Abstract
Here in this work, gum arabic tree seed shell (bio mass) was utilized to synthesize carbon adsorbents by chemical activation methods at constant carbonization temperature. The properties of the carbon adsorbents were estimated through characterization techniques such as X-ray diffraction, Fourier Transform Infrared spectroscopy, Laser Raman spectroscopy, Field Emission Scanning electron microscopy, CHNS-elemental analysis and N2 adsorption studies. Gum arabic tree seed shell–derived carbon adsorbents were examined for CO2 capture in 25 to 70 °C temperature range. The characterization results indicated that these carbons contain high surface area with micro porosity. Among all the carbons, the carbon prepared after treatment of KOH to biomass ratio is 3:1 followed by and carbonization at 750 °C exhibited high adsorption capacity of 3.42 m.mol/g at 25 °C. The reason for high adsorption capacity of the adsorbents mainly depended on surface area (1472 m2/g) and micropore volume. The adsorbents showed easy desorption and recyclable up to five cycles with consistent activity.
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References
Aksoy, T., Cetin, M., Cabuk, S. N., Senyel Kurkcuoglu, M. A., Bilge Ozturk, G., & Cabuk, A. (2023). Impacts of wind turbines on vegetation and soil cover: A case study of Urla, Cesme, and Karaburun Peninsulas, Turkey. Clean Technologies and Environmental Policy, 25, 51–68. https://doi.org/10.1007/s10098-022-02387-x
Cesur, A., Zeren Cetin, I., Cetin, M., Sevik, H., & Ozel, H. B. (2022). The use of Cupressus arizonica as a biomonitor of Li, Fe, and Cr pollution in Kastamonu. Water, Air, and Soil Pollution, 233, 193. https://doi.org/10.1007/s11270-022-05667-w
Cetin, M., Aljama, A. M. O., Alrabiti, O. B. M., Adiguzel, F., Sevik, H., & Zeren Cetin, I. (2022a). Determination and mapping of regional change of Pb and Cr pollution in Ankara city center. Water, Air, and Soil Pollution, 233, 163. https://doi.org/10.1007/s11270-022-05638-1
Cetin, M., Aljama, A. M. O., Alrabiti, O. B. M., Adiguzel, F., Sevik, H., & Zeren Cetin, I. (2022b). Using topsoil analysis to determine and map changes in Ni Co pollution. Water, Air, and Soil Pollution, 233, 293. https://doi.org/10.1007/s11270-022-05762-y
Cetin, M., Isik Pekkan, O., Bilge Ozturk, G., Senyel Kurkcuoglu, M. A., Kucukpehlivan, T., & Cabuk, A. (2022c). Examination of the change in the vegetation around the Kirka boron mine site by using remote sensing techniques. Water, Air, and Soil Pollution, 233, 254. https://doi.org/10.1007/s11270-022-05738-y
Choma, J., Marszewski, M., Osuchowski, L., Jagiello, J., Dziura, A., & Jaroniec, M. (2015). Adsorption properties of activated carbons prepared from waste CDs and DVDs. ACS Sustain Chem Eng, 3, 733–742. https://doi.org/10.1021/acssuschemeng.5b00036
Cicek, N., Erdogan, M., Yucedag, C., & Cetin, M. (2022). Improving the detrimental aspects of salinity in salinized soils of arid and semi-arid areas for effects of vermicompost leachate on salt stress in seedlings. Water, Air, and Soil Pollution, 233, 197. https://doi.org/10.1007/s11270-022-05677-8
Creamer, A. E., Gao, B., & Zhang, M. (2014). Carbon dioxide capture using biochar produced from sugarcane bagasse and hickory wood. Chemical Engineering Journal, 249, 174–179. https://doi.org/10.1016/j.cej.2014.03.105
Ding, S., & Liu, Y. (2020). Adsorption of CO2 from flue gas by novel seaweed-based KOH-activated porous biochars. Fuel, 260, 116382. https://doi.org/10.1016/j.fuel.2019.116382
Dissanayake, P. D., Choi, S. W., Igalavithana, A. D., Yang, X., Tsang, D. C. W., Wang, C.-H., Kua, H. W., Lee, K. B., & Ok, Y. S. (2020). Sustainable gasification biochar as a high efficiency adsorbent for CO2 capture: A facile method to designer biochar fabrication. Renewable and Sustainable Energy Reviews, 124, 109785. https://doi.org/10.1016/j.rser.2020.109785
Ello, A. S., de Souza, L. K. C., Trokourey, A., & Jaroniec, M. (2013). Development of microporous carbons for CO2 capture by KOH activation of African palm shells. Journal of CO2 Utilization, 2, 35–38. https://doi.org/10.1016/j.jcou.2013.07.003
Ello, A. S., de Souza, L. K. C., Trokourey, A., & Jaroniec, M. (2013b). Coconut shell-based microporous carbons for CO2 capture. Microporous and Mesoporous Materials, 180, 280–283. https://doi.org/10.1016/j.micromeso.2013.07.008
García, S., Gil, M. V., Martín, C. F., Pis, J. J., Rubiera, F., & Pevida, C. (2011). Breakthrough adsorption study of a commercial activated carbon for pre-combustion CO2 capture. Chemical Engineering Journal, 171, 549–556. https://doi.org/10.1016/j.cej.2011.04.027
Guo, Y., Tan, C., Sun, J., Li, W., Zhang, J., & Zhao, C. (2020). Biomass ash stabilized MgO adsorbents for CO2 capture application. Fuel, 259, 116298. https://doi.org/10.1016/j.fuel.2019.116298
Gurten, I. I., Ozmak, M., Yagmur, E., & Aktas, Z. (2012). Preparation and characterisation of activated carbon from waste tea using K2CO3. Biomass and Bioenergy, 37, 73–81. https://doi.org/10.1016/j.biombioe.2011.12.030
Hu, J., Chen, Y., Qian, K., Yang, Z., Yang, H., Li, Y., & Chen, H. (2017). Evolution of char structure during mengdong coal pyrolysis: Influence of temperature and K 2 CO 3. Fuel Processing Technology, 159, 178–186. https://doi.org/10.1016/j.fuproc.2017.01.042
Hu, Y., Lu, H., Liu, W., Yang, Y., & Li, H. (2020). Incorporation of CaO into inert supports for enhanced CO2 capture: A review. Chemical Engineering Journal, 396, 125253. https://doi.org/10.1016/j.cej.2020.125253
Igalavithana, A. D., Mandal, S., Niazi, N. K., Vithanage, M., Parikh, S. J., Mukome, F. N. D., Rizwan, M., Oleszczuk, P., Al-Wabel, M., Bolan, N., Tsang, D. C. W., Kim, K.-H., & Ok, Y. S. (2017). Advances and future directions of biochar characterization methods and applications. Critical Reviews in Environment Science and Technology, 47, 2275–2330. https://doi.org/10.1080/10643389.2017.1421844
Jain, A., Jayaraman, S., Balasubramanian, R., & Srinivasan, M. P. (2014). Hydrothermal pre-treatment for mesoporous carbon synthesis: Enhancement of chemical activation. Journal of Materials Chemistry A, 2, 520–528. https://doi.org/10.1039/C3TA12648J
Jiang, L., Hu, S., Syed-Hassan, S. S. A., Wang, Y., Shuai, C., Su, S., Liu, C., Chi, H., & Xiang, J. (2016). Performance and carbonation kinetics of modified CaO-based sorbents derived from different precursors in multiple CO2 capture cycles. Energy & Fuels, 30, 9563–9571. https://doi.org/10.1021/acs.energyfuels.6b01368
Kaur, B., Gupta, R. K., & Bhunia, H. (2019). Chemically activated nanoporous carbon adsorbents from waste plastic for CO2 capture: Breakthrough adsorption study. Microporous and Mesoporous Materials, 282, 146–158. https://doi.org/10.1016/j.micromeso.2019.03.025
Khan, A. A., de Jong, W., Jansens, P. J., & Spliethoff, H. (2009). Biomass combustion in fluidized bed boilers: Potential problems and remedies. Fuel Processing Technology, 90, 21–50. https://doi.org/10.1016/j.fuproc.2008.07.012
Krapivin, V. F., & Varotsos, C. A. (2016). Modelling the CO2 atmosphere-ocean flux in the upwelling zones using radiative transfer tools. Journal of Atmospheric and Solar-Terrestrial Physics, 150–151, 47–54. https://doi.org/10.1016/j.jastp.2016.10.015
Krapivin, V. F., Varotsos, C. A., & Soldatov, V. Y. (2017). Simulation results from a coupled model of carbon dioxide and methane global cycles. Ecological Modelling, 359, 69–79. https://doi.org/10.1016/j.ecolmodel.2017.05.023
KravkazKuscu, I., Cetin, M., Yigit, N., Savaci, G., & Sevik, H. (2018). Relationship between enzyme activity (urease-catalase) and nutrient element in soil use. Polish Journal of Environmental Studies, 27, 2107–2112. https://doi.org/10.15244/pjoes/78475
Kravkaz-Kuscu, I. S., Sariyildiz, T., Cetin, M., Yigit, N., Sevik, H., & Savaci, G. (2018). Evaluation of the soil properties and primary forest tree species in Taskopru (Kastamonu) district. Fresenius Environmental Bulletin, 27, 1613–1617.
Kumar, S., Srivastava, R., & Koh, J. (2020). Utilization of zeolites as CO2 capturing agents: advances and future perspectives. Journal of CO2 Utilization, 41, 101251. https://doi.org/10.1016/j.jcou.2020.101251
Li, M., & Xiao, R. (2019). Preparation of a dual pore structure activated carbon from rice husk char as an adsorbent for CO2 capture. Fuel Processing Technology, 186, 35–39. https://doi.org/10.1016/j.fuproc.2018.12.015
Libra, J. A., Ro, K. S., Kammann, C., Funke, A., Berge, N. D., Neubauer, Y., Titirici, M.-M., Fühner, C., Bens, O., Kern, J., & Emmerich, K.-H. (2011). Hydrothermal carbonization of biomass residuals: A comparative review of the chemistry, processes and applications of wet and dry pyrolysis. Biofuels, 2, 71–106. https://doi.org/10.4155/bfs.10.81
Liu, Z., Zhang, F.-S., & Wu, J. (2010). Characterization and application of chars produced from pinewood pyrolysis and hydrothermal treatment. Fuel, 89, 510–514. https://doi.org/10.1016/j.fuel.2009.08.042
Liu, Z., Quek, A., Kent Hoekman, S., & Balasubramanian, R. (2013). Production of solid biochar fuel from waste biomass by hydrothermal carbonization. Fuel, 103, 943–949. https://doi.org/10.1016/j.fuel.2012.07.069
Liu, W.-J., Jiang, H., & Yu, H.-Q. (2015). Development of biochar-based functional materials: Toward a sustainable platform carbon material. Chemical Reviews, 115, 12251–12285. https://doi.org/10.1021/acs.chemrev.5b00195
Lopes, F. V. S., Grande, C. A., Ribeiro, A. M., Loureiro, J. M., Evaggelos, O., Nikolakis, V., & Rodrigues, A. E. (2009). Adsorption of H2, CO2, CH4, CO, N2 and H2O in activated carbon and zeolite for hydrogen production. Separation Science and Technology, 44, 1045–1073. https://doi.org/10.1080/01496390902729130
Mallesh, D., Swapna, S., Rajitha, P., & Lingaiah, N. (2022). Termanalia arjuna waste biomass-derived porous activated carbons for efficient CO2 capture. Chemical Engineering and Technology, 45, 2042–2048. https://doi.org/10.1002/ceat.202200208
Maroto-Valer, M. M., Tang, Z., & Zhang, Y. (2005). CO2 capture by activated and impregnated anthracites. Fuel Processing Technology, 86, 1487–1502. https://doi.org/10.1016/j.fuproc.2005.01.003
Nartey, O. D., & Zhao, B. (2014). Biochar preparation, characterization, and adsorptive capacity and its effect on bioavailability of contaminants: An overview. Advances in Materials Science and Engineering, 2014, 1–12. https://doi.org/10.1155/2014/715398
Nelson, K. M., Mahurin, S. M., Mayes, R. T., Williamson, B., Teague, C. M., Binder, A. J., Baggetto, L., Veith, G. M., & Dai, S. (2016). Preparation and CO2 adsorption properties of soft-templated mesoporous carbons derived from chestnut tannin precursors. Microporous and Mesoporous Materials, 222, 94–103. https://doi.org/10.1016/j.micromeso.2015.09.050
Nowrouzi, M., Younesi, H., & Bahramifar, N. (2018). Superior CO2 capture performance on biomass-derived carbon/metal oxides nanocomposites from Persian ironwood by H3PO4 activation. Fuel, 223, 99–114. https://doi.org/10.1016/j.fuel.2018.03.035
Olivares-Marín, M., Drage, T. C., & Maroto-Valer, M. M. (2010). Novel lithium-based sorbents from fly ashes for CO2 capture at high temperatures. International Journal of Greenhouse Gas Control, 4, 623–629. https://doi.org/10.1016/j.ijggc.2009.12.015
Parshetti, G. K., Chowdhury, S., & Balasubramanian, R. (2015). Biomass derived low-cost microporous adsorbents for efficient CO2 capture. Fuel, 148, 246–254. https://doi.org/10.1016/j.fuel.2015.01.032
Patiño, J., Gutiérrez, M. C., Carriazo, D., Ania, C. O., Parra, J. B., Ferrer, M. L., & Del, M. F. (2012). Deep eutectic assisted synthesis of carbon adsorbents highly suitable for low-pressure separation of CO2–CH4 gas mixtures. Energy & Environmental Science, 5, 8699. https://doi.org/10.1039/c2ee22029f
Pekkan, O. I., Senyel Kurkcuoglu, M. A., Cabuk, S. N., Aksoy, T., Yilmazel, B., Kucukpehlivan, T., Dabanli, A., Cabuk, A., & Cetin, M. (2021). Assessing the effects of wind farms on soil organic carbon. Environmental Science and Pollution Research, 28, 18216–18233. https://doi.org/10.1007/s11356-020-11777-x
Rattanaphan, S., Rungrotmongkol, T., & Kongsune, P. (2020). Biogas improving by adsorption of CO2 on modified waste tea activated carbon. Renewable Energy, 145, 622–631. https://doi.org/10.1016/j.renene.2019.05.104
Roth, E. A., Agarwal, S., & Gupta, R. K. (2013). Nanoclay-based solid sorbents for CO2 capture. Energy & Fuels, 27, 4129–4136. https://doi.org/10.1021/ef302017m
Serafin, J., Baca, M., Biegun, M., Mijowska, E., Kaleńczuk, R. J., Sreńscek-Nazzal, J., & Michalkiewicz, B. (2019). Direct conversion of biomass to nanoporous activated biocarbons for high CO2 adsorption and supercapacitor applications. Applied Surface Science, 497, 143722. https://doi.org/10.1016/j.apsusc.2019.143722
Serafin, J., Sreńscek-Nazzal, J., Kamińska, A., Paszkiewicz, O., & Michalkiewicz, B. (2022). Management of surgical mask waste to activated carbons for CO2 capture. J CO2 Util, 59, 101970. https://doi.org/10.1016/j.jcou.2022.101970
Sevilla, M., & Fuertes, A. B. (2011). Sustainable porous carbons with a superior performance for CO2 capture. Energy & Environmental Science, 4, 1765. https://doi.org/10.1039/c0ee00784f
Shahkarami, S., Azargohar, R., Dalai, A. K., & Soltan, J. (2015). Breakthrough CO2 adsorption in bio-based activated carbons. Journal of Environmental Sciences, 34, 68–76. https://doi.org/10.1016/j.jes.2015.03.008
Singh, G., Kim, I. Y., Lakhi, K. S., Srivastava, P., Naidu, R., & Vinu, A. (2017). Single step synthesis of activated bio-carbons with a high surface area and their excellent CO2 adsorption capacity. Carbon N Y, 116, 448–455. https://doi.org/10.1016/j.carbon.2017.02.015
Sircar, S., & Golden, T. C. (1995). Isothermal and isobaric desorption of carbon dioxide by purge. Industrial and Engineering Chemistry Research, 34, 2881–2888. https://doi.org/10.1021/ie00047a042
Stuth, J. W., & Kamau, P. N. (1990). Influence of woody plant cover on dietary selection by goats in an Acacia senegal savanna of East Africa. Small Ruminant Research, 3, 211–225. https://doi.org/10.1016/0921-4488(90)90039-9
Su, F., Lu, C., Cnen, W., Bai, H., & Hwang, J. F. (2009). Capture of CO2 from flue gas via multiwalled carbon nanotubes. Science of the Total Environment, 407, 3017–3023. https://doi.org/10.1016/j.scitotenv.2009.01.007
Sun, H., Wu, C., Shen, B., Zhang, X., Zhang, Y., & Huang, J. (2018). Progress in the development and application of CaO-based adsorbents for CO2 capture—A review. Materials Today Sustainability, 1–2, 1–27. https://doi.org/10.1016/j.mtsust.2018.08.001
Tai, Z., Zhang, Q., Liu, Y., Liu, H., & Dou, S. (2017). Activated carbon from the graphite with increased rate capability for the potassium ion battery. Carbon N Y, 123, 54–61. https://doi.org/10.1016/j.carbon.2017.07.041
Tekin, O., Cetin, M., Varol, T., Ozel, H. B., Sevik, H., & Zeren Cetin, I. (2022). Altitudinal migration of species of fir (Abies spp.) in adaptation to climate change. Water, Air, & Soil Pollution, 233, 385. https://doi.org/10.1007/s11270-022-05851-y
Titirici, M.-M., & Antonietti, M. (2010). Chemistry and materials options of sustainable carbon materials made by hydrothermal carbonization. Chemical Society Reviews, 39, 103–116. https://doi.org/10.1039/B819318P
Tiwari, D., Bhunia, H., & Bajpai, P. K. (2018). Adsorption of CO2 on KOH activated, N-enriched carbon derived from urea formaldehyde resin: Kinetics, isotherm and thermodynamic studies. Applied Surface Science, 439, 760–771. https://doi.org/10.1016/j.apsusc.2017.12.203
Tongpoothorn, W., Sriuttha, M., Homchan, P., Chanthai, S., & Ruangviriyachai, C. (2011). Preparation of activated carbon derived from Jatropha curcas fruit shell by simple thermo-chemical activation and characterization of their physico-chemical properties. Chemical Engineering Research and Design, 89, 335–340. https://doi.org/10.1016/j.cherd.2010.06.012
Umamaheswari, S., & Margandan, M. M. (2013). FTIR spectroscopic study of fungal degradation of poly(ethylene terephthalate) and polystyrene foam. Elixir Chemical Engineering, 64, 19159–19164.
Upendar, K., Sagar, T. V., Raveendra, G., Lingaiah, N., Rao, B. V. S. K., Prasad, R. B. N., & Prasad, P. S. S. (2014). Development of a low temperature adsorbent from karanja seed cake for CO2 capture. RSC Advances, 4, 7142. https://doi.org/10.1039/c3ra45597a
Varol, T., Emir, T., Akgul, M., Ozel, H. B., Acar, H. H., & Cetin, M. (2020). Impacts of small-scale mechanized logging equipment on soil compaction in forests. Journal of Soil Science and Plant Nutrition, 20, 953–963. https://doi.org/10.1007/s42729-020-00182-5
Varol, T., Ozel, H. B., Ertugrul, M., Emir, T., Tunay, M., Cetin, M., & Sevik, H. (2021). Prediction of soil-bearing capacity on forest roads by statistical approaches. Environmental Monitoring and Assessment, 193, 527. https://doi.org/10.1007/s10661-021-09335-0
Varotsos, C. A., & Cracknell, A. P. (2020). Remote Sensing Letters contribution to the success of the sustainable development goals - UN 2030 agenda. Remote Sensing Letters, 11, 715–719. https://doi.org/10.1080/2150704X.2020.1753338
Varotsos, C., Assimakopoulos, M.-N., & Efstathiou, M. (2007). Technical note: Long-term memory effect in the atmospheric CO2; concentration at Mauna Loa. Atmospheric Chemistry and Physics, 7, 629–634. https://doi.org/10.5194/acp-7-629-2007
Varotsos, C., Mazei, Y., & Efstathiou, M. (2020). Paleoecological and recent data show a steady temporal evolution of carbon dioxide and temperature. Atmospheric Pollution Research, 11, 714–722. https://doi.org/10.1016/j.apr.2019.12.022
Wang, T., Zhai, Y., Zhu, Y., Li, C., & Zeng, G. (2018). A review of the hydrothermal carbonization of biomass waste for hydrochar formation: Process conditions, fundamentals, and physicochemical properties. Renewable and Sustainable Energy Reviews, 90, 223–247. https://doi.org/10.1016/j.rser.2018.03.071
Wei, H., Deng, S., Hu, B., Chen, Z., Wang, B., Huang, J., & Yu, G. (2012). Granular bamboo-derived activated carbon for high CO2 adsorption: The dominant role of narrow micropores. Chemsuschem, 5, 2354–2360. https://doi.org/10.1002/cssc.201200570
Zhang, N., Zou, B., Yang, G.-P., Yu, B., & Hu, C.-W. (2017). Melamine-based mesoporous organic polymers as metal-free heterogeneous catalyst: Effect of hydroxyl on CO2 capture and conversion. Journal of CO2 Utilization, 22, 9–14. https://doi.org/10.1016/j.jcou.2017.09.001
Zhao, Y., Liu, X., Yao, K. X., Zhao, L., & Han, Y. (2012). Superior capture of CO2 achieved by introducing extra-framework cations into N-doped microporous carbon. Chemistry of Materials, 24, 4725–4734. https://doi.org/10.1021/cm303072n
Zubbri, N. A., Mohamed, A. R., Lahijani, P., & Mohammadi, M. (2021). Low temperature CO2 capture on biomass-derived KOH-activated hydrochar established through hydrothermal carbonization with water-soaking pre-treatment. Journal of Environmental Chemical Engineering, 9, 105074. https://doi.org/10.1016/j.jece.2021.105074
Cetin M (2013) Landscape engineering, protecting soil, and runoff storm water. In: Advances in Landscape Architecture. InTech
Goskula, S., Siliveri, S., Gujjula, S. R., Chirra, S., & Narayanan, V. (2023) Synthesis of sustainable acid biochar catalysts derived from waste biomass for esterification of glycerol. ChemistrySelect 8. https://doi.org/10.1002/slct.202203662
Wang, L., Tian, C., Wang, B., Wang, R., Zhou, W., & Fu, H. (2008). Controllable synthesis of graphitic carbon nanostructures from ion-exchange resin-iron complex via solid-state pyrolysis process. Chemical Communications 5411. https://doi.org/10.1039/b810500f
Zyavuz, M. (2013). Inventory and analysis of the landscape. In: Advances in Landscape Architecture. InTech, pp 1–26
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The authors sincerely thank the Department of Science and Technology (DST-INSPIRE), Government of India for funding this work through INSPIRE fellowship program (IF160382) and also NIT-Warangal for providing facilities.
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Srinath Goskula: Conceptualization, Investigation, Methodology, Data curation, Formal analysis, Visualization, Writing—original draft, Software.
Suresh Siliveri: Investigation, Methodology, Validation, Resources.
Sripal reddy Gujjula: Investigation, Data curation, Writing-review & editing.
Suman Chirra: Data curation, Formal analysis, Resources.
Ajay kumar Adepu: Formal analysis, Resources.
Venkatathri Narayanan: Writing—review & editing, Project administration, Supervision.
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Goskula, S., Siliveri, S., Gujjula, S.R. et al. Sustainable Development of Activated Porous Carbon Materials from Gum Arabic Tree Seed Shell for CO2 Capture. Water Air Soil Pollut 234, 513 (2023). https://doi.org/10.1007/s11270-023-06529-9
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DOI: https://doi.org/10.1007/s11270-023-06529-9