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Synthesis of a novel UV-curable oligmer 1,4-cyclohexanedimethanol glycidyl ether acrylate and study on its UV-curing properties

  • Organic Materials
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Abstract

A novel UV-curable oligmer 1,4-cyclohexanedimethanol glycidyl ether acrylate (CHDMGEA) was synthesized by utilizing 1,4-cyclohexanedimethanol glycidyl ether (CHDMGE) and acrylic acid (AA) as starting materials, triphenyl phosphine as catalyst and p-hydroxyanisole as inhibitor. The optimum synthetic conditions were that the concentration of triphenyl phosphine was 0.90% of reactants by weight, the concentration of p-hydroxyanisole was 0.20% of reactants by weight, the reaction temperature was 90–100 °C, and the molar ratio of CHDMGE to AA was 0.5:1.1. The experimental results show that CHDMGEA is a kind of good UV-curable oligmer. The impact resistance of the UV-cured films with CHDMGEA as oligmer to prepare UV-curing coating was superior to that of the UV-cured films with bisphenol A diglycidyl ether diacrylate (BPGEA) as oligmer to prepare UV-curing coating.

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Authors and Affiliations

  1. School of Materials Science and Engineering, Nanchang University, Nanchang, 330031, China

    Biwu Huang  (黄笔武), Chong Deng, Qinchang Xu, Weiqing Chen & Huaihua Zou

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  1. Biwu Huang  (黄笔武)
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  2. Chong Deng
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  3. Qinchang Xu
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  4. Weiqing Chen
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  5. Huaihua Zou
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Corresponding author

Correspondence to Biwu Huang  (黄笔武).

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Funded by the Natural Science Foundation of Jiangxi Province(20142BAB206029)

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Huang, B., Deng, C., Xu, Q. et al. Synthesis of a novel UV-curable oligmer 1,4-cyclohexanedimethanol glycidyl ether acrylate and study on its UV-curing properties. J. Wuhan Univ. Technol.-Mat. Sci. Edit. 29, 1283–1289 (2014). https://doi.org/10.1007/s11595-014-1082-5

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  • DOI: https://doi.org/10.1007/s11595-014-1082-5

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