Abstract
The Cu65Ni35 alloy liquid was undercooled by the fluxing method, and the rapid solidification structure was obtained by natural cooling. The solidification interface migration information of Cu65Ni35 alloy liquid in rapid solidification stage was photographed with the help of high-speed camera, and the recalescence velocity was calculated. The microstructure evolution of the alloy was systematically studied by observing the microstructure morphology and taking photos on the metallographic microscope. By analyzing the evolution of dendrite grain size and microstructure microhardness with undercoolingand relying on electron backscatter diffraction (EBSD) technology, the grain refinement mechanism of microstructure under high undercooling and low undercooling is finally confirmed.
Similar content being viewed by others
References
Liu F, Yang GC. Rapid Solidification of Highly Undercooled Bulk Liquid Superalloy: Recent Developments, Future Directions[J]. International Materials Reviews, 2013, 51(3): 145–170
Wei B, Yang C, Zhou Y. High Undercooling and Rapid Solidification of Ni-32.5%Sn Eutectic Alloy[J]. Acta Metallurgica et Materialia, 1991, 39(6): 1249–1258
Ma K, Zhao Y, Xu X, et al. The Effect of Undercooling on Growth Velocity and Microstructure of Ni95Cu5 Alloys[J]. Journal of Crystal Growth, 2019, 513: 30–37
Zheng C, Yanan Y, Qiang C, et al. Recalescence Effect Simulation Andmicrostructure Evolution Ofundercooled Fe82B17Si1 Alloy[J]. Acta Metallurgica Sinica, 2014, 50(7): 795–801
Xi Z, Yang G, Zhou Y. Growth Morphology of Ni3Si in High Undercooled Ni-Si Eutectic Alloy[J]. Progressin Natural Science, 1997, 5: 114–121
Li D, Yang G, Zhou Y. Recalescence and Solidification Microstructure of Highly Undercooled Alloy Ni68B21Si11[J]. Acta Metallurgica Sinica, 1992, 28(10): 1–5
Xu XL, Chen YZ, Liu F. Evolution of Solidification Microstructure in Undercooled Co80Pd20 Alloys[J]. Materials Science and Technology, 2013, 28(12): 1492–1498
Dragnevski KI, Mullis AM, Cochrane RF. The Effect of Experimental Variables on the Levels of Melt Undercooling[J]. Materials Science and Engineering: A, 2004, 375–377: 485–487
Greer AL. Nucleation and Solidification Studies Using Drop-tubes[J]. Materials Science and Engineering A, 1994, 178(1–2): 113–120
Wang Z. Magnetic Levitation Melting Method[J]. Foreign Science and Technology, 1991, (7): 2
Perepezko JH. Nucleation Reactions in Undercooled Liquids[J]. Materials Science and Engineering A, 1984, 178(1): 105–111.
Lu SY, Li JF, Zhou YH. Grain Refinement in the Solidification of Undercooled Ni-Pd Alloys[J]. Journal of Crystal Growth, 2007, 309(1): 103–111
Dragnevski KI, Cochrane RF, Mullis AM. The Mechanism for Spontaneous Grain Refinement in Undercooled Pure Cu Melts[J]. Materials Science and Engineering A, 2004, 375: 479–484
Xu X, Hou H, Zhao Y, et al. Nonequilibrium Solidification, Grain Refinements, and Recrystallization of Deeply Undercooled Ni-20 At. Pct Cu Alloys: Effects of Remelting and Stress[J]. Metallurgical and Materials Transactions A, 2017, 48(10): 4777–4785
Wang H, Liu F, Yang G. Experimental Study of Grain Refinement Mechanism in Undercooled N-15at%Cu Alloy[J]. Journal of Materials Research, 2011, 25(10): 1963–1974
Xu XL, Zhao YH, Hou H. Observation of Dendrite Growth Velocity and Microstructure Transition in Highly Undercooled Single Phase Alloys[J]. Materials Characterization, 2019, 155
Grgač P, Mesárošová J, Behúlová M, et al. Experimental Determination of the Nuclei Number in the Deeply Undercooled and Rapidly Solidified Powder Particles of High-alloyed Steel[J]. Journal of Alloys and Compounds, 2019, 798: 204–209
Xu X, Chen Y, Liu F. Evidence of Recrystallization Mechanism of Grain Refinement in Hypercooled Co80Pd20 Alloys[J]. Materials Letters, 2012, 81: 73–75
Willnecker R, Herlach D M, Feuerbacher B. Grain Refinement Induced by a Critical Crystal Growth Velocity in Undercooled Melts[J]. Applied Physics Letters, 1990, 56(4): 324–326
Grain Refinement and the Stability of Dendrites Growing into Undercooled Pure Metals and Alloys[J]. Journal of Applied Physics, 1997, 82(8): 3783–3790
Powell L. The Undercooling of Silver[J]. J. Aust. Inst. Met., 1965, 10: 3223
Leung KK, Chiu CP, Kui HW. Grain Refinement in Undercooled Nickel[J]. Scripta Metallurgica et Materialia, 1995, 32(10): 1559–1563
Karma A. Model of Grain Refinement in Solidification of Undercooled Melts[J]. International Journal of Non-Equiulibrium Processing, 1998, 11(2): 201–223
Li J, Liu Y, Lu Y, et al. Structural Evolution of Undercooled Ni-Cu Alloys[J]. Journal of Crystal Growth, 1998, 192: 462–470
Horvay G. The Tension Field Created by a Spherical Nucleus Freezing into Its Less Dense Undercooled Melt[J]. International Journal of Heat and Mass Transfer, 1965, 8(2): 195–243
Boettinger WJ, Coriell SR, Trivedi R. Rapid Solidification Processing: Principles and Technologies IV[M]. Baton Rouge: Claitor’s Pulishing Division, 1988
Liu F, Yang G. Stress-induced Recrystallization Mechanism for Grain Refinement in Highly Undercooled Superalloy[J]. Journal of Crystal Growth, 2001, 231: 295–305
Funding
Funded by the National Natural Science Foundation of China (No.51701187), and the Basic Applied Research Projects in Shanxi Province (201801D221151)
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Liang, H., Cheng, T., Li, R. et al. Recalescence Velocity and Microstructure Evolution of Deeplyundercooled Cu65Ni35 Alloy. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 37, 277–284 (2022). https://doi.org/10.1007/s11595-022-2528-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11595-022-2528-9