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Chiral supramolecular 2D halogen-bonded organic frameworks constructed by post-synthetic modified cross-linking strategy

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Abstract

The development of preparation methods for XOFs, as a new class of organic frameworks, plays a crucial role in shaping their structures, functions, and potential applications. In this study, we presented the construction of chiral supramolecular 2D halogen-bonded organic frameworks (XOFs) through a post-synthetic modification strategy. A linear halogen-bonded organic polymer (XOP), XOP-DPBA, decorated with aldehyde groups, was initially prepared to validate the feasibility of post-synthetic modification for XOF construction and functionalization. XOP-DPBA exhibited excellent reactivity with amines, forming imine bonds. By utilizing this reactivity, a series of cross-linked 2D XOFs were efficiently prepared through post-synthetic modified cross-linking reactions. Furthermore, we successfully introduced chiral α/β-cyclodextrins (α/β-CD) into the XOF skeletons via host-guest interactions, resulting in the fabrication of chiral supramolecular 2D XOFs. These chiral XOFs displayed the induced circular dichroism (ICD) signals and assembled them into helical fibers. The post-synthetic modification strategy demonstrated its versatility and simplicity for the construction and functionalization of XOFs.

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Acknowledgements This work was supported by the National Natural Science Foundation of China (22371218, 21702153, 21801194) and the Wuhan Science and Technology Bureau (whkxjsj009). We thank the support of the Core Facility of Wuhan University and the Large-scale Instrument and Equipment Sharing Foundation of Wuhan University. We thank Miss Dai from the Core Facility of Wuhan University for her assistance with SEM analysis.

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  1. These authors contributed equally to this work.

Authors and Affiliations

  1. The Institute for Advanced Studies, Wuhan University, Wuhan, 430072, China

    Ning Xia, Jiahao Zhao, Guanfei Gong, Hongqiang Dong, Haohu Li, Jike Wang, Lu Wang & Shigui Chen

  2. School of Materials Science and Engineering, Hubei University of Automotive Technology, Shiyan, 442002, China

    Ning Xia

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  1. Ning Xia
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Correspondence to Shigui Chen.

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Supporting information The supporting information is available online at chem.scichina.com and link.springer.com/journal/11426. The supporting materials are published as submitted, without typesetting or editing. The responsibility for scientific accuracy and content remains entirely with the authors.

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11426_2023_1829_MOESM1_ESM.docx

Chiral Supramolecular 2D Halogen-Bonded Organic Frame-works Constructed by Post-Synthetic Modified Cross-Linking Strategy

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Xia, N., Zhao, J., Gong, G. et al. Chiral supramolecular 2D halogen-bonded organic frameworks constructed by post-synthetic modified cross-linking strategy. Sci. China Chem. 66, 3169–3177 (2023). https://doi.org/10.1007/s11426-023-1829-8

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