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Study of the carbonaceous aerosol and morphological analysis of fine particles along with their mixing state in Delhi, India: a case study

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Abstract

Because of high emissions of anthropogenic as well as natural particles over the Indo-Gangetic Plains (IGP), it is important to study the characteristics of fine (PM2.5) and inhalable particles (PM10), including their morphology, physical and chemical characteristics, etc., in Delhi during winter 2013. The mean mass concentrations of fine (PM2.5) and inhalable (PM10) (continuous) was 117.6 ± 79.1 and 191.0 ± 127.6 μg m−3, respectively, whereas the coarse mode (PM10–2.5) particle PM mass was 73.38 ± 28.5 μg m−3. During the same period, offline gravimetric monitoring of PM2.5 was conducted for morphological analysis, and its concentration was ~37 % higher compared to the continuous measurement. Carbonaceous PM such as organic carbon (OC) and elemental carbon (EC) were analyzed on the collected filters, and their mean concentration was respectively 33.8 and 4.0 μg m−3 during the daytime, while at night it was 41.2 and 10.1 μg m−3, respectively. The average OC/EC ratio was 8.97 and 3.96 during the day and night, respectively, indicating the formation of secondary organic aerosols during daytime. Effective carbon ratio was studied to see the effect of aerosols on climate, and its mean value was 0.52 and 1.79 during night and day, indicating the dominance of absorbing and scattering types of aerosols respectively into the atmosphere over the study region. Elemental analysis of individual particles indicates that Si is the most abundant element (~37–90 %), followed by O (oxide) and Al. Circularity and aspect ratio was studied, which indicates that particles are not perfectly spherical and not elongated in any direction. Trajectory analysis indicated that in the months of February and March, air masses appear to be transported from the Middle Eastern part along with neighboring countries and over Thar Desert region, while in January it was from the northeast direction which resulted in high concentrations of fine particles.

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References

  • Agrawal A, Upadhyay VK, Sachdeva K (2011) Study of aerosol behavior on the basis of morphological characteristics during festival events in India. Atmos Environ 45:3640–3644

    Article  CAS  Google Scholar 

  • Andreae MO, Gelencser A (2006) Black carbon or brown carbon, the nature of light absorbing carbonaceous aerosols. Atmos Chem Phys 6:3131–3148

    Article  CAS  Google Scholar 

  • Andreae MO, Rosenfeld D (2008) Aerosol–cloud–precipitation interactions. Part 1. The nature and sources of cloud-active aerosols. Earth-Sci Rev 89(1–2):13–41

    Article  Google Scholar 

  • Ault AP, Peters TM, Sawvel EJ, Casuccio GS, Willis RD, Norris GA, Grassian VH (2012) Single-particle SEM-EDX analysis of iron-containing coarse particulate matter in an urban environment: sources and distribution of iron within Cleveland, Ohio. Environ Sci Technol 46:4331–4339

    Article  CAS  Google Scholar 

  • Awasthi AR, Agarwal SK, Mittal N, Singh K, Gupta PK (2011) Study of size and mass distribution of particulate matter due to crop residue burning with seasonal variation in rural area of Punjab, India. J Environ Monit 13:1073–1081

    Article  CAS  Google Scholar 

  • Begum BA, Hossain A, Nahar N, Markwitz A, Hopke Philip K (2012) Organic and black carbon in PM2.5 at an urban site at Dhaka, Bangladesh. Aerosol Air Qual Res 12:1062–1072

    CAS  Google Scholar 

  • Bernabe JM, Carretero MI, Galan E (2005) Mineralogy and origin of atmospheric particles in the industrial area of Huelva (SWSpain). Atmos Environ 39:6777–6789

    Article  CAS  Google Scholar 

  • Bian H, Tie X, Cao J, Ying Z, Han S, Xue Y (2011) Analysis of a severe dust storm event over China: application of the WRF-Dust model. Aerosol Air Qual Res 11:419–428

    Google Scholar 

  • Birch ME, Cary RA (1996) Elemental carbon-based method for monitoring occupational exposures to particulate diesel exhaust. Aerosol Sci Technol 25:221–241

    Article  CAS  Google Scholar 

  • Bond TC et al (2004) A technology-based global inventory of black and organic carbon emissions from combustion. J Geophys Res 109, D14203

    Article  Google Scholar 

  • Bond TC, Zarzycki C, Flanner MG, Koch DM (2011) Quantifying immediate radiative forcing by black carbon and organic matter with the specific forcing pulse. Atmos Chem Phys 11:1505–1525

    Article  CAS  Google Scholar 

  • Bond TC et al (2013) Bounding the role of black carbon in the climate system: a scientific assessment. J Geophys Res Atmos 118:5380–5552

    Article  CAS  Google Scholar 

  • Campos-Ramos A, Aragón-Piñaa A, Galindo-Estrada I, Querol X, Alastuey A (2009) Characterization of atmospheric aerosols by SEM in a rural area in the western part of México and its relation with different pollution sources. Atmos Environ 43:6159–6167

    Article  CAS  Google Scholar 

  • Central Pollution Control Board (CPCB) (2006) http://www.cpcb.nic.in/S

  • Chandra S, Satheesh SK, Srinivasan J (2004) Can the state of mixing of black carbon aerosols explain the mystery of excess atmospheric absorption. Geophys Res Lett 31, L19109. doi:10.1029/2004GL020662

    Article  Google Scholar 

  • Chelani AB, Gajghate DG, Chalapati Rao CV, Devotta S (2010) Particle size distribution in ambient air of Delhi and its statistical analysis. Bull Environ Contam Toxicol 85:22–27

    Article  CAS  Google Scholar 

  • Delumyea RG, Chu LC, Macias ES (1979) Determination of elemental carbon component of soot in ambient aerosol samples. Atmos Environ 14:647–652

    Article  Google Scholar 

  • Dey S, Girolamo LD, Donkelaar AV, Tripathi SN, Gupta T, Mohan M (2012) Variability of outdoor fine particulate (PM2.5) concentration in the Indian subcontinent: a remote sensing approach. Remote Sens Environ 127:153–161

    Article  Google Scholar 

  • Draxler RR, Rolph GD (2003) HYSPLIT (Hybrid Single Particle Lagrangian Integrated Trajectory) model, report. Air Resource Laboratory, NOAA, Silver Spring (available at http://www.arl.noaa.gov/ready/hysplit4.html). Environ 31:4103–4117

  • Duan JC, Tan JH, Cheng DX, Bi XH, Deng WJ, Sheng GY, Fu JM, Wong MH (2007) Sources and characteristics of carbonaceous aerosol in two largest cities in Pearl River Delta Region, China. Atmos Environ 41(14):2895–2903

    Article  CAS  Google Scholar 

  • Gautam R, Hsu NC, Kafatos M, Tsay SC (2007) Influences of winter haze on fog/low cloud over the Indo-Gangetic plains. J Geophys Res 112:D05207. doi:10.1029/2005JD007036

  • Gehrig R, Hill M, Buchmann B, Imhof D, Weingartner E, Baltensperger U (2004) Separate determination of PM10 emission factors of road traffic for tailpipe emissions and emissions from abrasion and resuspension processes. Int J Environ Pollut 22(3):312–325

    Article  CAS  Google Scholar 

  • Goyal P, Sidharta (2002) Effect of wind on SO2 & SPM concentration in Delhi. Atmos Environ 36:2925–2930

    Article  CAS  Google Scholar 

  • Guttikunda SK, Calori G (2013) A GIS based emissions inventory at 1 km × 1 km spatial resolution for air pollution analysis in Delhi, India. Atmos Environ 67:101–111

    Article  CAS  Google Scholar 

  • Hansen ADA (2005) The aethalometer manual. Magee Scientific, Berkeley

    Google Scholar 

  • Hays DM, Fine MP, Geron DC, Kleeman JM, Gullett KB (2005) Open burning of agriculture biomass: physical and chemical properties of particle-phase emissions. Atmos Environ 39(36):6747–6764

    Article  CAS  Google Scholar 

  • Horvath H (1993) Atmospheric light absorption—a review. Atmos Environ 27A:293–317

    Article  CAS  Google Scholar 

  • Hsieh LT, Yang HH, Lin YC, Tsai CH (2012) Levels and composition of volatile organic compounds from the electric oven during roasting pork activities. Sustain Environ Res 22(1):17–24

    CAS  Google Scholar 

  • Hyvarinen AP, Lihavainen H, Komppula M, Sharma VP, Kerminen VM, Panwar TS, Viisanen Y (2009) Continuous measurements of optical properties of atmospheric aerosols in Mukteshwar, northern India. J Geophys Res 114, D08207. doi:10.1029/2008JD011489

    Google Scholar 

  • Inter Governmental Panel on Climate Change (IPCC) (2007) Changes in atmospheric constituents and in radiative forcing. In: Solomon S et al (eds) Climate change 2007: the physical science basis. Contribution of Working Group I to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge University Press, Cambridge

    Chapter  Google Scholar 

  • Jacobson MZ (2001) Strong radiative heating due to the mixing state of black carbon in atmospheric aerosols. Nature 409:695–697

    Article  CAS  Google Scholar 

  • Jacobson MZ (2006) Effects of externally-through-internally-mixed soot inclusions within clouds and precipitation on global climate. J Phys Chem 110(6860):6873

    Google Scholar 

  • Japar SM, Brachaczek WW, Gorse RA, Norbeck JM, Pierson WR (1986) The contribution of elemental carbon to the optical properties of rural atmospheric aerosols. Atmos Environ 20:1281–1289

    Article  CAS  Google Scholar 

  • Jung KH, Bernabé K, Moors K, Yan B, Chillrud SN, Whyatt R, Camann D, Kinney PL, Perera FP, Miller RL (2011) Effects of floor level and building type on residential levels of outdoor and indoor polycyclic aromatic hydrocarbons, black carbon, and particulate matter in New York City. Atmosphere 2:96–109

    Article  CAS  Google Scholar 

  • Kenny LC, Gussman R, Meyer M (2000) Development of a sharp-cut cyclone for ambient monitoring applications. Aerosol Sci Technol 32(4):338–358

    Article  CAS  Google Scholar 

  • Kirchstetter TW, Harley RA, Kreisberg NM, Stolzenburg MR, Hering SV (1999) On-road measurements of fine particles and nitrogen oxide emissions from light- and heavy-duty motor vehicles. Atmos Environ 33A:2955–2968

    Article  Google Scholar 

  • Lal DM, Patil SD, Singh HN, Ghude SD, Tiwari S, Srivastava MK (2013) Influence of aerosol on clouds over the Indo-Gangetic Plain, India. Clim Dyn 41:601–612

    Article  Google Scholar 

  • Liousse C, Penner JE, Chuang C, Walton JJ, Eddleman H (1996) A global three-dimensional model study of carbonaceous aerosol. J Geophys Res 101(D14):19,411–19,432

    Article  CAS  Google Scholar 

  • Mishra AK, Shibata T (2012) Climatologically aspects of seasonal variation of aerosol vertical distribution over central Indo-Gangetic belt (IGB) inferred by the space-borne lidar CALIOP. Atmos Environ 46:365–375

    Article  CAS  Google Scholar 

  • Moreno T, Gibbons W, Jones T, Richards R (2003) The geology of ambient aerosols: characterizing urban and rural/coastal silicate p M10–2.5 and PM2.5 using high volume cascade collection and scanning electron microscopy. Atmos Environ 37:4265–4276

    Article  CAS  Google Scholar 

  • Pandey P, Khan AH, Verma AK, Singh KA, Mathur N, Kisku GC, Barman SC (2012) Seasonal trends of PM2.5 and PM10 in ambient air and their correlation in ambient air of Lucknow City, India. Bull Environ Contam Toxicol 88(2):265–270

    Article  CAS  Google Scholar 

  • Penner JE, Eddleman H (1993) Towards the development of global inventory for black carbon. Atmos Environ 27A:1277–1295

    Article  CAS  Google Scholar 

  • Pipal AS, Satsangi PG (2015) Study of carbonaceous species, morphology and sources of fine (PM2.5) and coarse (PM10) particles along with their climatic nature in India. Atmos Res 154:103–115

    Article  CAS  Google Scholar 

  • Pipal AS, Kulshrestha A, Taneja A (2011) Characterization and morphological analysis of airbornePM2.5 and PM10 in Agra located in north central India. Atmos Environ 45:3621–3630

    Article  CAS  Google Scholar 

  • Pipal AS, Jan R, Bisht DS, Srivastsvs AK, Tiwari S, Taneja A (2014a) Day and night variability of atmospheric organic and elemental carbon during winter of 2011–12 in Agra, India. Sustain Environ Res 24(2):107–116

    CAS  Google Scholar 

  • Pipal AS, Tiwari S, Satsangi PG, Taneja A, Bisth DS, Srivastava AK, Srivastava MK (2014b) Sources and characteristics of carbonaceous aerosols at Agra “world heritage site” and Delhi, the capital city of India. Environ Sci Pollut Res 21:8678–8691

    Article  CAS  Google Scholar 

  • Pipal AS, Jan R, Satsangi PG, Tiwari S, Taneja A (2014c) Study of surface morphology, elemental composition and origin of atmospheric aerosols (PM2.5 and PM10) over Agra, India. Aerosol Air Qual Res 14:1685–1700

    CAS  Google Scholar 

  • Rastogi N, Sarin MM (2009) Quantitative chemical composition and characteristics of aerosols over western India: one-year record of temporal variability. Atmos Environ 43(22–23):3481–3488

    Article  CAS  Google Scholar 

  • Sachdeva KA, Attri AK (2008) Morphological characterization of carbonaceous aggregates in soot and free fall aerosol samples. Atmos Environ 42:1025–1034

    Article  CAS  Google Scholar 

  • Safai PD, Raju MP, Rao PSP, Pandithurai G (2014) Characterization of carbonaceous aerosols over the urban tropical location and a new approach to evaluate their climatic importance. Atmos Environ. doi:10.1016/j.atmosenv.2014.04.055

    Google Scholar 

  • Salma I, Chi X, Maenhaut W (2004) Elemental and organic carbon in urban canyon and background environments in Budapest, Hungary. Atmos Environ 38:27–36

    Article  CAS  Google Scholar 

  • Sharma M, Maloo S (2005) Assessment of ambient air PM10 and PM2.5 and characterization of PM10 in the city of Kanpur, India. Atmos Environ 39:6015–6026

    Article  CAS  Google Scholar 

  • Sielicki P, Janik H, Guzman A, Namiesnik J (2011) The progress in electron microscopy studies of particulate matters to be used as a standard monitoring method for air dust pollution. Crit Rev Anal Chem 41:314–334

    Article  CAS  Google Scholar 

  • Singh T, Khillare PS, Shridhar V, Agarwal T (2008) Visibility impairing aerosols in the urban atmosphere of Delhi. Environ Monit Assess 141:67–77

    Article  CAS  Google Scholar 

  • Slezakova K, Pires JCM, Pereira MC, Martins FC, Alvim-Ferraz M (2008) Influence of traffic emissions on the composition of atmospheric particles of different sizes—part 2: SEM–EDS characterization. J Atmos Chem 60:221–236

    Article  CAS  Google Scholar 

  • Slezakova K, Pires JCM, Martins FG, Pereira MC, Alvim-Ferraz MC (2011) Identification of tobacco smoke components in indoor breathable particles by SEM-EDS. Atmos Environ 45:863–872

    Article  CAS  Google Scholar 

  • Srivastava A, Jain VK, Srivastava A (2009) SEM-EDX analysis of various sizes aerosols in Delhi India. Environ Monit Assess 150:405–416

    Article  CAS  Google Scholar 

  • Srivastava AK, Singh S, Tiwari S, Bisht DS (2012) Contribution of anthropogenic aerosols in direct radiative forcing and atmospheric heating rate over Delhi in the Indo-Gangetic Basin. Environ Sci Pollut Res 19:1144–1158

    Article  CAS  Google Scholar 

  • Streets GD, Gupta S, Waldhoff TS, Wang QM, Bond CT, Yiyun B (2001) Black carbon emissions in China. Atmos Environ 35:4281–4296

    Article  CAS  Google Scholar 

  • Tiwari S, Singh AK (2013) Variability of aerosol parameters derived from ground and satellite measurements over Varanasi located in the Indo-Gangetic Basin. Aerosol Air Qual Res 13:627–638

    Google Scholar 

  • Tiwari S, Srivastava AK, Bisht DS, Bano T, Singh S, Behura S, Srivastava MK, Chate DM, Padmanabhamurty B (2009) Black carbon and chemical characteristics of PM10 and PM2.5 at an urban site of North India. Int J Atmos Chem 62:3193–3209

    Google Scholar 

  • Tiwari S, Chate DM, Srivastava MK, Safai PD, Srivastava AK, Bisht DS, Padmanabhamurty B (2012) Statistical evaluation of PM10 and distribution of PM1, PM2. 5, and PM10 in ambient air due to extreme fireworks episodes (Diwali festivals) in megacity Delhi. Nat Hazards 61(2):521–531

  • Tiwari S, Srivastava AK, Bisht DS, Parmita P, Srivastava MK, Attri SD (2013a) Diurnal and seasonal variations of black carbon and PM2.5 over New Delhi, India: influence of meteorology. Atmos Res 125–126:50–62

    Article  Google Scholar 

  • Tiwari S, Srivastava AK, Bisht DS, Safai PD, Parmita P (2013b) Assessment of carbonaceous aerosol over Delhi in the Indo-Gangetic Basin: characterization, sources and temporal variability. Nat Hazards 65:1745–1764

    Article  Google Scholar 

  • Tiwari S, Bisht DS, Srivastava AK, Pipal AS, Taneja A, Srivastava MK, Attri SD (2014a) Variability in atmospheric particulates and meteorological effects on its mass concentrations over Delhi, India. Atmos Res 145–146:45–56

    Article  Google Scholar 

  • Tiwari S, Srivastava AK, Chate DM, Safai PD, Bisht DS, Srivastava MK, Beig G (2014b) Impacts of the high loadings of primary and secondary aerosols on light extinction at Delhi during winter-time. Atmos Environ 92:60–68

    Article  CAS  Google Scholar 

  • Tiwari S, Pandithurai G, Attri SD, Srivastava AK, Soni VK, Bisht DS, Kumar AV, Srivastava MK (2015) Aerosol optical properties and their relationship with meteorological parameters during wintertime in Delhi, India. Atmos Res 153:465–479

    Article  CAS  Google Scholar 

  • Zhao X, Zhang X, Xu X, Xu J, Meng W, Pu W (2009) Seasonal and diurnal variations of ambient PM2.5 concentration in urban and rural environments in Beijing. Atmos Environ 43:2893–2900

    Article  CAS  Google Scholar 

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Acknowledgments

The authors gratefully thank the Director of IITM, Pune, for his encouragement and support for doing this study. The corresponding author is thankful to the University Grant Commission (F1-17.1/2011-12/RGNF-SC-UTT-502/(SA-III/website), New Delhi, for financial support. We also acknowledge the use of the HYSPLIT model of NOAA-ARL for back trajectory analysis. The authors are very much thankful to the two anonymous reviewers for their valuable comments/suggestions, which helped to improve the manuscript.

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Tiwari, S., Pipal, A.S., Hopke, P.K. et al. Study of the carbonaceous aerosol and morphological analysis of fine particles along with their mixing state in Delhi, India: a case study. Environ Sci Pollut Res 22, 10744–10757 (2015). https://doi.org/10.1007/s11356-015-4272-6

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