Skip to main content
SpringerLink
Log in

Synthesis and characterization of a novel well-defined comb-like ionomer

  • Research Article
  • Published:
Frontiers of Chemistry in China

Abstract

A novel well-defined comb-like ionomer with cations was synthesized by the combination of living anionic polymerization and atom transfer radical polymerization (ATRP). The synthetic approach involves the coupling reaction of polystyrene (PS) backbone bearing 1,1-diphenylethene (DPE) pendant groups with living polystyryllithium (PSLi), subsequent amine functionalization of the resulting 1,1-diphenylmethyl anions with 3-dimethylaminopropyl chloride (DMAPC), and quaternization of tertiary amino groups with hydrochloric acid. The comb-like ionomer was characterized by 1H NMR, IR, GPC measurements and end-group titrition.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Eisenberg, A., Macromolecules 1970, 3, 147–154

    Article  CAS  Google Scholar 

  2. Lundberg, R. D.; Makowski, H. S., J. Polym. Sci. Polym. Phys. Ed. 1980, 18, 1821–1836

    Article  CAS  Google Scholar 

  3. Schlick, S., Ionomers: Characterization, Theory and Applications; CRC Press: New York, 1995, 1–5

    Google Scholar 

  4. Eugene, A. L.; Tatiana, K. B.; Elena, V. S.; Eisenberg, A.; Victor, A. K.; Alexander, V. K., Macromolecules 2002, 35, 6344–6350

    Article  Google Scholar 

  5. Gao, Y.; Choudhury, N. R.; Dutta, N.; Matisons, J.; Reading, M.; Delmotte, L., Chem. Mater. 2001, 13, 3644–3652

    Article  CAS  Google Scholar 

  6. Chassenieux, C.; Nicolai, T.; Durand, D.; Gohy, J. F.; Jerome, R., Polym. Int. 2000, 49, 561–566

    Article  CAS  Google Scholar 

  7. Solomatin, S. V.; Bronich, T. K.; Eisenberg, A.; Kabanov, V. A.; Kabanov, A. V., Langmuir 2004, 20, 2066–2068

    Article  CAS  Google Scholar 

  8. Mao, C.; Jiang, L. C.; Luo, W. P.; Liu, H. K.; Bao, J. C.; Huang, X. H.; Shen, J., Macromolecules 2009, 42, 9366–9368

    Article  CAS  Google Scholar 

  9. Billon, L.; Manguian, M.; Pellerin, V.; Joubert, M.; Eterradossi, O.; Garay, H., Macromolecules 2009, 42, 345–356

    Article  CAS  Google Scholar 

  10. Saito, M.; Tsuzuki, S.; Hayamizu, K.; Okada, T., J. Phys. Chem. B 2006, 110, 24410–24417

    Article  CAS  Google Scholar 

  11. Sun, B. L.; Fang, L.; Liu, S. P., Polym. Mater. Sci. Eng. 2002, 18, 6–10

    CAS  Google Scholar 

  12. Zhu, Y. Q.; Ning, R. C.; Lan, L. W., Materials Review 2001, 15, 54–56

    Google Scholar 

  13. Shao, B.; Zhang, B. Y.; Hu, J. S.; Jiang, T. Y., Polym. Mater. Sci. Eng. 2002, 18, 70–72, 76

    CAS  Google Scholar 

  14. Liu, D. G.; Xie, H. Q., China Synthetic Rubber Industry 2004, 27, 56–59

    Google Scholar 

  15. Quirk, R. P.; Chenong, T. H.; Jiang, K.; Gomochak, D. L.; Yoo, T.; Andes, K. T.; Mathers, R. T., Macromol. Symp. 2003, 195, 69–74

    Article  CAS  Google Scholar 

  16. Chen, Y.; Xie, H. Q., China Synthetic Rubber Industry 2005, 28, 390

    Google Scholar 

  17. Quirk, R. P.; Mathers, R. T.; Ma, J. J.; Wesdemiotis, C.; Arnould, M. A., Macromol. Symp. 2002, 183, 17–22

    Article  CAS  Google Scholar 

  18. Quirk, R. P.; Kuang, J., Polym. Int. 1994, 33, 181–186

    Article  CAS  Google Scholar 

  19. Wang, Y. P.; Han, P.; Xu, H. P.; Wang, Z. Q.; Zhang, X.; Kabanov, A. V., Langmuir 2010, 26, 709–715

    Article  CAS  Google Scholar 

  20. Li, Y.; Bronich, T. K.; Chelushkin, P. S.; Kabanov, A. V., Macromolecules 2008, 41, 5863–5868

    Article  CAS  Google Scholar 

  21. Solomatin, S. V.; Bronich, T. K.; Bargar, T. W.; Eisenberg, A.; Kabanov, V. A.; Kabanov, A. V., Langmuir 2003, 19, 8069–8076

    Article  CAS  Google Scholar 

  22. Li, A.; Lu, Z., J. Shandong Univ. Nat. Sci. 2007, 47, 59–63

    CAS  Google Scholar 

  23. Quirk, R. P.; Lee, Y., J. Polym. Sci. A Polym. Chem. 2000, 38, 145–151

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Material Science and Engineering, Shandong University of Technology, Zibo, 255049, China

    Zijian Lv & Aixiang Li

  2. Glorious Sun School of Business and Management, Donghua University, Shanghai, 200051, China

    Zijian Lv

  3. School of Chemistry and Chemical Engineering, Shandong University, Jinan, 250100, China

    Zaijun Lu

Authors
  1. Zijian Lv
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Aixiang Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zaijun Lu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Aixiang Li.

About this article

Cite this article

Lv, Z., Li, A. & Lu, Z. Synthesis and characterization of a novel well-defined comb-like ionomer. Front. Chem. China 5, 342–347 (2010). https://doi.org/10.1007/s11458-010-0218-1

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11458-010-0218-1

Keywords

Search

Navigation