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Influence of metal-based cerium oxide nanoparticle additive on performance, combustion, and emissions with biodiesel in diesel engine

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Abstract

Biodiesel has been renowned as potential and alternative fuel for years. In order to improve the quality of the conventional fossil fuels, biodiesel, and air pollution from combustion, additives are essential to exploit. In this study, the uses of cerium oxide (CeO2) nanoparticle additive for B20 fuel in a diesel engine are investigated. The CeO2 nanoparticles with cetyl-trimethyl ammonium bromide are doped into the B20 fuel by using ultrasonicator. The purpose of the experimental work was adopted to enhance engine combustion and reduce the emissions with an approach of CeO2 nanoparticle additive. The experiment was conducted on a diesel engine using different propagation of CeO2 nanoparticle in blended mahua methyl ester fuel such as B20 + CeO2 50 ppm, B20 + CeO2 100 ppm, and B20 + CeO2 150 ppm. The obtained results are compared with the diesel and B20 fuels. The minor changes are obtained in B20 fuel properties due to the addition of CeO2 nanoparticles. The performance of brake thermal efficiency and combustion of pressure data is observed to be enhanced by the addition of a metal-based additive. The CO, HC, and smoke are decreased for B20 fuel with nanoparticles. The NOx is reduced by dosing the CeO2 due to the oxidation of unburned CeO2 in the exhaust.

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Abbreviations

BP:

Brake power

HRR:

Heat release rate

BSEC:

Brake-specific energy consumption

H2O:

Water vapor

BSFC:

Brake-specific fuel consumption

ID:

Ignition delay

BMEP:

Brake mean effective pressure

IT:

Injection timing

bTDC:

Before top dead center

MME:

Mahua methyl ester

BTE:

Brake thermal efficiency

MGT:

Mean gas temperature

CA:

Crank angle

N2 :

Nitrogen

cTAB:

Cetyl-trimethyl ammonium bromide

NOx :

Oxides of nitrogen

CI:

Compression ignition

N2O:

Nitrous oxide

CO:

Carbon monoxide

NO:

Nitric oxide

CO2 :

Carbon dioxide

NO2 :

Nitrogen dioxide

CeO2 :

Cerium oxide

O2 :

Oxygen

DI:

Direct injection

PM:

Particulate matter

FAME:

Fatty acid methyl ester

PPM:

Parts per million

HC:

Hydrocarbon

TEM:

Transmission electron microscopy

References

  • Ashrafur Rahman SM, Masjuki HH, Kalam MA, Abedin MJ, Sanjid A, Rahman MM (2014) Assessing idling effects on a compression ignition engine fueled with jatropha and palm biodiesel blends. Renew Energy 68:644–650

    Article  CAS  Google Scholar 

  • Campenon T, Blanchard G, Macaudiere P, Seguelong T (2004) Improvement and simplification of DPF system using a ceria-based fuelborne catalyst for diesel particulate filter regeneration in serial applications. SAE 2004-01-0071

  • Celik M, Solmaz H, Serdar Yucesu H (2015) Examination of the effects of organic based manganese fuel additive on combustion and engine performance. Fuel Process Technol 139:100–107

    Article  CAS  Google Scholar 

  • D’Silva R, Binu KG, Bhat T (2015) Performance and emission characteristics of a C.I. engine fuelled with diesel and TiO2 nanoparticles as fuel additive. Mater Today: Proc 2:3728–3735

    Google Scholar 

  • Ghanbari M, Najafi G, Ghobadian B, Yusaf T, Carlucci AP, Kiani Deh Kiani M (2017) Performance and emission characteristics of a CI engine using nano particles additives in biodiesel-diesel blends and modeling with GP approach. Fuel 202:699–716. https://doi.org/10.1016/j.fuel.2017.04.117

    Article  CAS  Google Scholar 

  • Guru M, Koca A, Can O, Cinar C, Sahin F (2010) Biodiesel production from waste chicken fat based sources and evaluation with Mg based additive in a diesel engine. Renew Energy 35:637–643

    Article  CAS  Google Scholar 

  • Jain S, Sharma MP (2011) Oxidation stability of blends of Jatropha biodiesel with diesel. Fuel 90:3014–3020

    Article  CAS  Google Scholar 

  • Jayed M, Masjuki H, Saidur R, Kalam M, Jahirul M (2009a) Environmental aspects and challenges of oilseed produced biodiesel in Southeast Asia. Renew Sust Energ Rev 13:2452–2462

    Article  CAS  Google Scholar 

  • Jayed M, Masjuki H, Saidur R, Kalam M, Jahirul M (2009b) Environmental aspects and challenges of oil seed produced biodiesel in Southeast Asia. Renew Sust Energ Rev 13:2452–2462

    Article  CAS  Google Scholar 

  • Jiaqiang E, Liu T, Yang W, Deng Y, Gong J (2016a) A skeletal mechanism modeling on soot emission characteristics for biodiesel surrogates with varying fatty acid methyl esters proportion. Appl Energy 181:322–331

    Article  CAS  Google Scholar 

  • Jiaqiang E, Liu T, Yang WM, Li J, Gong J, Deng Y (2016b) Effects of fatty acid methyl esters proportion on combustion and emission characteristics of a biodiesel fueled diesel engine. Energy Convers Manag 117:410–419

    Article  CAS  Google Scholar 

  • Jiaqiang E, Pham M, Zhao D, Deng Y, Le D, Zuo W, Zhu H, Liu T, Peng Q, Zhang Z (2017) Effect of different technologies on combustion and emissions of the diesel engine fueled with biodiesel: a review. Renew Sust Energ Rev 80:620–647

    Article  Google Scholar 

  • Jiaqiang E, Pham M, Deng Y, Nguyen T, Duy V, Le D, Zuo W, Peng Q, Zhang Z (2018a) Effects of injection timing and injection pressure on performance and exhaust emissions of a common rail diesel engine fueled by various concentrations of fish-oil biodiesel blends. Energy 149:979–989

    Article  CAS  Google Scholar 

  • Jiaqiang E, Zhang Z, Chen J, Pham M, Zhao X, Peng Q, Zhang B, Yin Z (2018b) Performance and emission evaluation of a marine diesel engine fueled by water biodiesel-diesel emulsion blends with a fuel additive of a cerium oxide nanoparticle. Energy Convers Manag 169:194–205

    Article  CAS  Google Scholar 

  • Joshi RM (2007) Flow properties of biodiesel fuel blends at low temperatures. Fuel 86:143–151

    Article  CAS  Google Scholar 

  • Jung H, Kittelson DB, Zachariah MR (2005) The influence of a cerium additive on ultrafine diesel particle emissions and kinetics of oxidation. Combust Flame 142:276–288

    Article  CAS  Google Scholar 

  • Kannan G, Karvembu R, Anand R (2011) Effect of metal-based additive on performance emission and combustion characteristics of diesel engine fuelled with biodiesel. Appl Energy 88:3694–3703

    Article  CAS  Google Scholar 

  • Keskin A, Guru M, Altiparmak D (2007) Biodiesel production from tall oil synthesized Mn and Ni based additives: effects of the additives on fuel consumption and emissions. Fuel 86:1139–1143

    Article  CAS  Google Scholar 

  • Keskin A, Guru M, Altiparmak D (2008) Influence of tall oil biodiesel with Mg and Mo based fuel additives on diesel engine performance and emission. Bioresour Technol 99:6434–6438

  • Lee HV, Taufiq-Yap YH, Hussein MZ, Yunus R (2013) Transesterification of Jatropha oil with methanol over Mg-Zn mixed metal oxide catalysts. Energy 49:12–18

    Article  CAS  Google Scholar 

  • Lenin MA, Swaminathan MR, Kumaresan G (2013) Performance and emission characteristics of a DI diesel engine with a nanofuel additive. Fuel 109:362–365

    Article  CAS  Google Scholar 

  • Liu T, Jiaqiang E, Yang W, Hui A, Cai H (2016) Development of a skeletal mechanism for biodiesel blend surrogates with varying fatty acid methyl esters proportion. Appl Energy 162:278–288

    Article  CAS  Google Scholar 

  • Liu T, Jiaqiang E, Yang WM, Deng Y, An H, Zhang Z, Pham M (2018) Investigation on the applicability for reaction rates adjustment of the optimized biodiesel skeletal mechanism. Energy 150:1031–1038

    Article  CAS  Google Scholar 

  • May WR, Hirs EA (2005) Catalyst for improving the combustion efficiency of petroleum fuels in diesel engines. 11th diesel engine emissions reduction conference , Chicago IL, August 21–25

  • Murugesan A, Umarani C, Chinnusamy TR, Krishnan M, Subramanian R, Neduzchezhain N (2009) Production and analysis of bio-diesel from non-edible oils – a review. Renew Sust Energ Rev 13:825–834

    Article  CAS  Google Scholar 

  • Okuda T, Schauer JJ, Olson RM, Shafer MM, Rutter PA, Walz AK, Morschauser AP (2009) Effects of a platinum-cerium bimetallic fuel additive on the chemical composition of diesel engine exhaust particles. Energy Fuel 23:4974–4980

    Article  CAS  Google Scholar 

  • Patil PD, Deng S (2009) Optimization of biodiesel production from edible and non-edible vegetable oils. Fuel 88:1302–1306

    Article  CAS  Google Scholar 

  • Prabu A (2017) Nanoparticles as additive in biodiesel on the working characteristics of a DI diesel engine. Ain Shams Eng J. https://doi.org/10.1016/j.asej.2017.04.004

  • Qi D, Chen H, Geng L, Bian Y (2010) Experimental studies on the combustion characteristics and performance of a direct injection engine fuelled with biodiesel/diesel blends. Energy Convers Manag 51:2985–2992

    Article  CAS  Google Scholar 

  • Rahmat N, Abdullah AZ, Mohamed AR (2010) Recent progress on innovative and potential technologies for glycerol transformation into fuel additives: a critical review. Renew Sust Energ Rev 14:987–1000

    Article  CAS  Google Scholar 

  • Rashedul HK, Masjuki HH, Kalam MA, Ashraful AM, Ashrafur Rahman SM, Shahir SA (2014) The effect of additives on properties, performance and emission of biodiesel fuelled compression ignition engine. Energy Convers Manag 88:348–364

    Article  CAS  Google Scholar 

  • Sadhik Basha J, Anand RB (2011) An experimental investigation in a diesel engine using carbon nanotubes blended water–diesel emulsion fuel. Proc Instit Mech Eng Part A: J Power Energ 225(3):279–288

    Article  CAS  Google Scholar 

  • Shahir VK, Jawahar CP, Suresh PR (2015) Comparative study of diesel and biodiesel on CI engine with emphasis to emissions – a review. Renew Sust Energ Rev 45:686–697

    Article  CAS  Google Scholar 

  • Syed Aalam C, Saravanan CG (2017) Effects of nano metal oxide blended mahua biodiesel on CRDI diesel engine. Ain Shams Eng J 8:689–696

    Article  Google Scholar 

  • Szulczyk KR, McCarl BA (2010) Market penetration of biodiesel. Renew Sust Energ Rev 14:2426–2433

    Article  Google Scholar 

  • Kumar MV, Veeresh Babu A, Ravi Kumar P (2017) The impacts on combustion, performance and emissions of biodiesel by using additives in direct injection diesel engine: review. Alexandria Eng J 57:509–516. https://doi.org/10.1016/j.aej.2016.12.016

    Article  Google Scholar 

  • Yang HH, Lee WJ, Mi HH, Wong CH, Chen CB (1998) PAH emissions influenced by Mn-based additive and turbocharging from a heavy-duty diesel engine. Environ Int 24:389–403

    Article  CAS  Google Scholar 

  • Zhang Z, Jiaqiang E, Deng Y, Pham M, Zuo W, Peng Q, Yin Z (2018) Effects of fatty acid methyl esters proportion on combustion and emission characteristics of a biodiesel fueled marine diesel engine. Energy Convers Manag 159:244–253

    Article  CAS  Google Scholar 

  • Zhang Z, Jiaqiang E, Chen J, Zhu H, Zhao X, Han D, Zuo W, Peng Q, Gong J, Yin Z (2019) Effects of low-level water addition on spray, combustion and emission characteristics of a medium speed diesel engine fueled with biodiesel fuel. Fuel 239:245–262

    Article  CAS  Google Scholar 

Download references

Acknowledgements

The authors are very grateful to the Director of National Institute of Technology Warangal for granting permission to do the research in the mechanical laboratory.

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Correspondence to Megavath Vijay Kumar.

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Kumar, M.V., Babu, A.V. & Kumar, P.R. Influence of metal-based cerium oxide nanoparticle additive on performance, combustion, and emissions with biodiesel in diesel engine. Environ Sci Pollut Res 26, 7651–7664 (2019). https://doi.org/10.1007/s11356-018-04075-0

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