Abstract
We have synthesized anisotropic flower-like sliver nanostructures with multiple silver nanopetal-like structures, which are found to be protruding from the core body, in large scale, using single step galvanic reaction of ferrocene (FeCp2) with silver nitrate in presence of poly(vinyl pyrrolidone). The non-uniformly distributed multiple petal-like structures are found to be self-assembled by stacking layer by layer to form the anisotropic flower-like silver nanostructures. These anisotropic silver nanostructures constitute an active substrate material for surface-enhanced Raman scattering, which was confirmed from representative experiments using Rhodamine 6G and melamine (2,4,6-triamino-1,3,5-triazine) as probe molecules. Moreover, the stability of the synthesized AgNS has also been investigated. The results suggested that these AgNS exhibited excellent stability even after 1 month of storage and even after 3 months they show surface-enhanced Raman scattering effect. Therefore, our study exhibits highly stable silver nanostructures with unique optical properties. We believe this synthetic route for the formation of self-assembled anisotropic silver nanostructures can be a general synthetic platform to fabricate metal nanostructures with complex morphologies.
Similar content being viewed by others
References
Kundu S (2013) J Mater Chem C 1:831
Zhang F, Braun GB, Shi YF, Zhang YC, Sun XH, Reich NO, Zhao DY, Stucky G (2010) J Am Chem Soc 132:2850
Gude K, Narayanan R (2010) J Phys Chem C 114:6356
Li YN, Wu YL, Ong BS (2005) J Am Chem Soc 127:3266
Tian ZQ, Ren B, Li JF, Yang ZL (2007) Chem Commun 34:3514
Saha A, Basiruddin SK, Sarkar R, Pradhan N, Jana NR (2009) J Phys Chem C 113:18492
Horiuchi Y, Shimada M, Kamegawa T, Mori KJ (2009) Mater Chem 19:6745
Atwater HA, Polman A (2010) Nat Mater 9:865
Kumar PS, Pastoriza-Santos I, Rodriguez-Gonzalez B, Garcia de Abajo FJ, Liz-Marzán LM (2008) Nanotechnology 19:01506
Mohanty A, Garg N, Jin RC (2010) Angew Chem Int Ed 49:4962
Zhang H, Xia XH, Li WY, Zeng J, Dai YQ, Yang DR, Xia YN (2010) Angew Chem Int Ed 49:5296
Rodriguez-Lorenzo L, Alvarez-Puebla RA, de Abajo FJG, Liz-Marzán LM (2010) J Phys Chem C 114:7336
Allgeyer ES, Pongan A, Browne M, Mason MD (2009) Nano Lett 9:3816
Bratlie KM, Lee H, Komvopoulos K, Yang PD, Somorjai GA (2007) Nano Lett 7:3097
Hong LJ, Li Q, Lin H, Li YA (2009) Mater Res Bull 44:1201
Tang SC, Meng XK, Wang CC, Cao ZH (2009) Mater Chem Phys 114:842
Jena BK, Mishra BK, Bohidar S (2009) J Phys Chem C 113:14753
Sahoo PK, Kalyan Kamal SS, Jagadeesh Kumar T, Sreedhar B, Singh AK, Srivastava SK (2009) Def Sci J 59:447
Murphy CJ, Sau TK, Gole AM, Orendorff CJ, Gao J, Gou L, Hunyadi SE, Li T (2005) J Phys Chem B 109:13857
Sharma J, Imae T (2009) J Nanosci Nanotechnol 9:19
Nezhad MRH, Aizawa M, Porter LA, Ribbe AE, Buriak JM (2005) Small 1:1076
Sławin’ski GW, Zamborini FP (2007) Langmuir 23:10357
Lee C-L, Tseng TM, Wu RB, Yang KL (2008) Nanotechnology 19:215709
Sharma J, Tai Y, Imae T (2008) J Phys Chem C 112:17033
Lu X, Chen J, Skrabalak SE, Xia Y (2007) J Nanoeng Nanosyst 221:1
Vasilic R, Viyannalage LT, Dimitrov N (2006) J Electrochem Soc 153:C648
Viyannalage LT, Vasilic R, Dimitrov N (2007) J Phys Chem C 111:4036
Bansal V, Jani H, Plessis JD, Coloe PJ, Bhargava SK (2008) Adv Mater 20:717
Dryfe RAW, Walter EC, Penner RM (2004) Chem Phys Chem 5:1879
Dryfe RAW, Simm AO, Kralj B (2003) J Am Chem Soc 125:13014
Katz E, Willner I (2004) Angew Chem Int Ed 43:6042
Courty A, Henry A-I, Goubet N, Pileni M-P (2007) Nat Mater 6:900
Linh Tran M, Centeno SP, Hutchison JA, Ngelkamp HE, Liang D, Van Tendeloo G, Sels BF, Hofkens J, Uji-i H (2008) J Am Chem Soc 130:17240
Liang H, Li Z, Wang W, Wu Y, Xu H (2009) Adv Mater 21:4614
Wei H, Reyes-Coronado A, Nordlander P, Aizpurua J, Xu H (2009) ACS Nano 4:2649
Yang Y, Matsubara S, Xiong L, Hayakawa T, Nogami M, Phys J (2007) Chem C 111:9095
Sun Y, Xia Y (2002) Science 298:2176
Desmonda C, Tai Y (2010) International Conference on Enabling Science and Nanotechnology (ESciNano). KLCC, Kuala Lumpur
Said M, Máca F, Kambe K, Scheffler M (1988) Physical Review B (Rapid Communication) 38:8505
Wang L, Guo SJ, Hu XG, Dong SJ (2008) Electrochem Commun 10:95
Guzel R, Ustundag Z, Eski H, Keskin S, Taner B, Durgun ZG, Turan AAI, Solak AO (2010) J Colloid Interface Sci 351:35
Jeon SH, Xu P, Zhang B, Mack NH, Tsai H, Chiang LY, Wang H-L (2011) J Mater Chem 21:2550
Washio Y, Xiong Y, Yin Y, Xia Y (2006) Adv Mater 18:1745
Hidebrandt P, Stockburger M (1984) J Phys Chem 88:5935
Michaels AM, Nirmal M, Brus LE (1999) J Am Chem Soc 121:9932
He L, Liu Y, Lin M, Awika J, Ledoux DR, Li H, Mustapha A (2008) Sens & Instrumen Food Qual 2:66
Koglin E, Kip BJ, Meier RJ (1996) J Phys Chem 100:5078
Du X, Chu H, Huang Y, Zhao Y (2010) Appl Spectrosc 64:781
Zhang XF, Zou MQ, Qi XH, Liu F, Zhu XH, Zhao BH (2010) J Raman Spectrosc 41:1365
Zhang B, Xu P, Xie X, Wei H, Li Z, Mack NH, Han X, Xu H, Wang H-L (2011) J Mater Chem 21:2495
Liu T, Li D, Yang D, Jiang M (2011) Langmuir 27:6211
Pastoriza-Santos I, Liz-Marzan LM (2002) Langmuir 18:2888
Acknowledgments
We thank Professor Bing-Joe Hwang of NTUST for the support of SERS experiments, Professor Thomas C. K. Yang for the support of XRD instrument and NTUST for the support of TEM and SEM instruments. This study was funded by the National Science Council.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kar, S., Desmonda, C. & Tai, Y. Synthesis of SERS-Active Stable Anisotropic Silver Nanostructures Constituted by Self-Assembly of Multiple Silver Nanopetals. Plasmonics 9, 485–492 (2014). https://doi.org/10.1007/s11468-013-9646-3
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11468-013-9646-3