Abstract
The unique characteristics of atmospheric aerosol in the northern foot of Mt. Fuji, central Japan were first clarified. The Mt. Fuji (an altitute of 3776 m) is the largest basaltic stratovolcano in the quaternary period in Japan. The aerosol measurements were carried out at an altitute of 1100 m from June 2000 to April 2001. Ambient aerosol in the predominant area of a typical volcanic rock like basalt was referred to as a basaltic aerosol in this study. Fifteen elements (Na, Mg, Al, Si, K, Ca, Ti, V, Cr, Mn, Fe, Cu, Zn, Ba, Pb) of major to trace in the aerosol samples were determined by X-ray fluorescence spectrometry. Total mass concentration (< 10 μm) of the basaltic aerosol showed the higher values in summer and spring rather than autumn to winter, and the seasonal variation pattern differed widely from that of general urban aerosol. The behavior of the basaltic aerosol was mainly controlled by mineral particles throughout the year, so that a typical anthropogenic-derived element like Pb was very rarely detected. Even V, Cr and Zn which have been generally considered to be typical anthropogenic-derived elements, showed crustal-like behaviors. A concentration ratio of Si/Al showed markedly a uniqueness of the basaltic aerosol. From a comparison with atmospheric aerosol Si/Al ratio in granitic region being an exact opposite geology, a correlation plot of Si/Al ratio against Si concentration was made. It showed a big regional difference available for source identification of atmospheric soil particles. The chemical and geological characteristics of the basaltic aerosol are very useful for the novel characterization of atmospheric soil particles.
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References
Blank, M., Leinen, M. and Prospero, J. M.: 1985, ‘Major Asian aeolian inputs indicated by the mineralogy of aerosoles and sediments in the western North Pacific’, Nature 314, 84–86.
Committee of Certified Reference Materials, National Research Center for Environmental Analysis and Measurement, P.R. China: 1999, Certificate of Analysis, Certified Reference Material CJ-1(China Loess) and CJ-2 (Simulated Asian Mineral Dust).
Dokiya, Y., Yoshikawa, T., Komada, T., Suzuki, I., Naemura, A., Hayashi, K., Naoe, H., Sawa, Y., Sekiyama, T. and Igarashi, Y.: (2001), ‘Atmospheric chemistry at the summit of Mt. Fuji: A challenging field for analytical chemists’, Analytical Sciences 17(supplement), i809–i812.
Duce, R. A., Unni, C. K., Ray, B. J., Prospero, J. M. and Merrill, J. T.: 1980, ‘Long-range atmospheric transport of soil dust from Asia to the tropical North Pacific: Temporal variability’, Science 209, 1522–1524.
Gao, Y., Nelson, E. D., Field, M. P., Ding, Q., Li, H., Sherrell, R. M., Gigliotti, C. L., Van Ry, D. A., Glenn, T. R. and Eisenreich, S. J.: 2002, ‘Characterization of atmospheric trace elements on PM2.5 particulate matter over the New York-New Jersey harbor estuary’, Atmospheric Environment 36, 1077–1086.
Gordon, G. E., Pierson, W. R., Daisey, J. M., Lioy, P. J., Cooper, J. A., Watson, J. G. and Cass, G. R.: 1984, ‘Considerations for design of source apportionment studies’, Atmospheric Environment 18, 1567–1582.
Imai, N., Terashima, S., Itoh, S. and Ando, A.: 1995, ‘1994 compilation values for GSJ reference samples, “Igneous rock seriess”’, Geochemical Journal 29, 91–95.
Ishizaka, Y. and Ono, A.: 1982, ‘Mass size distribution of the principal minerals of yellow sand dust in the air over Japan’, Idojaras 86, 249–253.
Iwasaka, Y., Minoura, H. and Nagaya, K.: 1979, ‘The transport and spacial scale of Asian dust-storm clouds: a case study of the dust-storm event of April’, Tellus 35B, 189–196.
Iwatsuki, M., Kyotani, T. and Koshimizu, S.: 1997, ‘A simple preparation method of thin-layer standard samples with activated carbon for the multi-element determination of airborne particulate matter by X-ray spectrometry’, Analytical Sciences 13, 807–813.
Kadowaki, S.: 1979, ‘Silicon and aluminum in urban aerosols for characterization of atmospheric soil particles in the Nagoya area’, Environmental Science & Technology 13, 1130–1133.
Kaneyasu, N., Yoshikado, H. and Kondo, H.: 2002, ‘Analysis on the major chemical composition and the estimation of water content in SPM collected in the extensive and highly time-resolved measurement during an early-winter severe pollution episode’, Journal of Japan Society for Atmospheric Environment 37, 108–121 (in Japanese).
Kyotani, T. and Iwatsuki, M.: 1998, ‘Multi-element analysis of environmental samples by X-ray fluorescence spectrometry using a simple thin-layer sample preparation technique’, Analyst 123, 1813–1816.
Kyotani, T. and Iwatsuki, M.: 2000, ‘Characteristics and seasonal variations in mass and multi-element concentrations of ambient fine and coarse particles – A case study at Kofu City-’, Journal of Japan Society for Atmospheric Environment 35, 287–300 (in Japanese).
Kyotani, T. and Koshimizu, S.: 2001, ‘Identification of individual Si-rich particles derived from Kosa aerosol by the alkali elemental composition’, Bulletin of the Chemical Society of Japan 74, 723–729.
Kyotani, T. and Iwatsuki, M.: 2002, ‘Characterization of soluble and insoluble components in PM2.5 and PM10 fractions of airborne particulate matter in Kofu City, Japan’, Atmospheric Environment 36, 639–649.
Lee, H. S. and Kang, B.-W.: 2001, ‘Chemical characteristics of principal PM2.5 species in Chongju, South Korea’, Atmospheric Environment 35, 739–746.
Leinen, M., Prospero, J. M., Arnold, E. and Blank, M.: 1994, ‘Mineralogy of aeolian dust reaching the North Pacific ocean 1. Sampling and analysis’, Journal of Geophysical. Research 99, 21017–21023.
Manoli, E., Voutsa, D. and Samara, C.: 2002, ‘Chemical characterization and source identification/apportionment of fine and coarse air particles in Thessaloniki, Greece’, Atmospheric Environment 36, 949–961.
Merrill, J. T., Arnold, E., Leinen, M. and Weaver, C.: 1994, ‘Mineralogy of aeolian dust reaching the North Pacific Ocean 2. Relationship of mineral assemblages to atmospheric transport patterns’, Journal of Geophysical. Research 99, 21025–21032.
Mizohata, A., Matsuda, Y., Sakamoto, K. and Kadowaki, S.: 1986, ‘Chemical composition of particulate air pollutants’, Journal of Japan Society for Air Pollution 21, 83–103 (in Japanese).
Nishikawa, M., Kanamori, S., Kanamori, N. and Mizoguchi, T.: 1991, ‘Kosa aerosol as eolian carrier of anthropogenic material’, The Science of the Total Environment 107, 13–27.
Querol, X., Alastuey, A., Rodriguez, S., Plana, F., Mantilla, E. and Ruiz, C. R.: 2001a, ‘Monitoring of PM10 and PM2.5 around primary particulate anthropogenic emission sources’, Atmospheric Environment 35, 845–858.
Querol, X., Alastuey, A., Rodriguez, S., Plana, F., Ruiz, C. R., Cots, N., Massague, G. and Puig, O.: 2001b, ‘PM10 and PM2.5 source apportionment in the Barcelona Metropolitan area, Catalonia, Spain’, Atmospheric Environment 35, 6407–6419.
Saitoh, K., Sera, K., Shirai, T., Sato, T. and Odaka, M.: 2003, ‘Determination of elemental and ionic compositions for diesel exhaust particles by particle induced X-ray emission and ion chromatography analysis’, Analytical Sciences 19, 525–528.
Tago, H., Imai, K., Ohtani, Y. and Shimada, Y.: 2003, ‘The effects of eruptions of Miyakejima on the fog water at Mt.Akagi’, Journal of Japan Society for Atmospheric Environment 38, 339–346 (in Japanese).
Taylor, S. R. and McLennan, S. M.: 1985, In: The Continental Crust: Its Composition and Evolution. Blackwell, Oxford, pp. 312.
Uematsu, M., Duce, R. A., Prospero, J. M., Chen, L., Merrill, J. T. and McDonald, R. L.: 1983, ‘Transport of mineral aerosol from Asia over the North Pacific Ocean’, Journal of Geophysical. Research 88, 5343–5352.
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Kyotani, T. Characterization of Atmospheric Aerosol in the Northern Foot of Mt. Fuji, Central Japan. Water Air Soil Pollut 164, 43–56 (2005). https://doi.org/10.1007/s11270-005-2252-z
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DOI: https://doi.org/10.1007/s11270-005-2252-z