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The correlation of Li+ Carrier Towards Immittance Conduction Properties on Alginate-PVA-LiNO3 Complexes-Based Solid Polymer Electrolytes System

  • Topical Collection: International Conference on Organic Electronics 2022
  • Published:
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Abstract

The increasing interest in green energy storage materials for electrochemical devices with the development of bio-polymer materials as electrolytes has recently attracted significant attention. It can offer many high-value opportunities and lower costs, and is environmentally friendly. In the present work, an investigation of the correlation of Li+ carrier in alginate-poly(vinyl alcohol) complexes-based solid bio-polymer electrolytes (SPE) was carried out and successfully prepared via the solution-casting method. The prepared SPE system’s immittance response properties were investigated using electrical impedance spectroscopy (EIS) at different frequencies and temperatures. The sample containing 35 wt% of LiNO3 was the most conducting sample, with ionic conductivity at ambient temperature achieved at 3.46 S cm−1 × 10−3 S cm−1. The temperature-dependent ionic conduction of the SPE system shows the properties of Arrhenius where the sample is thermally activated. Based on the electrical formulism approach, it shows that the SPE system is aligned with the ionic conductivity trend and reveals non-Debye characteristics. It also shows that the results of this finding have good potential to be applied as an electrolyte for application in electrochemical devices.

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Acknowledgments

The authors would like to thank the Ministry of Higher Education (MOHE) for providing financial support under the Fundamental Research Grant Scheme (FRGS) (RDU19001114), Universiti Malaysia Pahang for providing additional financial support under the UMP internal grant (RDU 223304), Postgraduate Grants Research Scheme (PGRS) (PGRS2003113) and Faculty of Industrial Sciences and Technology (FIST) for laboratory facilities, and Ionic Materials Team members for the help and support given for the completion of this work.

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  1. Faculty of Industrial Sciences and Technology, Ionic Materials Team, Universiti Malaysia Pahang, 26300, Kuantan, Pahang, Malaysia

    A. S. Samsudin, N. S. Suhaimi & N. M. Ghazali

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  1. A. S. Samsudin
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  2. N. S. Suhaimi
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  3. N. M. Ghazali
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Correspondence to A. S. Samsudin.

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Samsudin, A.S., Suhaimi, N.S. & Ghazali, N.M. The correlation of Li+ Carrier Towards Immittance Conduction Properties on Alginate-PVA-LiNO3 Complexes-Based Solid Polymer Electrolytes System. J. Electron. Mater. 52, 4261–4268 (2023). https://doi.org/10.1007/s11664-022-10168-x

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