Abstract
Lithium-sulfur battery, one of the most prominent and widely studied batteries, takes sulfur as the cathode which has rich reserves in the earth. It has the characteristics of high energy density, high theoretical specific capacity, affordable cost, and environment-friendly. Although this system has many advantages, it has many essential shortcomings, such as the non-conductivity of active materials and discharge intermediates, shuttle effect, the volume effect of the sulfur cathode, and the dendritic growth of lithium. In this paper, we summarize the solutions and related research of cathode materials in the lithium-sulfur battery from three aspects: the improvement of conductivity, the alleviation of the shuttle effect, and the use of Li2S cathode. And put forward the suggestions and prospects for future improvement methods.
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Abbreviations
- LiPs:
-
lithium polysulfides
- Li-S battery/Li-S batteries:
-
lithium-sulfur battery/lithium-sulfur batteries
- TDPAT (H6TDPAT):
-
2,4,6-tris(dicarboxyphenylamino)-1,3,5-triazine
- BTB:
-
benzene-1,3,5-triphenate
- BP:
-
4,4′-bipyridine
- MOF:
-
metal-organic framework
- COHP:
-
crystal orbital Hamilton population
References
Liang J, Zhao H, Yue L, Fan G, Li T, Lu S, Chen G, Gao S, Asiri AM, Sun X (2020) Recent advances in electrospun nanofibers for supercapacitors. J Mater Chem A. https://doi.org/10.1039/D0TA05100D
Yue LC, Zhao HT, Wu ZG, Liang J, Lu SY, Chen G, Gao SY, Zhong BH, Guo XD, Sun XP (2020) Recent advances in electrospun one-dimensional carbon nanofiber structures/heterostructures as anode materials for sodium ion batteries. J Mater Chem A 8:11493–11510
Feng G, Liu X, Wu Z, Chen Y, Yang Z, Wu C, Guo X, Zhong B, Xiang W, Li J (2020) Enhancing performance of Li–S batteries by coating separator with MnO @ yeast-derived carbon spheres. J Alloys Compd 817:152723
Feng GL, Liu XH, Liu YN, Wu ZG, Chen YX, Guo XD, Zhong BH, Xiang W, Li JS (2018) Trapping polysulfides by chemical adsorption barrier of LixLayTiO3 for enhanced performance in lithium-sulfur batteries. Electrochim Acta 283:894–903
Yin WZ, Wu ZG, Tian W, Chen YX, Xiang W, Feng GL, Li YC, Wu CJ, Xu CL, Bai CJ, Zhong BH, Wang XL, Zhang J, He FR, Alshehri AA, Guo XD (2019) Enhanced constraint and catalysed conversion of lithium polysulfides via composite oxides from spent layered cathodes. J Mater Chem A 7:17867–17875
Wang Y, Guo X, Chen C, Wang Y, Li Q, Wu Z, Zhong B, Chen Y (2020) Alleviating the shuttle effect via bifunctional MnFe2O4/AB modified separator for high performance lithium sulfur battery. Electrochim Acta:354
Chung SH, Chang CH, Manthiram A (2018) Progress on the critical parameters for lithium-sulfur batteries to be practically viable. Adv Funct Mater 28:1801188
Liu X, Huang JQ, Zhang Q, Mai LQ (2017) Nanostructured metal oxides and sulfides for lithium-sulfur batteries. Adv Mater 29:1601759
Pang Q, Liang X, Kwok CY, Nazar LF (2016) Advances in lithium-sulfur batteries based on multifunctional cathodes and electrolytes. Nat Energy 1:16132
Ji X, Nazar LF (2010) Advances in Li-S batteries. J Mater Chem 20:9821–9826
Ji XL, Lee KT, Nazar LF (2009) A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries. Nat Mater 8:500–506
Manthiram A, Fu YZ, Su YS (2013) Challenges and prospects of lithium-sulfur batteries. Acc Chem Res 46:1125–1134
Song MK, Cairns EJ, Zhang YG (2013) Lithium/sulfur batteries with high specific energy: old challenges and new opportunities. Nanoscale 5:2186–2204
Lim WG, Kim S, Jo C, Lee J (2019) A comprehensive review of materials with catalytic effects in Li-S batteries: enhanced redox kinetics. Angew Chem Int Ed 58:18746–18757
Manthiram A, Fu Y, Chung S-H, Zu C, Su Y-S (2014) Rechargeable lithium-sulfur batteries. Chem Rev 114:11751–11787
Yang Y, Zheng GY, Cui Y (2013) Nanostructured sulfur cathodes. Chem Soc Rev 42:3018–3032
Zhang J, Huang H, Bae J, Chung SH, Zhang WK, Manthiram A, Yu GH (2018) Nanostructured host materials for trapping sulfur in rechargeable Li-S batteries: structure design and interfacial chemistry. Small Methods:2, Unsp 1700279
Peng HJ, Huang JQ, Cheng XB, Zhang Q (2017) Review on High-loading and high-energy lithium-sulfur batteries. Adv Energy Mater 7:1700260
Yuan H, Peng H-J, Huang J-Q, Zhang Q (2019) Sulfur Redox reactions at working interfaces in lithium-sulfur batteries: a perspective. Adv Mater Interf:6
Zheng GY, Yang Y, Cha JJ, Hong SS, Cui Y (2011) Hollow carbon nanofiber-encapsulated sulfur cathodes for high specific capacity rechargeable lithium batteries. Nano Lett 11:4462–4467
Evers S, Nazar LF (2013) New approaches for high energy density lithium-sulfur battery cathodes. Acc Chem Res 46:1135–1143
Yuan Z, Peng HJ, Hou TZ, Huang JQ, Chen CM, Wang DW, Cheng XB, Wei F, Zhang Q (2016) Powering lithium-sulfur battery performance by propelling polysulfide redox at sulfiphilic hosts. Nano Lett 16:519–527
Song JX, Yu ZX, Gordin ML, Wang DH (2016) Advanced sulfur cathode enabled by highly crumpled nitrogen-doped graphene sheets for high-energy-density lithium-sulfur batteries. Nano Lett 16:864–870
Zhou GM, Li L, Ma CQ, Wang SG, Shi Y, Koratkar N, Ren WC, Li F, Cheng HM (2015) A graphene foam electrode with high sulfur loading for flexible and high energy Li-S batteries. Nano Energy 11:356–365
Li F, Kaiser MR, Ma JM, Guo ZP, Liu HK, Wang JZ (2018) Free-standing sulfur-polypyrrole cathode in conjunction with polypyrrole-coated separator for flexible Li-S batteries. Energy Storage Mater 13:312–322
Chen K, Cao J, Lu QQ, Wang QR, Yao MJ, Han MM, Niu ZQ, Chen J (2018) Sulfur nanoparticles encapsulated in reduced graphene oxide nanotubes for flexible lithium-sulfur batteries. Nano Res 11:1345–1357
Wu H, Zhuo D, Kong DS, Cui Y (2014) Improving battery safety by early detection of internal shorting with a bifunctional separator. Nat Commun 5
Cheng XB, Peng HJ, Huang JQ, Zhang R, Zhao CZ, Zhang Q (2015) Dual-phase lithium metal anode containing a polysulfide-induced solid electrolyte interphase and nanostructured graphene framework for lithium-sulfur batteries. ACS Nano 9:6373–6382
Xu ZL, Fan ML, Wang JJ, Zhang FF, Lin WR, Zhang HN (2020) Trace iron-decorated nitrogen/sulfur co-doped hierarchically porous carbon for oxygen reduction and lithium-sulfur batteries. ACS Appl Energy Mater 3:2719–2726
Yu ZS, Liu ML, Guo DY, Wang JH, Chen X, Li J, Jin HL, Yang Z, Chen X, Wang S (2020) Radially inwardly aligned hierarchical porous carbon for ultra-long-life lithium-sulfur batteries. Angew Chem Int Ed 59:6406–6411
Ren M, Lu X, Chai Y, Zhou X, Ren J, Zheng Q, Lin D (2019) A three-dimensional conductive cross-linked all-carbon network hybrid as a sulfur host for high performance lithium-sulfur batteries. J Colloid Interf Sci 552:91–100
Cao J, Chen C, Zhao Q, Zhang N, Lu QQ, Wang XY, Niu ZQ, Chen J (2016) A flexible nanostructured paper of a reduced graphene oxide-sulfur composite for high-performance lithium-sulfur batteries with unconventional con. Adv Mater 28:9629-+
Wang R, Yang J, Chen X, Zhao Y, Zhao W, Qian G, Li S, Xiao Y, Chen H, Ye Y, Zhou G, Pan F (2020) Highly dispersed cobalt clusters in nitrogen-doped porous carbon enable multiple effects for high-performance Li–S battery. Adv Energy Mater 10:1903550
Jin J, Cai W, Cai J, Shao Y, Song Y, Xia Z, Zhang Q, Sun J (2020) MOF-derived hierarchical CoP nanoflakes anchored on vertically erected graphene scaffolds as self-supported and flexible hosts for lithium–sulfur batteries. J Mater Chem A 8:3027–3034
Mei C, Jianhui Z, Ouwei S, Chengbin J, Huadong Y, Tiefeng L, Yujing L, Yao W, Jianwei N, Xinyong T (2019) Sulfur–nitrogen co-doped porous carbon nanosheets to control lithium growth for a stable lithium metal anode†. J Mater Chem A 7:18267–18274
Mengdi Z, Chang YU, Juan Y, Changtai Z, Zheng L, Jieshan Q (2017) Nitrogen-doped tubular/porous carbon channels implanted on graphene frameworks for multiple confinement of sulfur and polysulfides. J Mater Chem A 5:10380–10386
Wei A, Weiwei Z, Zhuzhu D, Yu C, Zhipeng S, Chao W, Chenji Z, Changming L, Wei H, Ting Y (2016) Nitrogen and phosphorus codoped hierarchically porous carbon as an efficient sulfur host for Li-S batteries. Energy Storage Mater 6:112–118
Yazhou W, Meng L, Lichun X, Tianyu T, Zeeshan A, Xiaoxiao H, Yanglong H, Shanqing Z (2018) Polar and conductive iron carbide@N-doped porous carbon nanosheets as a sulfur host for high performance lithium sulfur batteries. Chem Eng J 358:962–968
Wei D, Xufeng Z, Qile F, Zhaoping L (2017) Bifunctional hierarchical porous carbon network integrated with in-situ formed ultrathin graphene shell for stable lithium-sulfur battery. J Mater Chem A 5:13674–13682
Wang HL, Yang Y, Liang YY, Robinson JT, Li YG, Jackson A, Cui Y, Dai HJ (2011) Graphene-wrapped sulfur particles as a rechargeable lithium-sulfur battery cathode material with high capacity and cycling stability. Nano Lett 11:2644–2647
Li-Chang Y, Ji L, Guang-Min Z, Feng L, Riichiro S, Hui-Ming C (2016) Understanding the interactions between lithium polysulfides and N-doped graphene using density functional theory calculations. Nano Energy 25:203–210
Linlin Z, Daobin L, Zahir M, Fang W, Wei X, Yijing W, Li S, Zhiqiang N, Jun C (2019) Single nickel atoms on nitrogen-doped graphene enabling enhanced kinetics of lithium-sulfur batteries. Adv Mater 31:1903955
Weiwei S, Yanjun X, Xiudong C, Yi X, Fan W, Yong W (2019) Reduced graphene oxide modified with naphthoquinone for effective immobilization of polysulfides in high-performance Li-S batteries. Chem Eng J 383:123111
Yongzheng Z, Xia G, Qi K, Zhenkai K, Yanli W, Liang Z (2020) Vanadium oxide nanorods embed in porous graphene aerogel as high-efficiency polysulfide-trapping-conversion mediator for high performance lithium-sulfur batteries. Chem Eng J 393:124570
Zhao Y, Wu WL, Li JX, Xu ZC, Guan LH (2014) Encapsulating MWNTs into hollow porous carbon nanotubes: a tube-in-tube carbon nanostructure for high-performance lithium-sulfur batteries. Adv Mater 26:5113–5118
Raghunandan U, Martin F, Tony J, Juan B, Steffen O, Rafał N, Natalia S, Ivan K, Mark HR, Lars G (2017) Lightweight, free-standing 3D interconnected carbon nanotube foam as a flexible sulfur host for high performance lithium-sulfur battery cathodes. Energy Storage Mater 10:206–215
Ruopian F, Guoxian L, Shiyong Z, Lichang Y, Kui D, Pengxiang H, Shaogang W, Hui-Ming C, Chang L, Feng L (2017) Single-wall carbon nanotube network enabled ultrahigh sulfur-content electrodes for high-performance lithium-sulfur batteries. Nano Energy 42:205–214
Guangmin Z, Da-Wei W, Feng L, Peng-Xiang H, Lichang Y, Chang L, Gao Qing L, Ian RG, Hui-Ming C (2012) A flexible nanostructured sulphur–carbon nanotube cathode with high rate performance for Li-S batteries†. Energy Environ Sci 5:8901–8906
Zhang CF, Wu HB, Yuan CZ, Guo ZP, Lou XW (2012) Confining sulfur in double-shelled hollow carbon spheres for lithium-sulfur batteries. Angew Chem Int Ed 51:9592–9595
Zhu L, Peng HJ, Liang JY, Huang JQ, Chen CM, Guo XF, Zhu WC, Li P, Zhang Q (2015) Interconnected carbon nanotube/graphene nanosphere scaffolds as free-standing paper electrode for high-rate and ultra-stable lithium-sulfur batteries. Nano Energy 11:746–755
Wang T, Zhu J, Wei Z, Yang H, Ma Z, Ma R, Zhou J, Yang Y, Peng L, Fei H, Lu B, Duan X (2019) Bacteria-derived biological carbon building robust Li-S batteries. Nano Lett 19:4384–4390
Yu M, Li R, Tong Y, Li Y, Li C, Hong J-D, Shi G (2015) A graphene wrapped hair-derived carbon/sulfur composite for lithium–sulfur batteries. J Mater Chem A 3:9609–9615
Wu W, Pu J, Wang J, Shen Z, Tang H, Deng Z, Tao X, Pan F, Zhang H (2018) Biomimetic bipolar microcapsules derived from Staphylococcus aureus for enhanced properties of lithium-sulfur battery cathodes. Adv Energy Mater:8
Luo C, Zhu HL, Luo W, Shen F, Fan XL, Dai JQ, Liang YJ, Wang CS, Hu LB (2017) Atomic-layer-deposition functionalized carbonized mesoporous wood fiber for high sulfur loading lithium sulfur batteries. ACS Appl Mater Interfaces 9:14801–14807
Li Q, Liu Y, Wang Y, Chen Y, Guo X, Wu Z, Zhong B (2020) Review of the application of biomass-derived porous carbon in lithium-sulfur batteries. Ionics
Bhargav A, He J, Gupta A, Manthiram A (2020) Lithium-sulfur batteries: attaining the critical metrics. Joule 4:285–291
Cai D, Lu M, Li, Cao J, Chen D, Tu H, Li J, Han W (2019) A highly conductive MOF of graphene analogue Ni3 (HITP)2 as a sulfur host for high-performance lithium-sulfur batteries. Small 15:e1902605
Park J, Lee M, Feng DW, Huang ZH, Hinckley AC, Yakoyenko A, Zou XD, Cui Y, Bao ZA (2018) Stabilization of hexaaminobenzene in a 2D conductive metal-organic framework for high power sodium storage. J Am Chem Soc 140:10315–10323
Aubrey ML, Wiers BM, Andrews SC, Sakurai T, Reyes-Lillo SE, Hamed SM, Yu CJ, Darago LE, Mason JA, Baeg JO, Grandjean F, Long GJ, Seki S, Neaton JB, Yang PD, Long JR (2018) Electron delocalization and charge mobility as a function of reduction in a metal-organic framework. Nat Mater 17:625-+
Xin S, Gu L, Zhao NH, Yin YX, Zhou LJ, Guo YG, Wan LJ (2012) Smaller sulfur molecules promise better lithium-sulfur batteries. J Am Chem Soc 134:18510–18513
Zhou J, Yu X, Fan X, Wang X, Li H, Zhang Y, Li W, Zheng J, Wang B, Li X (2015) The impact of the particle size of a metal-organic framework for sulfur storage in Li-S batteries. J Mater Chem A 3:8272–8275
Jiang H, Liu X-C, Wu Y, Shu Y, Gong X, Ke F-S, Deng H (2018) Metal-organic frameworks for high charge-discharge rates in lithium-sulfur batteries. Angew Chem 130:3980–3985
Li ML, Wan Y, Huang JK, Assen AH, Hsiung CE, Jiang H, Han Y, Eddaoudi M, Lai ZP, Ming J, Li LJ (2017) Metal-organic framework-based separators for enhancing Li-S battery stability: mechanism of mitigating polysulfide diffusion. ACS Energy Lett 2:2362–2367
Demir-Cakan R, Morcrette M, Nouar F, Davoisne C, Devic T, Gonbeau D, Dominko R, Serre C, Ferey G, Tarascon J-M (2011) Cathode composites for Li-S batteries via the use of oxygenated porous architectures. J Am Chem Soc 133:16154–16160
Zhou J, Li R, Fan X, Chen Y, Han R, Li W, Zheng J, Wang B, Li X (2014) Rational design of a metal-organic framework host for sulfur storage in fast, long-cycle Li-S batteries. Energy Environ Sci 7:2715–2724
Wang Z, Dou Z, Cui Y, Yang Y, Wang Z, Qian G (2014) Sulfur encapsulated ZIF-8 as cathode material for lithium-sulfur battery with improved cyclability. Microporous Mesoporous Mater 185:92–96
Baumann AE, Aversa GE, Roy A, Falk ML, Bedford NM, Thoi VS (2018) Promoting sulfur adsorption using surface Cu sites in metal-organic frameworks for lithium sulfur batteries. J Mater Chem A 6:4811–4821
Kaiser MR, Ma ZH, Wang XW, Han FD, Gao T, Fan XL, Wang JZ, Liu HK, Dou SX, Wang CS (2017) Reverse microemulsion synthesis of sulfur/graphene composite for lithium/sulfur batteries. ACS Nano 11:9048–9056
Qiu YC, Li WF, Zhao W, Li GZ, Hou Y, Liu MN, Zhou LS, Ye FM, Li HF, Wei ZH, Yang SH, Duan WH, Ye YF, Guo JH, Zhang YG (2014) High-rate, ultra long cycle-life lithium/sulfur batteries enabled by nitrogen-doped graphene. Nano Lett 14:4821–4827
Luo C, Zhu YJ, Borodin O, Gao T, Fan XL, Xu YH, Xu K, Wang CS (2016) Activation of Oxygen-Stabilized Sulfur for Li and Na Batteries. Adv Funct Mater 26:745–752
Zhou WD, Yu YC, Chen H, DiSalvo FJ, Abruna HD (2013) Yolk-shell structure of polyaniline-coated sulfur for lithium-sulfur batteries. J Am Chem Soc 135:16736–16743
Wang JK, Yue KQ, Zhu XD, Wang KL, Duan LF (2016) C-S@PANI composite with a polymer spherical network structure for high performance lithium-sulfur batteries. Phys Chem Chem Phys 18:261–266
Xiao LF, Cao YL, Xiao J, Schwenzer B, Engelhard MH, Saraf LV, Nie ZM, Exarhos GJ, Liu J (2012) A soft approach to encapsulate sulfur: polyaniline nanotubes for lithium-sulfur batteries with long cycle life. Adv Mater 24:1176–1181
Yin LC, Wang JL, Yang J, Nuli YN (2011) A novel pyrolyzed polyacrylonitrile-sulfur@MWCNT composite cathode material for high-rate rechargeable lithium/sulfur batteries. J Mater Chem 21:6807–6810
Yin LC, Wang JL, Lin FJ, Yang J, Nuli Y (2012) Polyacrylonitrile/graphene composite as a precursor to a sulfur-based cathode material for high-rate rechargeable Li-S batteries. Energy Environ Sci 5:6966–6972
Wang J, Chen J, Konstantinov K, Zhao L, Ng SH, Wang GX, Guo ZP, Liu HK (2006) Sulphur-polypyrrole composite positive electrode materials for rechargeable lithium batteries. Electrochim Acta 51:4634–4638
Fu YZ, Manthiram A (2012) Orthorhombic bipyramidal sulfur coated with polypyrrole nanolayers as a cathode material for lithium-sulfur batteries. J Phys Chem C 116:8910–8915
Wu F, Chen JZ, Chen RJ, Wu SX, Li L, Chen S, Zhao T (2011) Sulfur/polythiophene with a core/shell structure: synthesis and electrochemical properties of the cathode for rechargeable lithium batteries. J Phys Chem C 115:6057–6063
Li WY, Zhang QF, Zheng GY, Seh ZW, Yao HB, Cui Y (2013) Understanding the role of different conductive polymers in improving the nanostructured sulfur cathode performance. Nano Lett 13:5534–5540
Zheng J, Tian J, Wu D, Gu M, Xu W, Wang C, Gao F, Engelhard MH, Zhang J-G, Liu J, Xiao J (2014) Lewis acid-base interactions between polysulfides and metal organic framework in lithium sulfur batteries. Nano Lett 14:2345–2352
Tang H, Li W, Pan L, Tu K, Du F, Qiu T, Yang J, Cullen CP, McEvoy N, Zhang C (2019) A robust, freestanding MXene-sulfur conductive paper for long-lifetime Li–S batteries. Adv Funct Mater 29:1901907
Wang Z, Wang B, Yang Y, Cui Y, Wang Z, Chen B, Qian G (2015) Mixed-metal-organic framework with effective Lewis acidic sites for sulfur confinement in high-performance lithium-sulfur batteries. ACS Appl Mater Interfaces 7:20999–21004
Wang Z, Li X, Cui Y, Yang Y, Pan H, Wang Z, Wu C, Chen B, Qian G (2013) A metal-organic framework with open metal sites for enhanced confinement of sulfur and lithium-sulfur battery of long cycling life. Cryst Growth Des 13:5116–5120
Zhang Z, An Y, Feng J, Ci L, Duan B, Huang W, Dong C, Xiong S (2016) Carbon coated copper sulfides nanosheets synthesized via directly sulfurizing metal-organic frameworks for lithium batteries. Mater Lett 181:340–344
Hong X-J, Tan T-X, Guo Y-K, Tang X-Y, Wang J-Y, Qin W, Cai Y-P (2018) Confinement of polysulfides within bi-functional metal-organic frameworks for high performance lithium-sulfur batteries. Nanoscale 10:2774–2780
Hou Y, Mao H, Xu L (2017) MIL-100(V) and MIL-100(V)/rGO with various valence states of vanadium ions as sulfur cathode hosts for lithium-sulfur batteries. Nano Res 10:344–353
Park H, Siegel DJ (2017) Tuning the Adsorption of polysulfides in lithium-sulfur batteries with metal-organic frameworks. Chem Mater 29:4932–4939
Jiang GY, Zheng N, Chen X, Ding GY, Li YH, Sun FG, Li YS (2019) In-situ decoration of MOF-derived carbon on nitrogen-doped ultrathin MXene nanosheets to multifunctionalize separators for stable Li-S batteries. Chem Eng J 373:1309–1318
Zhao YM, Zhao JX (2017) Functional group-dependent anchoring effect of titanium carbide-based MXenes for lithium-sulfur batteries: a computational study. Appl Surf Sci 412:591–598
Wang DS, Li F, Lian RQ, Xu J, Kan DX, Liu YH, Chen G, Gogotsi Y, Wei YJ (2019) A general atomic surface modification strategy for improving anchoring and electrocatalysis behavior of Ti3C2T2 MXene in lithium-sulfur batteries. ACS Nano 13:11078–11086
Zhang CF, Anasori B, Seral-Ascaso A, Park SH, McEvoy N, Shmeliov A, Duesberg GS, Coleman JN, Gogotsi Y, Nicolosi V (2017) Transparent, flexible, and conductive 2D titanium carbide (MXene) films with high volumetric capacitance. Adv Mater 29:1702678
Li N, Meng QQ, Zhu XH, Li Z, Ma JL, Huang CX, Song J, Fan J (2019) Lattice constant-dependent anchoring effect of MXenes for lithium-sulfur (Li-S) batteries: a DFT study. Nanoscale 11:8485–8493
Bao WZ, Su DW, Zhang WX, Guo X, Wang GX (2016) 3D metal carbide@mesoporous carbon hybrid architecture as a new polysulfide reservoir for lithium-sulfur batteries. Adv Funct Mater 26:8746–8756
Lee JT, Zhao YY, Thieme S, Kim H, Oschatz M, Borchardt L, Magasinski A, Cho WI, Kaskel S, Yushin G (2013) Sulfur-infiltrated micro- and mesoporous silicon carbide-derived carbon cathode for high-performance lithium sulfur batteries. Adv Mater 25:4573–4579
Cui ZM, Zu CX, Zhou WD, Manthiram A, Goodenough JB (2016) Mesoporous titanium nitride-enabled highly stable lithium-sulfur batteries. Adv Mater 28:6926-+
Zhou GM, Zhao YB, Manthiram A (2015) Dual-confined flexible sulfur cathodes encapsulated in nitrogen-doped double-shelled hollow carbon spheres and wrapped with graphene for Li-S batteries. Adv Energy Mater 5:1402263
Song JX, Gordin ML, Xu T, Chen SR, Yu ZX, Sohn H, Lu J, Ren Y, Duan YH, Wang DH (2015) Strong lithium polysulfide chemisorption on electroactive sites of nitrogen-doped carbon composites for high-performance lithium-sulfur battery cathodes. Angew Chem Int Ed 54:4325–4329
Xia G, Su J, Li M, Jiang P, Yang Y, Chen Q (2017) A MOF-derived self-template strategy toward cobalt phosphide electrodes with ultralong cycle life and high capacity. J Mater Chem A 5:10321–10327
Deng WN, Hu AP, Chen XH, Zhang SY, Tang QL, Liu Z, Fan BB, Xiao KK (2016) Sulfur-impregnated 3D hierarchical porous nitrogen-doped aligned carbon nanotubes as high-performance cathode for lithium-sulfur batteries. J Power Sources 322:138–146
Yang CP, Yin YX, Ye H, Jiang KC, Zhang J, Guo YG (2014) Insight into the effect of boron doping on sulfur/carbon cathode in lithium-sulfur batteries. ACS Appl Mater Interfaces 6:8789–8795
Wang JL, Yan XF, Zhang Z, Ying HJ, Guo RN, Yang WT, Han WQ (2019) Facile preparation of high-content N-doped CNT microspheres for high-performance lithium storage. Adv Funct Mater 29:1904819
Sun FG, Wang JT, Chen HC, Li WC, Qiao WM, Long DH, Ling LC (2013) High efficiency immobilization of sulfur on nitrogen-enriched mesoporous carbons for Li-S batteries. ACS Appl Mater Interfaces 5:5630–5638
Wu F, Li J, Tian YF, Su YF, Wang J, Yang W, Li N, Chen S, Bao LY (2015) 3D coral-like nitrogen-sulfur co-doped carbon-sulfur composite for high performance lithium-sulfur batteries. Sci Rep 5:13340
Wang XW, Gao T, Fan XL, Han FD, Wu YQ, Zhang ZA, Li J, Wang CS (2016) Tailoring surface acidity of metal oxide for better polysulfide entrapment in Li-S batteries. Adv Funct Mater 26:7164–7169
Song MS, Han SC, Kim HS, Kim JH, Kim KT, Kang YM, Ahn HJ, Dou SX, Lee JY (2004) Effects of nanosized adsorbing material on electrochemical properties of sulfur cathodes for Li/S secondary batteries. J Electrochem Soc 151:A791–A795
Choi YJ, Jung BS, Lee DJ, Jeong JH, Kim KW, Ahn HJ, Cho KK, Gu HB (2007) Electrochemical properties of sulfur electrode containing nano Al2O3 for lithium/sulfur cell. Phys Scr T129:62–65
Ji XL, Evers S, Black R, Nazar LF (2011) Stabilizing lithium-sulphur cathodes using polysulphide reservoirs. Nat Commun 2:325
Seh ZW, Li WY, Cha JJ, Zheng GY, Yang Y, McDowell MT, Hsu PC, Cui Y (2013) fSulphur-TiO2 yolk-shell nanoarchitecture with internal void space for long-cycle lithium-sulphur batteries. Nat Commun 4:1331
Lei T, Chen W, Huang J, Yan C, Sun H, Wang C, Zhang W, Li Y, Xiong J (2017) Multi-functional layered WS2 nanosheets for enhancing the performance of lithium-sulfur batteries. Adv Energy Mater 7:1601843
Pang Q, Kundu D, Nazar LF (2016) A graphene-like metallic cathode host for long-life and high-loading lithium–sulfur batteries. Mater Horizons 3:130–136
Li R, Peng H, Wu Q, Zhou X, He J, Shen H, Yang M, Li C (2020) Sandwich-like catalyst–carbon–catalyst trilayer structure as a compact 2D host for highly stable lithium–sulfur batteries. Angew Chem Int Ed 59:12129–12138
Fan Q, Liu W, Weng Z, Sun YM, Wang HL (2015) Ternary hybrid material for high-performance lithium-sulfur battery. J Am Chem Soc 137:12946–12953
Hu L, Dai C, Liu H, Li Y, Shen B, Chen Y, Bao S-J, Xu M (2018) Double-shelled NiO-NiCo2O4 heterostructure@carbon hollow nanocages as an efficient sulfur host for advanced lithium-sulfur batteries. Adv Energy Mater 8:1800709
Qu QT, Gao T, Zheng HY, Wang Y, Li XY, Li XX, Chen JM, Han YY, Shao J, Zheng HH (2015) Strong surface-bound sulfur in conductive MoO2 Matrix for enhancing Li-S battery performance. Adv Mater Interfaces 2:1500048
Wang Y, Feng G, Wang Y, Wu Z, Chen Y, Guo X, Zhong B (2020) MoO2 nanoparticles embedded in N-doped hydrangea-like carbon as a sulfur host for high-performance lithium–sulfur batteries. RSC Adv 10:20173–20183
Sun FG, Wang JT, Long DH, Qiao WM, Ling LC, Lv CX, Cai R (2013) A high-rate lithium–sulfur battery assisted by nitrogen-enriched mesoporous carbons decorated with ultrafine La2O3 nanoparticles. J Mater Chem A 1:13283–13289
Evers S, Yim T, Nazar LF (2012) Understanding the nature of absorption/adsorption in nanoporous polysulfide sorbents for the Li–S battery. J Phys Chem C 116:19653–19658
Hu NN, Lv XS, Dai Y, Fan LL, Xiong DB, Li XF (2018) SnO2/reduced graphene oxide interlayer mitigating the shuttle effect of Li-S batteries. ACS Appl Mater Interfaces 10:18665–18674
Cheng H, Wang SP, Tao D, Wang M (2014) Sulfur/Co3O4 nanotube composite with high performances as cathode materials for lithium sulfur batteries. Funct Mater Lett 7:1450020
Lin H, Zhang S, Zhang T, Ye H, Yao Q, Zheng GW, Lee JY (2018) Elucidating the catalytic activity of oxygen deficiency in the polysulfide conversion reactions of lithium-sulfur batteries. Adv Energy Mater 8:1801868
Yang W, Xiao J, Ma Y, Cui S, Zhang P, Zhai P, Meng L, Wang X, Wei Y, Du Z, Li B, Sun Z, Yang S, Zhang Q, Gong Y (2018) Tin intercalated ultrathin MoO3 nanoribbons for advanced lithium-sulfur batteries. Adv Energy Mater:1803137
Zhu M, Li S, Liu J, Li B (2019) Promoting polysulfide conversion by V2O3 hollow sphere for enhanced lithium-sulfur battery. Appl Surf Sci 473:1002–1008
Ponraj R, Kannan AG, Ahn JH, Kim DW (2016) Improvement of cycling performance of lithium-sulfur batteries by using magnesium oxide as a functional additive for trapping lithium polysulfide. ACS Appl Mater Interfaces 8:4000–4006
Ma L, Chen R, Zhu G, Hu Y, Wang Y, Chen T, Liu J, Jin Z (2017) Cerium oxide nanocrystal embedded bimodal micromesoporous nitrogen-rich carbon nanospheres as effective sulfur host for lithium-sulfur batteries. ACS Nano 11:7274–7283
Zhang J, Gu P, Xu J, Xue HG, Pang H (2016) High performance of electrochemical lithium storage batteries: ZnO-based nanomaterials for lithium-ion and lithium-sulfur batteries. Nanoscale 8:18578–18595
Gu XX, Tong CJ, Wen B, Liu LM, Lai C, Zhang SQ (2016) Ball-milling synthesis of ZnO@sulphur/carbon nanotubes and Ni (OH)(2)@sulphur/carbon nanotubes composites for high-performance lithium-sulphur batteries. Electrochim Acta 196:369–376
Li X, Lu Y, Hou Z, Zhang W, Zhu Y, Qian Y, Liang J, Qian Y (2016) SnS2- compared to SnO2-stabilized S/C composites toward high-performance lithium sulfur batteries. ACS Appl Mater Interfaces 8:19550–19557
Ma L, Wei SY, Zhuang HLL, Hendrickson KE, Hennig RG, Archer LA (2015) Hybrid cathode architectures for lithium batteries based on TiS2 and sulfur. J Mater Chem A 3:19857–19866
Xiao D, Li Q, Zhang H, Ma Y, Lu C, Chen C, Liu Y, Yuan S (2017) A sulfur host based on cobalt-graphitic carbon nanocages for high performance lithium-sulfur batteries. J Mater Chem A 5:24901–24908
Yang M, Hu X, Fang Z, Sun L, Yuan Z, Wang S, Hong W, Chen X, Yu D (2017) Bifunctional MOF-derived carbon photonic crystal architectures for advanced Zn-Air and Li-S batteries: highly exposed graphitic nitrogen matters. Adv Funct Mater 27:1701971
Cai J, Song Y, Chen X, Sun Z, Yi Y, Sun J, Zhang Q (2020) MOF-derived conductive carbon nitrides for separator-modified Li–S batteries and flexible supercapacitors. J Mater Chem A 8:1757–1766
Cui GL, Li GR, Luo D, Zhang YG, Zhao Y, Wang DR, Wang JY, Zhang Z, Wang X, Chen ZW (2020) Three-dimensionally ordered macro-microporous metal organic frameworks with strong sulfur immobilization and catalyzation for high-performance lithium-sulfur batteries. Nano Energy 72:104685
Zhang J, Yu L, Lou XW (2017) Embedding CoS2 nanoparticles in N-doped carbon nanotube hollow frameworks for enhanced lithium storage properties. Nano Res 10:4298–4304
Jiang Y, Liu H, Tan X, Guo L, Zhang J, Liu S, Guo Y, Zhang J, Wang H, Chu W (2017) Monoclinic ZIF-8 nanosheet-derived 2D Carbon nanosheets as sulfur immobilizer for high-performance lithium sulfur batteries. ACS Appl Mater Interfaces 9:25239–25249
Zhou S, Liu J, Xie F, Zhao Y, Mei T, Wang Z, Wang X (2020) A “boxes in fibers” strategy to construct a necklace-like conductive network for the high-rate and high-loading lithium-sulfur batteries. J Mater Chem A 8:11327–11336
Guan L, Hu H, Li L, Pan Y, Zhu Y, Li Q, Guo H, Wang K, Huang Y, Zhang M, Yan Y, Li Z, Teng X, Yang J, Xiao J, Zhang Y, Wang X, Wu M (2020) Intrinsic defect-rich hierarchically porous carbon architectures enabling enhanced capture and catalytic conversion of polysulfides. ACS Nano 14:6222–6231
Xie J, Li BQ, Peng HJ, Song YW, Zhao M, Chen X, Zhang Q, Huang JQ (2019) Implanting atomic cobalt within mesoporous carbon toward highly stable lithium-sulfur batteries. Adv Mater 31:1903813
Zhou G, Zhao S, Wang T, Yang SZ, Johannessen B, Chen H, Liu C, Ye Y, Wu Y, Peng Y, Liu C, Jiang SP, Zhang Q, Cui Y (2020) Theoretical calculation guided design of single-atom catalysts toward fast kinetic and long-life Li-S batteries. Nano Lett 20:1252–1261
Zhang LL, Liu DB, Muhammad Z, Wan F, Xie W, Wang YJ, Song L, Niu ZQ, Chen J (2019) Single nickel atoms on nitrogen-doped graphene enabling enhanced kinetics of lithium-sulfur batteries. Adv Mater 31:1903955
He YS, Li MJ, Zhang YG, Shan ZZ, Zhao Y, Li JD, Liu GH, Liang CY, Bakenov Z, Li Q (2020) All-purpose electrode design of flexible conductive scaffold toward high-performance Li-S batteries. Adv Funct Mater 30:2000613
Luo L, Li J, Yaghoobnejad Asl H, Manthiram A (2020) In-situ assembled VS4 as a polysulfide mediator for high-loading lithium–sulfur batteries. ACS Energy Lett 5:1177–1185
He J, Bhargav A, Yaghoobnejad Asl H, Chen Y, Manthiram A (2020) 1T′-ReS2 Nanosheets in situ grown on carbon nanotubes as a highly efficient polysulfide electrocatalyst for stable Li–S batteries. Adv Energy Mater 10:2001017
Wu X, Liu N, Wang M, Qiu Y, Guan B, Tian D, Guo Z, Fan L, Zhang N (2019) A class of catalysts of BiOX (X = Cl, Br, I) for Anchoring polysulfides and accelerating redox reaction in lithium sulfur batteries. ACS Nano 13:13109–13115
Shen Z, Zhang Z, Li M, Yuan Y, Zhao Y, Zhang S, Zhong C, Zhu J, Lu J, Zhang H (2020) Rational design of a Ni3N0.85 Electrocatalyst to accelerate polysulfide conversion in lithium-sulfur batteries. ACS Nano 14:6673–6682
Yuan H, Peng HJ, Li BQ, Xie J, Kong L, Zhao M, Chen X, Huang JQ, Zhang Q (2019) Conductive and catalytic triple-phase interfaces enabling uniform nucleation in high-rate lithium-sulfur batteries. Adv Energy Mater 9:1802768
Cai D, Liu BK, Zhu DH, Chen D, Lu MJ, Cao JM, Wang YH, Huang WH, Shao Y, Tu HR, Han W (2020) Ultrafine Co3Se4 nanoparticles in nitrogen-doped 3D carbon matrix for high-stable and long-cycle-life lithium sulfur batteries. Adv Energy Mater 10:1904273
Zhao YY, Cai WL, Fang YT, Ao HS, Zhu YC, Qian YT (2019) Sulfur-deficient TiS2-x for promoted polysulfide redox conversion in lithium-sulfur batteries. Chemelectrochem 6:2231–2237
Luo D, Zhang Z, Li GR, Cheng SB, Li S, Li JD, Gao R, Li M, Sy S, Deng YP, Jiang Y, Zhu YF, Dou HZ, Hu YF, Yu AP, Chen ZW (2020) Revealing the rapid electrocatalytic behavior of ultrafine amorphous defective Nb2O5-x nanocluster toward superior Li-S performance. ACS Nano 14:4849–4860
Lv KZ, Wang PF, Wang C, Shen ZH, Lu ZD, Zhang HG, Zheng MB, He P, Zhou HS (2020) Oxygen-deficient ferric oxide as an electrochemical cathode catalyst for high-energy lithium-sulfur batteries. Small 16:2000870
Zhang Y, Li G, Wang J, Cui G, Wei X, Shui L, Kempa K, Zhou G, Wang X, Chen Z (2020) Hierarchical defective Fe3-xC@C hollow microsphere enables fast and long-lasting lithium-sulfur batteries. Adv Funct Mater 30:2001165
Wang N, Chen B, Qin KQ, Liu EZ, Shi CS, He CN, Zhao NQ (2019) Rational design of Co9S8/CoO heterostructures with well-defined interfaces for lithium sulfur batteries: a study of synergistic adsorption-electrocatalysis function. Nano Energy 60:332–339
Bhoyate S, Kim J, Lee E, Park B, Lee E, Park J, Oh SH, Kim J, Choi W (2020) Mixed phase 2D Mo0.5W0.5S2 alloy as multi-functional electrocatalyst for the high-performance cathode in Li-S batteries. J Mater Chem A
Zhao M, Peng HJ, Li BQ, Chen X, Xie J, Liu X, Zhang Q, Huang JQ (2020) Electrochemical phase evolution of metal-based pre-catalysts for high-rate polysulfide conversion. Angew Chem Int Ed Eng 59:9011–9017
Cheng Z, Xiao Z, Pan H, Wang S, Wang R (2018) Elastic sandwich-type rGO-VS2/S composites with high tap density: structural and chemical cooperativity enabling lithium-sulfur batteries with high energy density. Adv Energy Mater 8:1702337
Wu WY, Chakrabortty S, Chang CKL, Guchhait A, Lin M, Chan Y (2014) Promoting 2D growth in colloidal transition metal sulfide semiconductor nanostructures via halide ions. Chem Mater 26:6120–6126
Boyjoo Y, Shi HD, Olsson E, Cai Q, Wu ZS, Liu J, Lu GQ (2020) Molecular-level design of pyrrhotite electrocatalyst decorated hierarchical porous carbon spheres as nanoreactors for lithium-sulfur batteries. Adv Energy Mater 10:2000651
Jin ZS, Zhao M, Lin TN, Liu BQ, Zhang Q, Zhang LY, Chen LH, Li L, Su ZM, Wang CG (2020) Rational design of well-dispersed ultrafine CoS2 nanocrystals in micro-mesoporous carbon spheres with a synergistic effect for high-performance lithium-sulfur batteries. J Mater Chem A 8:10885–10890
Yu J, Xiao JW, Li AR, Yang Z, Zeng L, Zhang QF, Zhu YJ, Guo L (2020) Enhanced multiple anchoring and catalytic conversion of polysulfides by amorphous MoS3 nanoboxes for high-performance Li-S batteries. Angew Chem Int Ed
Xu HH, Manthiram A (2017) Hollow cobalt sulfide polyhedra-enabled long-life, high areal-capacity lithium-sulfur batteries. Nano Energy 33:124–129
Jin Z, Liang Z, Zhao M, Zhang Q, Liu B, Zhang L, Chen L, Li L, Wang C (2020) Rational design of MoNi sulfide yolk-shell heterostructure nanospheres as the efficient sulfur hosts for high-performance lithium-sulfur batteries. Chem Eng J 394:124983
Guo D, Zhang Z, Xi B, Yu Z, Zhou Z, Chen X a (2020) Ni3S2 anchored to N/S co-doped reduced graphene oxide with highly pleated structure as a sulfur host for lithium–sulfur batteries. J Mater Chem A 8:3834–3844
Xiao ZB, Yang Z, Zhang LJ, Pan H, Wang RH (2017) Sandwich-type NbS2@S@I-doped graphene for high-sulfur-loaded, ultrahigh-rate, and long-life lithium sulfur batteries. ACS Nano 11:8488–8498
Chang Z, Dou H, Ding B, Wang J, Wang Y, Hao XD, MacFarlane DR (2017) Co3O4 nanoneedle arrays as a multifunctional “super-reservoir” electrode for long cycle life Li-S batteries. J Mater Chem A 5:250–257
He JR, Luo L, Chen YF, Manthiram A (2017) Yolk-shelled C@Fe3O4 nanoboxes as efficient sulfur hosts for high-performance lithium-sulfur batteries. Adv Mater:29
Ma LB, Chen RP, Zhu GY, Hu Y, Wang YR, Chen T, Liu J, Jin Z (2017) Cerium oxide nanocrystal embedded bimodal microniesoporous nitrogen-rich carbon nanospheres as effective sulfur host for lithium-sulfur batteries. ACS Nano 11:7274–7283
Yao L, Dong XW, Zhang CR, Hu NT, Zhang YF (2018) Metal oxide nanoprism-arrays assembled in N-doped carbon foamy nanoplates that have efficient polysulfide-retention for ultralong-cycle-life lithium-sulfur batteries. J Mater Chem A 6:11260–11269
Zhao M, Peng HJ, Wei JY, Huang JQ, Li BQ, Yuan H, Zhang Q (2019) Dictating high-capacity lithium-sulfur batteries through redox-mediated lithium sulfide growth. Small Methods 4:1900344
Wu X, Liu N, Guan B, Qiu Y, Wang M, Cheng J, Tian D, Fan L, Zhang N, Sun K (2019) Redox mediator: a new strategy in designing cathode for prompting redox process of Li-S batteries. Adv Sci (Weinh) 6:1900958
Li H, Ma S, Li J, Liu F, Zhou H, Huang Z, Jiao S, Kuang Y (2020) Altering the reaction mechanism to eliminate the shuttle effect in lithium-sulfur batteries. Energy Storage Mater 26:203–212
Tsao YC, Lee M, Miller EC, Gao GP, Park J, Chen SC, Katsumata T, Tran H, Wang LW, Toney MF, Cui Y, Bao ZN (2019) Designing a quinone-based redox mediator to facilitate Li2S oxidation in Li-S batteries. Joule 3:872–884
Yang Y, Zheng G, Misra S, Nelson J, Toney MF, Cui Y (2012) High-capacity micrometer-sized Li2S particles as cathode materials for advanced rechargeable lithium-ion batteries. J Am Chem Soc 134:15387–15394
Seh ZW, Wang H, Hsu P-C, Zhang Q, Li W, Zheng G, Yao H, Cui Y (2014) Facile synthesis of Li2S–polypyrrole composite structures for high-performance Li2S cathodes. Energy Environ Sci 7:672–676
Jeong S, Bresser D, Buchholz D, Winter M, Passerini S (2013) Carbon coated lithium sulfide particles for lithium battery cathodes. J Power Sources 235:220–225
Yang Z, Guo J, Das SK, Yu Y, Zhou Z, Abruña HD, Archer LA (2013) In situ synthesis of lithium sulfide–carbon composites as cathode materials for rechargeable lithium batteries. J Mater Chem A 1:1433–1440
Hayashi A, Ohtsubo R, Ohtomo T, Mizuno F, Tatsumisago M (2008) All-solid-state rechargeable lithium batteries with Li2S as a positive electrode material. J Power Sources 183:422–426
Hayashi A, Ohtsubo R, Tatsumisago M (2008) Electrochemical performance of all-solid-state lithium batteries with mechanochemically activated Li2S-Cu composite electrodes. Solid State Ionics 179:1702–1705
Hayashi A, Komiya R, Tatsumisago M, Minami T (2002) Characterization of Li2S-SiS2-Li3MO3 (M=B Al, Ga and In) oxysulfide glasses and their application to solid state lithium secondary batteries. Solid State Ionics 152:285–290
He JR, Chen YF, Lv WQ, Wen KC, Wang ZG, Zhang WL, Li YR, Qin W, He WD (2016) Three-dimensional hierarchical reduced graphene oxide/tellurium nanowires: a high-performance freestanding cathode for Li-Te batteries. ACS Nano 10:8837–8842
He JR, Chen YF, Manthiram A (2019) Metal sulfide-decorated carbon sponge as a highly efficient electrocatalyst and absorbant for polysulfide in high-loading Li2S batteries. Adv Energy Mater 9:1900584
Zhou GM, Tian HZ, Jin Y, Tao XY, Liu BF, Zhang RF, Seh ZW, Zhuo D, Liu YY, Sun J, Zhao J, Zu CX, Wu DS, Zhang QF, Cui Y (2017) Catalytic oxidation of Li2S on the surface of metal sulfides for Li−S batteries. Proc Natl Acad Sci 114:840–845
Zhang J, Shi Y, Ding Y, Peng L, Zhang W, Yu G (2017) A conductive molecular framework derived Li2S/N, P-codoped carbon cathode for advanced lithium-sulfur batteries. Adv Energy Mater 7:1602876
Meini S, Elazari R, Rosenman A, Garsuch A, Aurbach D (2014) The use of redox mediators for enhancing utilization of Li2S cathodes for advanced Li-S battery systems. J Phys Chem Lett 5:915–918
Liang X, Yun JF, Xu K, Xiang HF, Wang Y, Sun Y, Yu Y (2019) A multi-layered Ti3C2/Li2S composite as cathode material for advanced lithium-sulfur batteries. J Energy Chem 39:176–181
Wang ZY, Zhang N, Yu ML, Liu JS, Wang S, Qiu JS (2019) Boosting redox activity on MXene-induced multifunctional collaborative interface in high Li2S loading cathode for high-energy Li-S and metallic Li-free rechargeable batteries. J Energy Chem 37:183–191
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This work was supported by National Key R&D Program of China (2019YFC1900602).
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Yang, L., Li, Q., Wang, Y. et al. A review of cathode materials in lithium-sulfur batteries. Ionics 26, 5299–5318 (2020). https://doi.org/10.1007/s11581-020-03767-3
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DOI: https://doi.org/10.1007/s11581-020-03767-3