Abstract
Deep eutectic solvent (DES) was applied as the solvent of iron/alcohol amine system, and the prepared iron/ethanolamine/DES system was found to be a good desulfurizer for H2S removal. The absorbents were characterized by Fourier transform infrared spectroscopy. The iron/ethanolamine/DES system showed a significantly enhanced desulfurization performance compared with DES solution of iron or alcohol amine separately. Besides, the absorbents showed relatively stable desulfurization performance, which could keep a high H2S removal efficiency in a wide temperature range from 30–90°C. The iron/ethanolamine/DES system could be recycled for at least three times. The desulfurization product was analyzed by energy dispersive spectrum and X-ray diffraction, and the desulfurization product was identified as sulfur element.
Similar content being viewed by others
References
Deshmukh GM, Shete A, Pawar DM (2013) Oxidative absorption of hydrogen sulfide using an iron-chelate based process: chelate degradation. J Chem Technol Biotechnol 88:432–436. https://doi.org/10.1002/jctb.3903
Dixon BE, Williams RA (1950) Reaction of iron with monoeth anolamine. J Soc Chem Ind 69:69–71. https://doi.org/10.1002/jctb.5000690302
Eng SJ, Motekaitis RJ, Martell AE (2000) Degradation of coordinated β-diketonates as iron chelate catalysts during the oxidation of H2S to S8 by molecular oxygen. Inorg Chim Acta 299:9–15. https://doi.org/10.1016/S0020-1693(99)00434-X
Garcia G, Aparicio S, Ullah R, Atilhan M (2015) Deep eutectic solvents: physicochemical properties and gas separation applications. Energy Fuel 29:2616–2644. https://doi.org/10.1021/ef5028873
Hua G, Zhang Q, McManus D, Slawin AMZ, Woollins JD (2006) Novel non-aqueous Fe(iii)/Fe(ii) redox couple for the catalytic oxidation of hydrogen sulfide to sulfur by air. Dalton Trans:1147-1156. https://doi.org/10.1039/B513384J
Huang Z, Jiang B, Yang H, Wang B, Zhang N, Dou H, Wei G, Sun Y, Zhang L (2017) Investigation of glycerol-derived binary and ternary systems in CO2 capture process. Fuel 210:836–843. https://doi.org/10.1016/j.fuel.2017.08.043
Iliuta I, Larachi F (2003) Concept of bifunctional Redox iron-chelate process for H2S removal in pulp and paper atmospheric emissions. Chem Eng Sci 58:5305–5314. https://doi.org/10.1016/j.ces.2003.09.009
Keuleers R, Janssens J, Desseyn HO (2000) Thermal analysis and vibrational spectroscopy of Mn(II)–urea–halide complexes: comparative study of the metal–ligand bond strength. Thermochim Acta 354:125–133. https://doi.org/10.1016/S0040-6031(00)00464-0
Lenninger M, Aguilo-Aguayo N, Bechtold T (2018) Quantification of triethanolamine through measurement of catalytic current in alkaline iron-d-gluconate solution. J Electroanal Chem 830-831:50–55. https://doi.org/10.1016/j.jelechem.2018.10.026
Liu W, Chu G-W, Luo Y, Zhan Y-Y, Zhang L-L, Chen J-F (2019a) Desulfurization of offshore natural gas by chelated iron solution in a higee reactor: a feasibility study. Ind Eng Chem Res 58:10629–10634. https://doi.org/10.1021/acs.iecr.9b02630
Liu X, Li J, Wang R (2017a) Desulfurization and regeneration performance of heteropoly compound/ionic liquid solutions at high temperature. Chem Eng J 316:171–178. https://doi.org/10.1016/j.jhazmat.2020.124271
Liu X, Li J, Wang R (2017b) Study on the desulfurization performance of hydramine/ionic liquid solutions at room temperature and atmospheric pressure. Fuel Process Technol 167:382–387. https://doi.org/10.1016/j.fuproc.2017.07.023
Liu X, Wang B, Cheng J, Meng Q, Song Y, Li M (2020) Investigation on the capture performance and influencing factors of ZIF-67 for hydrogen sulfide. Sep Purif Technol 250:117300. https://doi.org/10.1016/j.seppur.2020.117300
Liu X, Wang B, Lv X, Meng Q, Li M (2021) Enhanced removal of hydrogen sulfide using novel nanofluid system composed of deep eutectic solvent and Cu nanoparticles. J Hazard Mater:124271. https://doi.org/10.1016/j.jhazmat.2020.124271
Liu X, Wang B, Wang D, Cheng J, Meng Q, Zhang Z, Gao P, An J, Lou J, Li M (2019b) Study on the desulfurization performance of metal-based low transition temperature mixtures: removal of hydrogen sulfide and sulfur recovery. Fuel Process Technol 193:372–377. https://doi.org/10.1016/j.fuproc.2019.05.029
Liu X, Wang R (2017a) Effective removal of hydrogen sulfide using 4A molecular sieve zeolite synthesized from attapulgite. J Hazard Mater 326:157–164. https://doi.org/10.1016/j.jhazmat.2016.12.030
Liu X, Wang R (2017b) H2S removal by peroxo heteropoly compound/ionic liquid solution. Fuel Process Technol 160:78–85. https://doi.org/10.1016/j.fuproc.2017.02.024
Salem IA (1995) Kinetics of hydrogen peroxide decomposition with Fe(III) and Cr(III)-ethanolamines complexes sorbed on dowex-50W resin. Int J Chem Kinet 27:499–505. https://doi.org/10.1002/kin.550270508
Taheri M, Zhu R, Yu G, Lei Z (2021) Ionic liquid screening for CO2 capture and H2S removal from gases: The syngas purification case. Chem Eng Sci 230:116199. https://doi.org/10.1016/j.ces.2020.116199
Wang B, Cheng J, Wang DD, Li X, Meng Q, Zhang Z, An J, Liu X, Li M (2020a) Study on the desulfurization and regeneration performance of functional deep eutectic solvents. ACS Omega 5:15353–15361. https://doi.org/10.1021/acsomega.0c01467
Wang J, Zhang L, Sun Y, Jiang B, Chen Y, Gao X, Yang H (2018) Deep catalytic oxidative desulfurization of fuels by novel Lewis acidic ionic liquids. Fuel Process Technol 177:81–88. https://doi.org/10.1016/j.fuproc.2018.04.013
Wang R (2003) Investigation on a new liquid redox method for H2S removal and sulfur recovery with heteropoly compound. Sep Purif Technol 31:111–121. https://doi.org/10.1016/S1383-5866(02)00153-3
Wang Y, Liu X, Kraslawski A, Gao J, Cui P (2019) A novel process design for CO2 capture and H2S removal from the syngas using ionic liquid. J Clean Prod 213:480–490. https://doi.org/10.1016/j.jclepro.2018.12.180
Wang Y, Liu Y, Liu X, Li G, Qi J, Yang J, Zhu Z, Ma Y, Gao J, Meng F (2020b) Novel postcombustion capture process for CO2 from the flue gas of coal-fired power plants using a green deep eutectic solvent. ACS Sustain Chem Eng 8:2236–2245. https://doi.org/10.1021/acssuschemeng.9b06026
Wubs HJ, Beenackers AACM (1994) Kinetics of H2S absorption into aqueous ferric solutions of edta and hedta. AIChE J 40:433–444. https://doi.org/10.1002/aic.690400307
Yang C, Kou J, Fan H, Tian Z, Kong W, Shangguan J (2019) Facile and versatile sol–gel strategy for the preparation of a high-loaded ZnO/SiO2 adsorbent for room-temperature H2S removal. Langmuir 35:7759–7768. https://doi.org/10.1021/acs.langmuir.9b00853
Yang X, Zhang Y, Liu F, Chen P, Zhao T, Wu Y (2020) Deep eutectic solvents consisting of EmimCl and amides: highly efficient SO2 absorption and conversion. Sep Purif Technol 250:117273. https://doi.org/10.1016/j.seppur.2020.117273
Yuan J, Du L, Li S, Yang F, Zhang Z, Li G, Wang G (2019) Use of mature compost as filter media and the effect of packing depth on hydrogen sulfide removal from composting exhaust gases by biofiltration. Environ Sci Pollut Res 26:3762–3770. https://doi.org/10.1007/s11356-018-3795-z
Zhang F, Zhang X, Jiang G, Li N, Hao Z, Qu S (2018a) H2S selective catalytic oxidation over Ce substituted La1−xCexFeO3 perovskite oxides catalyst. Chem Eng J 348:831–839. https://doi.org/10.1016/j.cej.2018.05.050
Zhang Y, Ji X, Lu X (2018b) Choline-based deep eutectic solvents for CO2 separation: review and thermodynamic analysis. Renew Sust Energ Rev 97:436–455. https://doi.org/10.1016/j.rser.2018.08.007
Zheng Z, Cao Y, Cheng S, Chen L, Zhang C (1996) Study of desulfurization by TEA complex iron. J East China Univ Sci Technol 22:19–23 (in Chinese)
Funding
This work was supported by funding from the National Natural Science Foundation of China (Nos.21908134, 41771348), Natural Science Foundation of Shandong Province (Nos.ZR2019BB045).
Author information
Authors and Affiliations
Contributions
Xinpeng Liu conceived and planned the whole work. Baohua Wang, Yahui Qiu, and Xiaole Dong carried out the experimental work. Baohua Wang and Yixin Song contributed to the analysis and interpretation of results. Qingmei Meng and Menghong Li were contributors in writing the manuscript. All authors read and approved the final manuscript.
Corresponding author
Ethics declarations
Ethics approval and consent to participate
Not applicable.
Consent for publication
Not applicable.
Competing interests
The authors declare no competing interests.
Additional information
Responsible Editor: Santiago V. Luis
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Liu, X., Wang, B., Qiu, Y. et al. Study on the desulfurization performance of iron/ethanolamine/deep eutectic solvent system. Environ Sci Pollut Res 28, 38026–38033 (2021). https://doi.org/10.1007/s11356-021-13487-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-021-13487-4