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Preparation of NiMoO4 porous nanosheets by freezing method as adhesive-free electrodes for high-performance flexible supercapacitors

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Abstract

This article successfully prepared porous NiMoO4 sheet-like structured nanomaterials deposited on carbon cloth using the freeze-drying method. The morphology and phase structure were characterized by SEM, TEM, and XRD, proving that the material is NiMoO4 porous nanosheets. The NiMoO4 porous nanosheets have a large specific surface area, which increases the reaction sites of the material, shortens the transmission distance of electrons and ions, accelerates the reaction rate, and thus improves the charge storage capacity. We conducted electrochemical performance tests on the material, and the test results showed that the specific capacity was 1683 F/g at a current density of 5 A/g. After 5000 cycles, the capacitance retention rate was 99.7%. We further assembled NiMoO4 porous nanosheets as positive electrodes and CNTs as negative electrodes to form solid-state asymmetric capacitor devices. At a current density of 15 A/g and a working window voltage of 1.6 V, the asymmetric device has an energy density of 70.8 Wh/Kg and a power density of 7000 W/Kg. After 10,000 cycles at a current density of 5 A/g, the device exhibits excellent cycling stability with a capacitance retention rate of 87.6%. This article provides a valuable reference for the development of electrode materials for capacitors.

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Data Availability

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Funding

This research was supported by the National Natural Science Foundation of China (No. 52002099), the Youth Scientific Research Item of Harbin Commercial University (18XN034), and the Foundation of State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering (Grant No. 2022-K74). Basic research business fees for provincial higher education institutions in Heilongjiang Province (2023-KYYWF-1015).

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Authors and Affiliations

  1. School of Light Industry, Harbin University of Commerce, Harbin, 150028, China

    Jing Wang, Yang Liu, Jun Wang, Tenghao Ma & Yingjie Hao

  2. Center for Composite Materials and Structure, Harbin Institute of Technology, Harbin, 150001, China

    Tingting Hao

  3. State Key Laboratory of High-Efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Ningxia, 750021, Ningxia, China

    Jian Hao

  4. School of Chemistry and Chemical Engineering, Quzhou College, Quzhou, 324000, China

    Shen Wang

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  1. Jing Wang
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Contributions

Y.L. and J.W.1 planned this study. Y.L. conducted an experiment, organized the data, and wrote an article. T.H. and J.W.2 revised the experimental data, J.H. and S.W. participated in the organization of the experimental data, T.M and Y.H. contributed to the analysis of the experimental data, and all authors reviewed the first draft.

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Correspondence to Jing Wang.

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Wang, J., Liu, Y., Hao, T. et al. Preparation of NiMoO4 porous nanosheets by freezing method as adhesive-free electrodes for high-performance flexible supercapacitors. Ionics 30, 1749–1758 (2024). https://doi.org/10.1007/s11581-024-05379-7

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