Abstract
Locally available low-cost material viz. sand from the Kaliani river of Kanaighat area of Golaghat district Assam, India, was collected. The sand was fractionated and the different fractions were characterized by classical chemical analysis, powder XRD, SEM-EDXA, DTA-TGA, and by FT-IR. The chemical analysis of the size fraction of a 600–850-μm range gave more than 90% silica. This fractionated portion was modified by coating with iron oxide. Coating was carried out on the washed and separated sand by repeated treatment of Fe(NO3)3 at 110 and 600 °C, respectively. From FESEM analysis, formation of iron oxide coating over sand surface is clearly observed. The coated sand was used to remove toxic fluoride ion from the drinking water. Iron oxide-coated sand shows highly improved fluoride removal capacity compared to raw sand. The defluoridation capacity of coated sands rose up to 89% from 7% in uncoated raw sand. The effects of different parameters like adsorbent dose, contact time, temperature, initial fluoride concentration, and pH and the effects of different anions present in water along with arsenic on defluoridation capacity of the material were studied in a batch mode.
Similar content being viewed by others
References
Agarwal, M., Rai, K., Shrivastav, R., & Dass, S. (2003). Defluoridation of water using amended clay. J. Cleaner Produc., 11, 439–444.
Al-Rashed, S. M., & Al-Gaid, A. A. (2012). Kinetic and thermodynamic studies on the adsorption behavior of Rhodamine B dye on Duolite C-20 resin. Journal of Saudi Chemical Society, 16(2), 209–215.
Amalraj, A., & Pius, A. (2017). Removal of fluoride from drinking water using aluminum hydroxide coated activated carbon prepared from bark of Morinda tinctoria. Applied Water Science, 7, 2653–2665.
Apshankar Kruttika R., Goel, S.: 2017, Defluoridation of groundwater using electrocoagulation and filtration: efficiency and energy consumption. Journal of Enverionmental Engineering 143(2), February 2017.
Azbar, N., & Turkman, A. (2000). Defluoridation in drinking waters. Water Science and Technology, 42, 403–407.
Baruah, B., Mishra, M., Bhattacharjee, C. R., Nihalani, M. C., Mishra, S. K., Baruah, S. D., Phukan, P., & Goswami, R. L. (2013). The effect of particle size of clay on the viscocity bulid up property of mixed metal hydroxide (MMH) in the low solid-drilling and composition. Applied Clay Science, 80-81, 169–175.
Bejaoui, I., Mnif, A., & Hamroun, B. (2014). Performance of reverse osmosis and nanofiltration in the removal of fluoride from model water and metal packaging industrial effluent. Separation Science and Technology, 49(8), 1135–1145.
Benjamin, M. M., Sletten, R. S., Bailey, R. P., & Bennet, T. (1996). Sorption and filtration of metals using iron oxide coated sand. Water Research, 30(11), 2609–2620.
Brindha, K., Elango, L., 2011. Fluoride in groundwater: causes, implications and mitigation measures. In: Monroy, S.D. (Ed.), Fluoride properties applications and environmental management, 111–136.
Browne, D., Whelton, H., & O’Mullane, D. (2005). Fluoride metabolism and fluorosis. Journal of Dentistry, 33(3), 177–186.
Bureau of Indian Standards (BIS) (1991). 10500:1991, Second Revision ICS No. 13.060.20. http://www.bis.org.in/sf/fad/FAD25(2047)C.pdf. Accessed 6 Jan 2010.
Chai, L., Wang, Y., Zhao, N., Yang, W., & You, X. (2013). Sulfate-doped Fe3O4/Al2O3 nanoparticles as a novel adsorbent for fluoride removal from drinking water. Water Research, 47(12), 4040–4049.
Chen, N., Feng, C., & Li, M. (2014). Fluoride removal on Fe-Al-impregnated granular ceramic adsorbent from aqueous solution. Clean Technologies and Environmental Policy, 16(3), 609–617.
Chen, N., Zhang, Z., Fenga, C., Zhub, D., Yang, Y., & Sugiura, N. (2011). Preparation and characterization of porous granular ceramic containing dispersed aluminum and iron oxides as adsorbents for fluoride removal from aqueous solution. Journal of Hazardous Materials, 186(1), 863–868.
Cornell, R.M., Schwertmann, U.: 1996, The iron oxides, Weinheim (Germany), V C H Publishers. 573.
Czarnowski, W., Wrzesniowska, K., & Krechniak, J. (1996). Fluoride in drinking water and human urine in Northern and Central Poland. Science of the Total Environment, 191, 177–184.
Daifullah, A., Yakout, S., & Elreefy, S. (2007). Adsorption of fluoride in aqueous solutions using KMnO4-modified activated carbon derived from steam pyrolysis of rice straw. Journal of Hazardous Materials, 147(1-2), 633–643.
Dissanayake, C. B. (1991). The fluoride problem in the groundwater of Sri Lanka—environmental management and health. International Journal of Environmental Studies, 19, 195–203.
Dutta, R. K., Saikia, G., Das, B., Bezboruah, C., Das, H. B., & Dube, S. N. (2006). Fluoride contamination in ground water of Central Assam, India. Asian Journal of Water Environment and Pollution, 2(3), 93–100.
Edwards, M., & Benjamin, M. M. (1989). Adsorptive filtration using coated sand: a new approach for treatment of metal bearing wastes. Journal - Water Pollution Control Federation, 61(9), 1523–1533.
Elazhar, E., Tahaikt, M., Zouahri, A., Taky, M., Hafsi, M., & Elmidaoui, A. (2013). Defluoridation of Moroccan groundwater by nanofiltration and electrodialysis: performances and cost comparison. World Applied Sciences Journal, 22(6), 844–850.
Erdem, E., Karapinar, N., & Donat, R. (2004). The removal of heavy metal cations by natural zeolites. Journal of Colloid and Interface Science, 280, 309–314.
Fan, X., Parker, D. J., & Smith, M. D. (2003). Adsorption kinetics of fluoride on low cost materials. Water Research, 37, 4929–4937.
Ford, R. G., & Bertsch, P. M. (1999). Distinguishing between surface and bulk dehydration-dehydroxylation reactions in synthetic goethites by high-resolution thermogravimetric analysis. Clays and Clay Minerals, 47(3), 32–337.
Gandhi, N., Sirisha, D., Asthana, S., Manjusha, A., 2012. Adsorption studies of fluoride on multani matti and red soil. Res. Journal of Chemical Sciences 2, 32–37.
Gandhia, M. R., Kalaivania, G., & Meenakshia, S. (2011). Sorption of chromate and fluoride onto duolite a 171 anion exchange resin—a comparative study. Pollution, 32, 2034–2040.
Ganvir, V., & Das, K. (2011). Removal of fluoride from drinking water using aluminum hydroxide coated rice husk ash. Journal of Hazardous Materials, 185, 1287–1294.
Geethamani, C. K., Ramesh, S. T., Gandhimathi, R., & Nidheesh. (2013). Alkali-treated fly ash for the removal of fluoride from aqueous solutions. Desalination and Water Treatment, 52(19-21), 3466–3476.
Gupta, V. K., Lmran, A., & Sain, V. K. (2007). Defluoridation of wastewaters using waste carbon slurry. Water Research, 41(15), 3307–3316.
Hameed, B. H. (2009). Removal of cationic dye from aqueous solution using jackfruit peel as non-conventional low-cost adsorbent. Journal of Hazardous Materials, 162, 344–350.
Harrison, P. T. C. (2005). Fluoride in water: a UK perspective. Journal of Fluorine Chemistry, 126, 1448–1456.
Ho, Y. S., & McKay, G. (1999). Pseudo-second order model for sorption processes. Process Biochemistry, 34(5), 451–465.
Hu, C. Y., Lo, S. L., Kuan, W. H., & Lee, Y. D. (2005). Removal of fluoride from semiconductor wastewater by electrocoagulation-flotation. Water Research, 39, 895–901.
Indian Standard Methods of Sampling and Test for Water Used in Industry: 1964, 3025.
Indian Standard Classification and Identification of Soils for General Engineering Purposes, First revision 1970, IS 1498.
Jagtap, S., Yenkie, M. K., Labhsetwar, N., & Rayalu, S. (2012). Fluoride in drinking water and defluoridation of water. Chemical Reviews, 112, 2454–2466.
Jiménez, L. V., Fregozo, C. S., Beltrán, M. L. M., Coronado, O. G., & Vega, M. I. P. (2011). Effects of the fluoride on the central nervous system. Neurología, 26, 297–300.
Johnson, A. C., & Bretzler, A. (2015). Eawag, geogenic contamination handbook. Addressing arsenic and fluoride in drinking water. Dubendorf, Switzerland: Swiss federal Institute of Aquatic Science and Technology (Eawag).
Kalkan, N. A., Aksoy, S., Aksoy, E. A., & Hasirci, N. (2012). Preparation of chitosan-coated magnetite nanoparticles and application for immobilization of laccase. Journal of Applied Polymer Science, 123, 707–716.
Kamaraj, R., & Vasudevan, S. (2015a). Decontamination of selenate from aqueous solution by oxidized multi-walled carbon nanotubes. Powder Technology, 274, 268–275.
Kamaraj, R., & Vasudevan, S. (2015b). Evaluation of electrocoagulation process for the removal of strontium and cesium from aqueous solution. Chemical Engineering Research and Design, 93, 522–530.
Khal, H. E., & Batis, N. H. (2015). Effects of temperature on the preparation and characteristics of hydroxyapatite and its adsorptive properties toward lead. New Journal of Chemistry, 39, 3597–3607.
Khan, S. A., Ali, N., & Srivastava, Y. (2015). Comparative study of defluoridation from water using waste materials as adsorbents—a review. IJIET, 6, 159–164.
Kiczka, M., Wiederhold, J. G., Frommer, J., Voegelin, A., Kraemer, S. M., Bourdon, B., & Kretzschmar, R. (2011). Iron speciation and isotope fractionation during silicate weathering and soil formation in an alpine glacier forefield chronosequence. Geochimica et Cosmochimica Acta, 75, 5559–5573.
Kosmulski, M. (2003). A literature survey of the differences between the reported isoelectric points and their discussion. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 222, 113–118.
Ku, Y., & Chiou, H. M. (2002). The adsorption of fluoride ion from aqueous solution by activated alumina. Water, Air, and Soil Pollution, 133, 349–360.
Kumar, E., Bhatnagar, A., Ji, M., Jung, W., Lee, S. H., Kim, S. J., Lee, G., Song, H., Choi, J. Y., Yang, J. S., & Jeon, B. H. (2009). Defluoridation from aqueous solutions by granular ferric hydroxide (GFH). Water Research, 43, 490–498.
Kut, K. M. K., Sarswat, A., Srivastava, A., Charles, U., Pittman Jr., C. U., & Mohan, D. (2016). A review of fluoride in african groundwater and local remediation methods. Groundwater for Sustainable Development, 2-3, 190–212.
Lagergren, S. (1898). About the theory of so called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens Handlingar, 24, 1–39.
Lavecchia, R., Medici, F., Piga, L., Rinaldi, G., & Zuorro, A. (2012). Fluoride removal from water by adsorption on a high alumina content bauxite. Chemical Engineering Transactions, 26, 225–230.
Loganathan, P., Vigneswaran, S., Kandasamy, J., & Naidu, R. (2013). Defluoridation of drinking water using adsorption processes. Journal of Hazardous Materials, 248–249, 1–19.
Malay, K.D., Salim, A.J.: 2011, Comparative study of batch adsorption of fluoride using commercial and natural adsorbent, Res. Journal of Chemical Sciences 1, 68–75.
Mandinic, Z., Curcic, M., Antonijevic, B., Lekic, C. P., & Carevic, M. (2009). Relationship between fluoride intake in Serbian children living in two areas with different natural levels of fluorides and occurrence of dental fluorosis. Food and Chemical Toxicology, 47, 1080–1084.
Meenakshi, S., Sundaram, C. S., & Sukumar, R. (2008). Enhanced fluoride sorption by mechano-chemically activated kaolinites. Journal of Hazardous Materials, 153, 164–172.
Minju, N., Swaroop, K. V., Haribabu, K., Sivasubramanian, V., & Kumar, P. S. (2013). Removal of fluoride from aqueous media by magnesium oxide-coated nanoparticles. Desalination and Water Treatment, 53(11), 2905–2914.
Mohan, D., Singh, K. P., & Singh, V. K. (2008). Wastewater treatment using low cost activated carbons derived from agricultural byproducts—a case study. Journal of Hazardous Materials, 152, 1045–1053.
Nasr, A. B., Charcosset, C., Amar, R. B., & Walha, K. (2013). Defluoridation of water by nanofiltration. Journal of Fluorine Chemistry, 150, 92–97.
Rincon-Silva, N. G., Moreno-Piraján, J. C., Giraldo, L. G.: 2015, Thermodynamic study of adsorption of phenol, 4-chlorophenol, and 4-nitrophenol on activated carbon obtained from eucalyptus seed, Journal of Chemistry. 2015, Article ID 569403, https://doi.org/10.1155/2015/569403
Rudzinski, W., & Plazinski, W. (2007). Studies of the kinetics of solute adsorption at solid/solution interfaces: on the possibility of distinguishing between the diffusional and the surface reaction kinetic models by studying the pseudo-first-order kinetics. Journal of Physical Chemistry C, 111(41), 15100–15110.
Saikia, J., Sarmah, S., Ahmed, T. H., Kalita, P. J., & Goswamee, R. L. (2017). Removal of toxic fluoride ion from water using low cost ceramic nodules prepared from some locally available raw materials of Assam. Journal of Environmental Chemical Engineering, 5, 2488–2497.
Sarmah, S., Saikia, J., Bordoloi, D., & Goswamee, R. L. (2017). Surface modification of paddy husk ash by hydroxyl-alumina coating to develop an efficient water defluoridation media and the immobilization of the sludge by lime-silica reaction. Journal of Environmental Chemical Engineering. https://doi.org/10.1016/j.jece.2017.08.032.
Sasaki, K., Fukumoto, N., Moriyama, S., Yu, Q., & Hirajima, T. (2012). Chemical regeneration of magnesium oxide used as a sorbent for fluoride. Separation and Purification Technology, 9(8), 24–30.
Singh, B., Gaur, S., & Garg, V. K. (2007). Fluoride in drinking water and human urine in Southern Haryana, India. Journal of Hazardous Materials, 144, 147–151.
Shukla S. C. (2014) Development, Safety evaluation and comparative studies of low cost adsorbent technology for arsenic removal from drinking water Ph D Thesis, Hemwati Nandan Bahuguna Garhwal University; Srinagar (Garwahl); Uttaranchal.
Thirunavukkarasu, O. S., Viraraghavan, T., & Subramanian, K. S. (2003). Arsenic removal from drinking water using iron oxide-coated sand. Water, Air, and Soil Pollution, 142, 95–111.
Umlong, I. M., Das, B., Devi, R. R., Borah, K., Saikia, L. B., Raul, P. K., & Singh, S. B. L. (2012). Defluoridation from aqueous solution using stone dust and activated alumina at a fixed ratio. Applied Water Science, 2, 29–36.
Viswanathan, N., & Meenakshi, S. (2008). Effect of metal ion loaded in a resin towards fluoride retention. Journal of Fluorine Chemistry, 129, 645–653.
Viswanathan, N., Prabhu, S. M., & Meenakshi, S. (2013). Development of amine functionalized co-polymeric resins for selective fluoride sorption. Journal of Fluorine Chemistry, 153, 143–150.
Waghmare, S. S., & Arfin, T. (2015). Fluoride removal from water by calcium materials: a state-of-the-art review. International Journal of Innovative Research in Science, Engineering and Technology, 4(9), 2347–6710.
Wambu, E. W., Onindo, C. O., Ambusso, W., & Muthakia, G. K. (2012). Removal of fluoride from aqueous solutions by adsorption using a siliceous mineral of a Kenyan origin. Clean Soil, Air, Water, 41(4), 340–348.
Wan, S. L., He, F., Wu, J. Y., Wan, W. B., Gu, Y. W., & Gao, B. (2016). Rapid and highly selective removal of lead from water using graphene oxide-hydrated manganese oxide nanocomposites. Journal of Hazardous Materials, 314, 32–40.
Wang, B., Zheng, B., Zhai, C., Yu, G., & Liu, X. (2004). Relationship between fluorine in drinking water and dental health of residents in some large cities in China. Environment International, 30, 1067–1073.
Wang, W. Y., Li, R. B., Tan, J. A., Luo, K. L., Yang, L. S., Li, H. R., & Li, Y. H. (2002). Adsorption and leaching of fluoride in soils of China. Fluoride, 35, 122–129.
Weber, W. J., & Morris, J. C. (1963). Kinetics of adsorption on carbon from solutions. Journal of the Sanitary Engineering Division American Society of Civil Engineers, 89(SA2), 31.
Yadav, A. K., Kaushik, C. P., Haritash, A. K., Kansal, A., & Rani, N. (2006). Defluoridation of groundwater using brick powder as an adsorbent. Journal of Hazardous Materials, 128, 289–293.
Ying, X., & Lisa, A. (2005). Synthesis and characterization of iron oxide-coated silica and its effect on metal adsorption. Journal of Colloid and Interface Science, 282, 11–19.
Zhang, J., Chen, N., Tang, Z., Yu, Y., Hua, Q., & Feng, C. (2015). A study of the mechanism of fluoride adsorption from aqueous solutions onto Fe-impregnated chitosan. Physical Chemistry Chemical Physics, 17, 12041–12050.
Acknowledgements
Authors are very thankful to the Director, CSIR-NEIST, Jorhat, Assam, India, for providing facilities for the work and allowing to publish the work, Nagaland University for allowing to register under Ph.D. program, and CSIR project CSC 408 for the infrastructural facilities. Author CG is also grateful to Principal CNB College Bokakhat, Golaghat, Assam, for giving permission to carry out the work as a part of a faculty improvement of the Chemistry Department.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Gogoi, C., Saikia, J., Sarmah, S. et al. Removal of Fluoride from Water by Locally Available Sand Modified with a Coating of Iron Oxides. Water Air Soil Pollut 229, 118 (2018). https://doi.org/10.1007/s11270-018-3754-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11270-018-3754-9