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Nanoscale characterization of the silicon dioxide-silicon carbide interface using elemental mapping by energy-filtered transmission electron microscopy

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Abstract

Energy-filtered transmission electron microscopy (EFTEM) was used to study 6H-SiC/SiO2 interfaces produced by thermal oxidation as a function of the oxidation conditions. Elemental maps of C and Si were used to calculate C-to-Si concentration profiles across the interfaces. Enhanced C/Si concentrations (up to ∼ 35%) were observed at distinct regions in samples oxidized at 1100°C for 4 h in a wet ambient. The data from a number of randomly selected regions indicate that re-oxidation at 950°C for 3 h significantly reduced, but did not eliminate, the amount of excess interfacial carbon.

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References

  1. L.A. Lipkin, M.K. Das, and J.W. Palmour, in Silicon Carbide—Materials, Processing and Devices, ed. A. Agarwal, M.S. Kowronski, J.A. Cooper, Jr., and E. Janzen (Warrendale, PA: Materials Research Society), H3.1.1 (2001).

    Google Scholar 

  2. M.K. Das, B.S. Um, and J.A. Cooper, Jr., Mater. Sci. Forum 338–342, 1069 (2000).

    Article  Google Scholar 

  3. G. Pensl, M. Bassler, F. Ciobanu, V.V. Afanas’ev, H. Yano, T. Kimoto, and H. Matsunami, in Silicon Carbide—Materials, Processing and Devices, ed. A. Agarwal, M.S. Kowronski, J.A. Cooper, Jr., and E. Janzen (Warrendale, PA: Materials Research Society), H3.2.1 (2001).

    Google Scholar 

  4. S. Wang, M. Di Ventra, S.G. Kim, and S.T. Pantelides, Phys. Rev. Lett. 86, 5946 (2001).

    Article  CAS  Google Scholar 

  5. L. A. Lipkin, D.B. Slater, Jr., and J.W. Palmour, U.S. patent 5,972,801 (1999).

    Google Scholar 

  6. S.T. Pantelides, R. Buczjo, M.D. Ventra, S. Wang, S.G. Kim, S.J. Pennycook, G. Duscher, L.C. Feldman, K. McDonald, R.K. Chanana, R.A. Weller, J.R. Williams, G.Y. Chung, C.C. Tin, and T. Issacs-Smith, in Silicon Carbide-Materials, Processing and Devices, ed. A. Agarwal, M.S. Kowronski, J.A. Cooper, Jr., and E. Janzen (Warrendale, PA: Materials Research Society), H3.3.1 (2001).

    Google Scholar 

  7. V.V. Afanas’ev, M. Bassler, G. Pensl, and M.J. Schulz, Phys. Status Solidi (a) 162, 321 (1997).

    Article  CAS  Google Scholar 

  8. M. Bassler, G. Pensl, and V.V. Afanas’ev, Dia. Rel. Mater. 6, 1472 (1997).

    Article  CAS  Google Scholar 

  9. L. Simon, L. Kubler, A. Ermolieff, and T. Billon, Phys. Rev. B 60, 5673 (1999).

    Article  CAS  Google Scholar 

  10. C. Virojanadara and L.I. Johansson, Surf. Sci. 505, 358 (2002).

    Article  CAS  Google Scholar 

  11. H.-F. Li, S. Dimitrijec, D. Sweatman, and H.B. Harrison, Mater. Sci. Forum. 338–342, 399 (2000).

    Google Scholar 

  12. J.R. Williams, G.Y. Chung, C.C. Tin, K. McDonald, D. Farmer, R.K. Chanana, R.A. Weller, S.T. Pantelides, O.W. Holland, M.K. Das, L.A. Lipkin, and L.C. Feldman, in Silicon Carbide—Materials, Processing and Devices, ed. A. Agarwal, M.S. Kowronski, J.A. Cooper, Jr., and E. Janzen (Warrendale, PA: Materials Research Society), H3.5.1 (2001).

    Google Scholar 

  13. C.-Y. Lu, J.A. Cooper, Jr., G.Y. Chung, J.R. Williams, K. McDonald, and L.C. Feldman, Mater. Sci. Forum 389–393, 977 (2002).

    Google Scholar 

  14. K. Fukuda, S. Suzuki, T. Tanaka, and K. Arai, Appl. Phys. Lett. 76, 1585 (2000).

    Article  CAS  Google Scholar 

  15. K.C. Chang, N.T. Nuhfer, L.M. Porter, and Q. Wahab, Appl. Phys. Lett. 77, 2186 (2000).

    Article  CAS  Google Scholar 

  16. L. Reimer, Energy-Filtering Transmission Electron Microscopy (Berlin: Springer-Verlag, 1995), p. 387.

    Google Scholar 

  17. J. T. Wolan, B.A. Grayson, J. Kohlscheen, Y. Emirov, R. Schlaf, R. Swartz, and S.E. Saddow, J. Electron Mater. 31, 380 (2002).

    Article  CAS  Google Scholar 

  18. R.N. Ghosh, S. Ezhilvalavan, B. Golding, S.M. Mukhopadhyay, N. Mahadev, P. Joshi, M.K. Das, and J.A. Cooper, Jr., in Silicon Carbide—Materials, Processing and Devices, ed. A. Agarwal, M.S. Kowronski, J.A. Cooper, Jr., and E. Janzen (Warrendale, PA: Materials Research Society), H3.7.1. (2001).

    Google Scholar 

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Chang, K.C., Bentley, J. & Porter, L.M. Nanoscale characterization of the silicon dioxide-silicon carbide interface using elemental mapping by energy-filtered transmission electron microscopy. J. Electron. Mater. 32, 464–469 (2003). https://doi.org/10.1007/s11664-003-0179-y

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  • DOI: https://doi.org/10.1007/s11664-003-0179-y

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