. Then, the sintered HSS was strengthened by boron atoms while they were distributed in M6C or MC carbides and iron matrix. Second, a plenty of M6C carbides were formed due to the release of carbon atoms. As a result, the value of solidus temperature was reduced. In addition, mechanical properties were greatly improved by heat treatment (quenching and tempering) (e.g., 61.2 ± 0.3 in HRC, 4356 ± 64 MPa in bending strength, and 42.3 ± 0.5 MPa m1/2 in fracture toughness, respectively).
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References
F. Velasco, R. Isabel, N. Antón, M.A. Martínez, and J.M. Torralba, TiCN-High Speed Steel Composites: Sinterability and Properties, Compos. Part A App. Sci. Manuf., 2002, 33(6), p 819–827
S. Giménez, C. Zubizarreta, V. Trabadelo, and I. Iturriza, Sintering Behaviour and Microstructure Development of T42 Powder Metallurgy High Speed Steel Under Different Processing Conditions, Mater. Sci. Eng. A, 2008, 480(1–2), p 130–137
B. Šuštaršič, L. Kosec, M. Kosec, B. Podgornik, and S. Dolinšek, The Influence of MoS2 Additions on the Densification of Water-Atomized HSS Powders, J. Mater. Process. Technol., 2006, 173(3), p 291–300
Q. Zhang, J. Yao, W. Shen, H. Zhang, Y. He, L. Nan, C.T. Liu, H. Huang, and X. Huang, Direct Fabrication of High-Performance High Speed Steel Products Enhanced by LaB6, Mater. Des., 2016, 112, p 469–478
V. Astini, Y. Prasetyo, and E.R. Baek, Effect of Boron Addition on the Microstructure and Mechanical Properties of 6.5% V-5% W High Speed Steel, Met. Mater. Int., 2012, 18(6), p 923–931
H. Fu, S. Ma, J. Hou, Y. Lei, and J. Xing, Microstructure and Properties of Cast B-Bearing High Speed Steel, J. Mater. Eng. Perform., 2013, 22(4), p 1194–1200
R. Tardon and R.M. German, Sintering and Mechanical Properties of Boron-Doped Austenitic Stainless Steel, Met. Powder Rep., 1998, 53(12), p 36
S.G. Napara-Volgina, Investigation of Features of Various Modes of Alloying by Boron of Powder Structural Steels, Met. Sci. Met. Treat., 2008, 4, p 34–37
G. Bagliuk, Properties and Structure of Sintered Boron Containing Carbon Steels, Sintering: Methods and Products, V. Shatokha, Ed., InTech, Rijeka, 2012, p 249–266
R. Zhou, D. Wang, J. Shen, and J. Sun, Effect of Carbon Addition on the Microstructure and Properties of M3:2 High Speed Steels Processed by Powder Metallurgy, Adv. Mater. Res., 2007, 29–30, p 153–158
G. Steven, A.E. Nehrenberg, and T.V. Philip, High Performance High Speed Steel by Design, Trans. ASM, 1964, 57, p 925–948
S. Raju, B.J. Ganesh, A. Banerjee, and E. Mohandas, Characterisation of Thermal Stability and Phase Transformation Energetics in Tempered 9Cr-1Mo Steel Using Drop and Differential Scanning Calorimetry, Mater. Sci. Eng. A, 2007, 465(1–2), p 29–37
A. Basu, B.K. Ghosh, S. Jana, and S.C. Dasgupta, Effect of Metallurgical Variables on Grain Size of High-Speed Tool Steels, Met. Technol., 1980, 7(1), p 151–158
M.A. Selamat and M. Mohamad, Supersolidus Sintering and Mechanical Properties of Water-Atomised M3/2 High-Speed Steel Powder Sintered Under Nitrogen-Based Atmosphere, Jurnal Teknologi, 2004, 41(A), p 77–84
YuV Turov, B.M. Khusid, L.G. Voroshnin, B.B. Khina, and I.L. Kozlovskii, Structure Formation in Sintering Iron-Boron Carbide Powder Composite, Powder Metall., 1991, 6(342), p 25–31
L. Karlsson, Non-equilibrium Grain Boundary Segregation of Boron in Austenitic Stainless Steel-III. Computer Simulations, Acta Metall., 1988, 36(1), p 25–34
R. Correa, A. Bedolla-Jacuinde, J. Zuno-Silva, E. Cardoso, and I. Mejía, Effect of Boron on the Sliding Wear of Directionally Solidified High-Chromium White Irons, Wear, 2009, 267(1–4), p 495–504
C. Toennes, P. Ernst, G. Meyer, and R.M. German, Full Density Sintering by Boron Addition in a Martensitic Stainless Steel, Adv. Powder Metall., 1992, 3, p 371–381
L. Karlsson, H. Nordén, and H. Odelius, Non-Equilibrium Grain Boundary Segregation of Boron in Austenitic Stainless Steel-I. Large Scale Segregation Behaviour, Acta Metall., 1988, 36(1), p 13–24
E.D. Bendereva and S.T. Vylkanov, Activating Effect of Boron Micro-additions on Sintering of Powder Alloy Based on Iron, Metallurgist, 2012, 55(9–10), p 761–768
M. Lin, X.F. Zhao, L.Z. Han, Q.D. Liu, and J.F. Gu, Microstructural Evolution and Carbide Precipitation in a Heat-Treated H13 Hot Work Mold Steel, Metall. Micro Anal., 2016, 56, p 520–527
J.W. Park, C.L. Huo, and S. Lee, Composition, Microstructure, Hardness, and Wear Properties of High-Speed Steel Rolls, Metall. Mater. Trans. A, 1999, 30(2), p 399–409
P. Luo, Q.D. Hu, and X. Wu, Quantitatively Analyzing Strength Contribution vs Grain Boundary Scale Relation in Pure Titanium Subjected to Severe Plastic Deformation, Metall. Mater. Trans. A, 2016, 47(5), p 1922–1928
S.R. Keown and F.B. Pickering, Some Aspects of the Occurrence of Boron in Alloy Steels, Met. Sci. J., 1977, 11(7), p 225–234
A. Röttger, J. Lentz, and W. Theisen, Boron-Alloyed Fe-Cr-C-B Tool Steels-Thermodynamic Calculations and Experimental Validation, Mater. Des., 2015, 88, p 420–429
H.L. Peng, L. Hu, L.J. Li, L.Y. Zhang, and X.L. Zhang, Evolution of the Microstructure and Mechanical Properties of Powder Metallurgical High-Speed Steel S390 After Heat Treatment, J. Alloys Compd., 2018, 740, p 766–773
J. Jaworski, R. Kluz, and T. Trzepieciński, Influence of Heat Treatment on Content of the Carbide Phases in the Microstructure of High-Speed Steel, Arch. Foundry Eng., 2017, 17(3), p 59–62
P.B. Bijlsma, B. Fihn, A. Sjoqvist, R.A. Peeters, and R.V.D. Meer, The Metallography and Heat Treatment of Iron and Steel, McGraw-Hill, Boston, 1926
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This work was supported by the National High Technology Research and Development Program of China (863 Program) under the grant number 2013AA031102. One of the authors (PL) gratefully acknowledges the financial support from Shanghai Collaborative Innovation Centre for Heavy Casting/Forging Manufacturing Technology and the Practice Scheme via Industry-University-Research Cooperation for Shanghai Higher Education Teachers, as sponsored by Shanghai Municipal Education Commission.
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Zhang, F., Luo, P., Ouyang, Q. et al. Microstructure and Mechanical Properties of B4C-Blended M3:2 High-Speed Steel Powders Consolidated by Sintering and Heat Treatment. J. of Materi Eng and Perform 28, 6145–6156 (2019). https://doi.org/10.1007/s11665-019-04347-x
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DOI: https://doi.org/10.1007/s11665-019-04347-x