Skip to main content
Log in

Geochemical characteristics and origin of light hydrocarbons in biogenic gas

  • Research Paper
  • Published:
Science China Earth Sciences Aims and scope Submit manuscript

Abstract

The light hydrocarbon geochemical characteristics of biogenic gases from Sebei 1 gas field in the Qaidam Basin, Baoshan gas field in the Baoshan Basin and Alaxin gas field, Puqian gas pool, Aonan gas pool in the Songliao Basin are studied and the origin is discussed based on the composition and isotope data of gases. The isoalkane contents among light hydrocarbons in natural gas show a negative relationship with δ13C1 values. The isoalkane contents of the gases with δ13C1 values of less than −60‰ are also high with more than 40% among light hydrocarbons in Sebei 1 gas field and Puqian gas pool. Moreover, the 2,2-dimethylbutane and 2-methylpentane, mainly sourced from bacteria, have predominance among isoalkanes, which suggests that light hydrocarbons in biogenic gases from these gas fields or pools were probably generated by microbial action. However, the cycloalkane contents among light hydrocarbons in biogenic gas are related to δ13C1 values positively. In Alaxin gas field and Aonan gas pool, where δ13C1 values of biogenic gases are less than −60‰, the average contents of cycloalkane are higher than 44%. Light hydrocarbons among biogenic gases from these gas fields were probably generated by catalysis. The isoalkane and cycloalkane contents among light hydrocarbons from biogenic gases in the Baoshan gas field are both high, which might be generated by these two actions. The results show that the data of light hydrocarbons in biogenic gas can provide important information for understanding the generation mechanisms of light hydrocarbons during geological evolution and identifying biogenic gas and low mature gas.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Martini A M, Budai J M, Walter L M, et al. Microbial generation of economic accumulations of methane within a shallow organic-rich shale. Nature, 1996, 383: 155–158

    Article  Google Scholar 

  2. Lin C M, Gu L X, Li G Y, et al. Geology and formation mechanism of late Quaternary shallow biogenic gas reservoirs in the Hangzhou Bay area, eastern China. AAPG Bull, 2004, 88: 613–625

    Article  Google Scholar 

  3. Stadnitskaia A, Ivanov M K, Poludetkina E N, et al. Sources of hydrocarbon gases in mud volcanoes from the Sorokin Trough, NE Black Sea, based on molecular and carbon isotopic compositions. Mar Petrol Geol, 2008, 25: 1040–1057

    Article  Google Scholar 

  4. Xu Y C, Wang Z Y, Wang S F, et al. Low-mature gases and typical low-mature gas fields in China. Sci China Ser D-Earth Sci, 2008, 51: 312–320

    Article  Google Scholar 

  5. Zhang S C, Zhao W Z, Li X Q, et al. Advances in biogenic gas studies and play strategies (in Chinese). Petro Geol Exp, 2005, 32: 90–96

    Google Scholar 

  6. Shuai Y H, Zhang S C, Zhao W Z, et al. Longitudinal distributions of two formation pathways of biogenic gases in continental deposits: A case study from Sebei 1 gas field in the Qaidam Basin, western China. Sci China Ser D-Earth Sci, 2007, 50: 221–227

    Article  Google Scholar 

  7. Liu W H, Xu Y C, Shi J Y, et al. Evolution model and formation mechanism of bio-thermocatalytic transitional zone gas. Sci China Ser D-Earth Sci, 1997, 40: 43–53

    Article  Google Scholar 

  8. Dai J X, Chen Y. Characteristics of carbon isotopes of alkane components and identification marks of biogenic gases in China. Sci China Ser B, 1994, 37: 231–241

    Google Scholar 

  9. Liu W H, Xv Y C, Lei H Y, et al. The bio-theormocatalytic transitional zone gas and its comprehensive identification criterias (in Chinese). Bull Miner Petrol Geochem, 1997, 16: 51–54

    Google Scholar 

  10. Xu Y C, Liu W H, Shen P, et al. Carbon and hydrogen isotopic characteristics of natural gases from the Luliang and Baoshan Basins in Yunnan Province, China. Sci China Ser D-Earth Sci, 2006, 49: 938–946

    Article  Google Scholar 

  11. Xiao Z H, Hu G Y, Li J, et al. Light hydrocarbons distribution characteristics and significance of natural gas in Baoshan, Luliang and Qujing Basin in Yunnan Province (in Chinese). Nat Gas Geosci, 2006, 17: 173–176

    Google Scholar 

  12. Hu G Y, Shan X Q, Li Z S, et al. The component and isotope characteristics of hydrocarbon in fluid inclusions and its affection on the gas reservoir formation: The case of Ordovician reservoir in the northwest area of Ordos (in Chinese). Acta Petrol Sin, 2005, 25: 1461–1466

    Google Scholar 

  13. Wang N F. A probe of shallow teriary gas formation production law in Luliang and Baoshan Basin in Yunnan Province (in Chinese). Southwest Petrol Inst, 2004, 26: 29–33

    Google Scholar 

  14. Dai J X, Song Y, Zhang H F. Main factors controlling the foundation of medium-giant gas fields in China. Sci China Ser D-Earth Sci, 1997, 40: 1–10

    Article  Google Scholar 

  15. Gu S S, Zhou Z H. Geochemical characteristics and classification of natural gas in Quaternary in the east part of Chaidamu Basin (in Chinese). Nat Gas Ind, 1993, 13: 1–6

    Google Scholar 

  16. Gutsalo L K, Plotnikov A M. The origin identification of methane and carbon dioxide by the carbon isotope system of CH4 and CO2 in the earth. Bull Soviet Acad Sci, 1981, 259: 470–473

    Google Scholar 

  17. Schoell M. The hydrogen and carbon isotopic composition of methane from natural gases of various origins. Geochim Cosmochim Acta, 1980, 44: 649–661

    Article  Google Scholar 

  18. Rice D D, Claypool G E. Generation, accumulation and resource potential of biogenic gas. AAPG Bull, 1981, 65: 5–25

    Google Scholar 

  19. Whiticar M J, Faber E, Schoell M. “Biogenic” methane formation in marine and freshwater environments: CO2 reduction vs. acetate fermentation-isotopic evidence. Geochim Cosmochim Acta, 1986, 50: 693–709

    Article  Google Scholar 

  20. Whiticar M J. Carbon and hydrogen isotope systematics of bacterial formation and oxidation of methane. Chem Geol, 1999, 161: 291–314

    Article  Google Scholar 

  21. Tissot B P, Welte D H. Petroleum Formation and Occurrence: A New Approach to Oil and Gas Exploration. New York: Springer Verlag, 1978. 50–70

    Google Scholar 

  22. Leythaeuser D, Schaefer R G, Cornford C. Generation and migration of light hydrocarbon (C2-C7) in sedimentary Basin. Org Geochem, 1979, 1: 191–204

    Article  Google Scholar 

  23. Thompson K F M. Classification and thermal history of petroleum based on light hydrocarbons. Geochim Cosmochim Acta, 1983, 47: 303–316

    Article  Google Scholar 

  24. Kissin Y V. Catagenesis and composition of light cycloalkanes in petroleum. Org Geochem, 1990, 15: 575–594

    Article  Google Scholar 

  25. Mango F D. The origin of light hydrocarbon in petroleum: A kinetic test of the steady state catalytic hypothesis. Geochim Cosmochim Acta, 1990, 54: 1315–1323

    Article  Google Scholar 

  26. Mango F D. The origin of light hydrocarbons in petroleum-Ring preference in the closure of carbocyclic rings. Geochim Cosmochim Acta, 1994, 58: 895–901

    Article  Google Scholar 

  27. Mango F D. The light hydrocarbons in petroleum: A critical review. Org Geochem, 1997, 26: 417–440

    Article  Google Scholar 

  28. Mango F D. The origin of light hydrocarbons. Geochim Cosmochim Acta, 2000, 64: 1265–1277

    Article  Google Scholar 

  29. Hunt J M. Origin of gasoline range alkanes in the deep sea. Nature, 1975, 254: 411

    Article  Google Scholar 

  30. Hunt J M, Huc A Y, Whelan J K. Generation of light hydrocarbons in sedimentary rocks. Nature, 1980, 288: 688–690

    Article  Google Scholar 

  31. Whelan J K, Hunt J M. C1–C8 hydrocarbons in Leg 64 sediments, Gulf of California. In: Curray J, Moore D G, et al, eds. Initial Reports DSDP 64, Washington: U. S. Gort. Printing Office, 1982. 763–779

    Google Scholar 

  32. Schaefer R G. C2–C8 hydrocarbons in sediments from Deep Sea Drilling Project, Leg71, Site 5511, Falkland plateau, South Atlantic. In: Ludcuig W J, Krasheninnikow V A, et al, eds. Init Repts. Washington: U. S. Gort Printing Office, 1983. 1033–1043

    Google Scholar 

  33. Kaneda T. Fatty acids in the genus Bacillus: An example of branched-chain preference. Bcteriol Rev, 1977, 41: 371–418

    Google Scholar 

  34. Hartgers W A, Damste J S, Requejo A G, et al. Evidence for only minor contributions from bacteria to sedimentary organic carbon. Nature, 1994, 369: 64–77

    Article  Google Scholar 

  35. Wang T G, Zhong N N, Hou D J, et al. The bacterial effects of hydrocarbon generation mechanism in banqiao sag (in Chinese). Sci China Ser B, 1995, 25: 882–889

    Google Scholar 

  36. Qian Y B, Lian L W, Chen W Z, et al. The alteration of methane carbon isotope in biogas generation process (in Chinese). Acta Petrol Sin, 1998, 19: 29–33

    Google Scholar 

  37. Mango F D. Transition metal catalysis in the generation of petroleum and natural gas. Geochim Cosmochim Acta, 1992, 56: 553–555

    Article  Google Scholar 

  38. Chen Y C, Luo X P, Shen Z M, et al. Biological gas resource and its exploration potential in Neogene, Baoshan Basin (in Chinese). Nat Gas Geosci, 2008, 19: 618–622

    Google Scholar 

  39. Thompson K F M. Light hydrocarbons in subsurface sediments. Geochim Cosmochim Acta, 1979, 43: 657–672

    Article  Google Scholar 

  40. Hu G Y, Li J, Li J, et al. Preliminary study on the origin identification of natural gas by parameters of light hydrocarbon. Sci China Ser D-Earth Sci, 2008, 51(Suppl): 131–139

    Article  Google Scholar 

  41. Xu Y C, Shen P, Liu W H, et al. A new genetic type of natural gas bio-theormocatalytic transitional zone gas (in Chinese). Sci China Ser B, 1990, 20: 975–980

    Google Scholar 

  42. Liu S G, Dai S L, Zhao Y S, et al. Hydrocarbon source rocks and their natural gas generation characteristics in Baoshan Basin, Yunnan Province (in Chinese). Nat Gas Ind, 1998, 18: 18–24

    Google Scholar 

  43. Xu Y C, Shen P, Zheng J J. Natural gas geochemistry of low evolutionary stage of medium- and small-sized basin in Yunnan Province, Southwestern China. Chin Sci Bull, 1999, 44: 1709

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to GuoYi Hu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hu, G., Luo, X., Li, Z. et al. Geochemical characteristics and origin of light hydrocarbons in biogenic gas. Sci. China Earth Sci. 53, 832–843 (2010). https://doi.org/10.1007/s11430-010-3072-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11430-010-3072-6

Keyword

Navigation