Skip to main content
Log in

Ti5Si3 whisker in-situ reinforced TiAl alloys

  • Published:
Metallurgical and Materials Transactions A Aims and scope Submit manuscript

Abstract

The effects of Fe, Cr, V, and Nb on the microstructures, tensile properties at 20 °C and 900 °C, and creep resistance at 800 °C of Ti5Si3 whisker-reinforced Ti52Al48-3Si2M alloys were investigated. The addition of Fe, Cr, Nb, and V modifies not only the morphologies but also the distribution of Ti5Si3 whiskers. A microstructure with a uniform and homogeneous distribution of Ti5Si3 whiskers was obtained in a Ti52Al48-3Si2Cr2V alloy by conventional ingot metallurgy. The Ti52Al48-3Si2Cr2V alloy has the best room-temperature tensile strength, relatively good ductility, an attractive tensile property at 900 °C, and good creep resistance at 800 °C. The improvement of properties results from not only the homogeneous distribution of Ti5Si3 whiskers but also from the higher fracture strength of the Ti5Si3 whisker and the interface property. The solubility of V in the Ti5Si3 phase is higher than that of Fe, Cr, and Nb. The element V is very effective in strengthening the Ti5Si3 whiskers. Different failure modes were found in the Ti5Si3 whisker-reinforced TiAl alloys at room temperature. Cleavage fracture dominates the failure of Ti5Si3 whiskers and γ phase in V-free alloys, whereas crack deflection and branching at the Ti5Si3-whisker/γ-matrix interface, subsequently followed by interface debonding and whisker bridging, were observed in Ti52Al48-3Si2V and Ti52Al48-3Si2Cr2V alloys. In addition, twinning and dislocation slip in Ti5Si3 whisker-reinforced TiAl alloys were investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Y.W. Kim: JOM, 1994, vol. 46, pp. 30–40.

    CAS  Google Scholar 

  2. D.M. Dimiduk: in Gamma Titanium Aluminides, Y.-W. Kim, R. Wagner, and M. Yamaguchi, eds., TMS, Warrendale, PA, 1995, pp. 3–20.

    Google Scholar 

  3. Y.W. Kim: Acta Metall. Mater., 1992, vol. 40 (6), pp. 1121–34.

    Article  CAS  Google Scholar 

  4. M. Yamaguchi and H. Inui: in Structural Intermetallics, R. Darolia, J.J. Lewandowski, C.T. Liu, P.L. Martin, D.B. Miracle, and M.V. Nathal, eds., TMS, Warrendale, PA, 1993, pp. 127–42.

    Google Scholar 

  5. S.C. Huang and E.L. Hall: Metall. Trans. A, 1991, vol. 22A, pp. 2619–27.

    CAS  Google Scholar 

  6. S.C. Huang and E.L. Hall: Acta Metall. Mater., 1991, vol. 39, pp. 1053–60.

    Article  CAS  Google Scholar 

  7. H. Doi, K. Hashimoto, K. Kasahara, and T. Tsujimoto: Mater. Trans. JIM, 1990, vol. 31, pp. 975–82.

    Google Scholar 

  8. T. Tsujimoto and K. Hashimoto: Mater. Res. Soc. Symp. Proc., 1989, vol. 133, pp. 391–96.

    Google Scholar 

  9. T. Hanamura and M. Tanino: J. Mater. Sci. Lett., 1989, vol. 8, pp. 24–28.

    Article  CAS  Google Scholar 

  10. T. Hanamura, R. Uemori, and M. Tanino: J. Mater. Sci. Lett., 1989, vol. 8, pp. 1239–40.

    Article  CAS  Google Scholar 

  11. Y.G. Li and M.H. Loretto: Acta Metall. Mater., 1994, vol. 42, pp. 2913–19.

    Article  CAS  Google Scholar 

  12. S. Das, J.M. Howe, and J.H. Perepezko: Metall. Mater. Trans. A, 1996, vol. 27A, pp. 1618–29.

    Google Scholar 

  13. T. Tetsui: in Gamma Titanium Aluminides, Y.-W. Kim, R. Wagner, and M. Yamaguchi, eds., TMS, Las Vegas, NV, 1995, pp. 603–60.

    Google Scholar 

  14. J. Beddoes, L. Zhao, J. Triantafillou, P. Au, and W. Wallace: in Gamma Titanium Aluminides, Y.-W. Kim, R. Wagner, and M. Yamaguchi, eds., TMS, Las Vegas, NV, 1995, pp. 959–67.

    Google Scholar 

  15. P.R. Bhowal, W.A. Konkel, and H.F. Merrick: in Gamma Titanium Aluminides, Y.-W. Kim, R. Wagner, and M. Yamaguchi, eds., TMS, Las Vegas, NV, 1995, pp. 787–94.

    Google Scholar 

  16. Y.-W. Kim: Acta Metall. Mater., 1992, vol. 40, pp. 1121–34.

    Article  CAS  Google Scholar 

  17. S. Tsuyama, S. Mitao, and K. Minakawa: Mater. Sci. Eng. 1992, vol. A153, pp. 451–56.

    CAS  Google Scholar 

  18. M. Es-Souni, R. Wagner, P.A. Beaven, and A. Bartels: Mater. Sci. Eng. 1992. vol. A153, pp. 444–50.

    CAS  Google Scholar 

  19. G.-X. Wang, B. Dogan, F.-Y. Hsu, H.-J. Klaar, and M. Dahms: Metall. Mater. Trans. A, 1995, vol. 26A, pp. 691–702.

    CAS  Google Scholar 

  20. L.T. Zhang, G.H. Qiu, and J.S. Wu: Scripta Metall. Mater., 1995, vol. 32, pp. 1683–88.

    Article  Google Scholar 

  21. D. Shechtman, M.J. Blackburn, and H.A. Lipsitt: Metall. Trans., 1974, vol. 5, pp. 1373–81.

    CAS  Google Scholar 

  22. Y.D. Hahn and S.H. Whang: Metall. Mater. Trans. A, 1995, vol. 26A, pp. 113–32.

    CAS  Google Scholar 

  23. Th. Jungling, B. Kieback, W. Glatz, and H. Clemens: in Gamma Titanium Aluminides, Y.-W. Kim, R. Wagner, and M. Yamaguchi, eds., TMS, Las Vegas, NV, 1995, pp. 627–34.

    Google Scholar 

  24. L. Clochefert, Y. Lepetitcorps, C. Colin, and M. Chanteranne: in Titanium ’95 Science and Technology, P.A. Blenkinsop, W.J. Evans, and H.M. Flower, eds., The Institute of Materials, Birmingham, United Kingdom, 1995, pp. 527–33.

    Google Scholar 

  25. A.L. Dore, T.J.A. Doel, and P. Bowen: in Titanium ’95 Science and Technology, P.A. Blenkinsop, W.J. Evans, and H.M. Flower, eds., The Institute of Materials, Birmingham, United Kingdom, 1995, pp. 2819–26.

    Google Scholar 

  26. A. Vassel, C. Indrigo, and F. Pautonnier: in Titanium ’95 Science and Technology, P.A. Blenkinsop, W.J. Evans, and H.M. Flower, eds., The Institute of Materials, Birmingham, United Kingdom, 1995, pp. 2739–46.

    Google Scholar 

  27. D. Upadhyaya, F.H. Froes, C.M. Ward-Close, L. Chandrasekaran, and M.J. Wood: in Titanium ’95 Science and Technology, P.A. Blenkinsop, W.J. Evans, and H.M. Flower, eds., The Institute of Materials, Birmingham, United Kingdom, 1995, pp. 527–33.

    Google Scholar 

  28. K.S. Chan: Metall. Trans. A, 1993, vol. 24A, pp. 1531–42.

    CAS  Google Scholar 

  29. Lanting Zhang and Jiansheng Wu: in High-Temperature Ordered Intermetallic Alloys VIII, Boston, MA, Nov. 30–Dec. 3, 1999, Easo P. George, Micael J. Mills, and Masaharu Yamaguchi, eds., Materials Research Society, pp. kk5.24.1–6.

  30. D.L. Davidson, R.M. Arrowood, J.E. Hack, G.R. Leverant, and S.P. Clough: in Mechanical Behavior of Metal Matrix Composites, J.E. Hack and M.F. Amateau, eds., TMS-AIME, Warrendale, PA, 1981, pp. 117–42.

    Google Scholar 

  31. D.L. Davidson, K.S. Chan, A. McMinn, and G.R. Leverant: Metall. Trans. A, 1989, vol. 20A, pp. 2369–78.

    CAS  Google Scholar 

  32. D.L. Davidson: Metall. Trans. A, 1992, vol. 23A, pp. 865–79.

    CAS  Google Scholar 

  33. P. Kantzos, J. Teleman, and L. Ghosn: NASA-CP-10039, NASA, Washington, DC, 1989, pp. 66-1–66-10.

  34. J.M. Larsen, K.A. Williams, J. Balsone, and M.A. Stucke: in High-Temperature Aluminides and Intermetallics, S.A. Whang, C.T. Liu, D. Pope, and J.O. Stiegler, eds., TMS, Warrendale, PA, 1990, pp. 521–56.

    Google Scholar 

  35. V.C. Nardone and K.M. Prewo: Scripta Metall., 1986, vol. 20, pp. 43–48.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sun, FS., Cao, CX., Yan, MA. et al. Ti5Si3 whisker in-situ reinforced TiAl alloys. Metall Mater Trans A 32, 1233–1244 (2001). https://doi.org/10.1007/s11661-001-0132-8

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11661-001-0132-8

Keywords

Navigation