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CT Imaging of Low-Permeability, Dual-Porosity Systems Using High X-ray Contrast Gas

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Abstract

Low-permeability, dual-porosity media such as coal and gas shale (i.e., mudstone) exhibit structural and chemical features across a range of scales spanning from tens of meters to nanometers. Characterization methods and efforts for these porous media are needed to understand gas in place, gas flow behavior, and storage capacity for potential CO\(_{2}\) sequestration. Characterizing the structure and heterogeneity of representative samples helps determine how the physical and chemical processes associated with CO\(_{2}\) transport in coal and gas shale affect injectivity and storage capacity (over long periods of time), and the ability of these media to sequester CO\(_{2}\) (as both a free and adsorbed phase) for thousands of years. In this study, an imaging technique focused on the submillimeter scale is applied to shale and coal samples of interest. In particular, porosity, component matrix distribution, and evidence of gas transport through these tight media were studied.

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References

  • Akin, S., Schembre, J.M., Bhat, S.K., Kovscek, A.R.: Spontaneous imbibition characteristics of diatomite. J. Pet. Sci. Eng. 25, 149–165 (2000)

    Article  Google Scholar 

  • Akin, S., Kovscek, A.R.: Computed Tomography in Petroleum Engineering Research. Applications of X-ray Computed Tomography in the Geosciences. Geological Society, London, Special Publications, 215, pp. 23–28 (2003)

  • Akkutlu, Y., Fathi, E.: Multi-scale gas transport in shales with local Kerogen heterogeneities. Paper SPE 146422 presented Annual Technical Conference and Exhibition held in Denver, CO. 30 Oct–2 Nov (2011)

  • Ambrose, R.J., Hartman, R.C., Diaz-Campos, M., Akkutlu, Y., Sondergeld, C.H.: New Pore-scale considerations for shale gas in place calculations. Paper SPE 131772 presented at the SPE Unconventional Gas Conference held in Pittsburgh, PA, 23–25 Feb (2010)

  • Clarkson, C.R., Bustin, R.M.: The effect of pore structure and gas pressure upon the transport properties of coal: a laboratory and modeling study. 2. Adsorption rate modeling. Fuel 78, 1345–1362 (1999)

    Article  Google Scholar 

  • Curtis, M.E., Ambrose, R.J., Sondergeld, C.H., Rai, C.S.: Structural characterization of gas shales on the micro- and nano-scales. Paper SPE 137693 presented at the Canadian Unconventional Resources & International Petroleum Conference held in Calgary, Canada, 19–21 Oct (2010)

  • Curtis, M.E., Ambrose, R.J., Sondergeld, C.H., Rai, C.S.: Transmission and scanning electron microscopy investigation of pore connectivity of gas shales on the nanoscale. Paper SPE 144391 presented at the SPE North American Unconventional Gas Conference and Exhibition held in The Woodlands, TX, 14–16 Jun (2011)

  • Dutta, A.: Multicomponent gas diffusion and absorption in coals for enhanced methane recovery. Master thesis report, Stanford University (2009)

  • Elgmati, M., Zhang, H., Bai, B., Flori, R., Qu, Q.: Submicron-pore characterization of shale gas plays. Paper SPE 144050 presented at the SPE North American Unconventional Gas Conference and Exhibition held in The Woodlands, TX, 14–16 Jun (2011)

  • Harris, J, Kovscek, A.R., Orr, F.M., Zoback, M.D.: Geologic storage of carbon dioxide. Technical Report of the Global Climate and Energy Project, Stanford University. http://gcep.stanford.edu/research/technical_report/20012.html (2008)

  • Honarpour, M.M., Cromwell, V., Hatton, D., Satchwell, R.: Reservoir rock descriptions using computed tomography (CT). Paper SPE 14272 presented at the SPE Annual Technical Conference and Exhibition held in Las Vegas, NV, 22–25 Sep (1985)

  • IPCC.: Special report on carbon dioxide capture and storage. Ch. 5: underground geological storage (2005)

  • IUPAC: recommendations for the characterization of porous solids. Pure Appl. Chem. 66(8), 1739–1758 (1994)

    Google Scholar 

  • Jessen, K., Tang, G.-Q., Kovscek, A.R.: Laboratory and simulation investigation of enhanced coalbed methane recovery by gas injection. Transp. Porous Media 73(2), 141–159 (2008)

    Article  Google Scholar 

  • Kang, S.M., Fathi, E., Ambrose, R.J., Akkutlu, I.Y., Sigal, R.F.: Carbon dioxide storage capacity of organic-rich shales. Paper SPE 134583 presented at the Annual Technical Conference and Exhibition held in Houston, TX, 3–6 Oct (2010)

  • Karacan, C.O., Okandan, E.: Heterogeneity effects on the storage and production of Gas from coal seams. Paper SPE 56551 presented at the Annual Technical Conference and Exhibition held in Florence, Italy, 19–22 Sep (1999)

  • King, G.R., Ertekin, T., Schwerer, F.: Numerical simulation of the transient behavior of coal-seam degasification wells. SPE Formation Evaluation 2(1), 165–183 (1986)

    Google Scholar 

  • Laxminarayana, C., Crosdale, P.J.: Role of coal type and rank on methane sorption characteristics of Bowen Basin, Australia. Int. J. Coal Geol. 40, 309–325 (1990)

    Article  Google Scholar 

  • Le Guen, S.S., Kovscek, A.R.: Non-equilibrium effects during spontaneous imbibition. Transp. Porous Media 63, 127–146 (2006)

    Google Scholar 

  • Lin, W., Tang, G.-Q., Kovscek, A.R.: Sorption-induced permeability change of coal during gas-injection processes. SPE Reserv. Eval. Eng. 11(4), 792–802 (2008)

    Google Scholar 

  • Lu, X.C., Pepin, G.P., Moss, R.M., Watson, A.T.: Determination of gas storage in Devonian shales with X-ray-computed tomography. Paper SPE 24810 presented at the 67th Annual Technical Conference and Exhibition held in Washington, DC, 4–7 Oct (1992)

  • Lu, X., Miao, P., Watson, A.T., Pepin, G.P., Moss, R.M., Semmelbeck, M.: X-ray computerized tomography studies of gas storage and transport in Devonian shales. AIChE J. 40(7), 1246–1253 (1994)

    Google Scholar 

  • Moss, R.M., Pepin, G.P., Davis, L.A.: Direct measurement of the constituent porosities in a dual-porosity matrix. Log Analyst. 33(2), 126–135 (1992)

    Google Scholar 

  • Nuttall, B., Drahovzal, J., Eble, C. Bustin, R.: Analysis of Devonian black shales in Kentucky for potential carbon dioxide sequestration and enhanced natural gas production. Final Report to U.S. Department of Energy. http://www.osti.gov/scitech/biblio/920185 (2005)

  • Rice, D.D.: Composition and origins of coalbed gas. In: Law, B.E., Rice, D.D. (eds) Hydrocarbons from Coal. AAPG Studies in Geology, 38, 159–185 (1993)

  • Saites, F, Wang, G., Guo, R., Mannhardt, A., Kantzas, A.: Coalbed characterization studies with X-ray computerized tomography (CT) and micro CT techniques. Paper 2006–027 presented at the Canadian International Petroleum Conference held in Calgary, Canada, 13–15 Jun (2006)

  • Shi, J.Q., Durucan, S.: Modeling mixed-gas adsorption and diffusion in coalbed reservoirs. SPE 114197, paper presented at the SPE Unconventional Reservoirs Conference held in Keystone, CO (2008)

  • Sondergeld, C.H., Ambrose, R.J., Rai, C.S.: Micro-structural studies of gas shales. Paper SPE 131771 presented at the SPE Unconventional Gas Conference held in Pittsburgh, PA, 23–25 Feb (2010)

  • Vega, B., Andrews, J.C., Liu, Y., Gelb, J., Kovscek, A.R.: Nanoscale visualization of gas shale pore and textural features. In: Proceedings of the Unconventional Resources Technology Conference held in Denver, Colorado, USA, 12–14 Aug (2013)

  • Vinegar, H.J., Wellington, S.L.: Tomographic imaging of three-phase flow experiments. Rev. Sci. Instrum. 58, 96–107 (1987)

    Article  Google Scholar 

  • Wang, F.P., Reed, R.M.: Pore networks and fluid flow in gas shales. Paper SPE 124253 presented at the Annual Technical Conference and Exhibition held in New Orleans, LA, 4–7 Oct (2009)

  • Watson, A.T., Mudra, J.: Characterization of devonian shales with X-ray computed tomography. SPE Form. Eval. 9(3), 209–212 (1994)

    Google Scholar 

  • Whithjack, E.M.: Computed tomography for rock property determination and fluid flow visualization. Soc. Pet. Eng. Form. Eval. 3, 696–705 (1988)

    Google Scholar 

  • Whithjack, E., Devier, C., Michael, G.: The role of X-ray computed tomography in core analysis. Paper SPE 83467 presented at the SPE Western Regional/AAPG Pacific Section Joint Meeting held in Long Beach, CA, 19–24 May (2003)

  • Wong, S., Gunter, W.D., Mavor, M.J.: Economics of CO\(_{2}\) sequestration in coalbed methane reservoirs. SPE 59785, presented at the 2000 SPE/CERI Gas Technology Symposium held in Calgary, Alberta Canada (2000)

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Acknowledgments

A portion of this work was prepared with the support of the US Department of Energy under Award No. DE-FE-0004731. However, any opinions, findings, conclusions, or recommendations expressed herein are those of the authors and do not necessarily reflect the views of the DOE. Additional financial support was provided by the Stanford University Petroleum Research Institute (SUPRI-A) Industrial Affiliates. We also acknowledge C. Ross who provided SEM analysis of the Barnett core sample.

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Correspondence to Anthony R. Kovscek.

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Vega, B., Dutta, A. & Kovscek, A.R. CT Imaging of Low-Permeability, Dual-Porosity Systems Using High X-ray Contrast Gas. Transp Porous Med 101, 81–97 (2014). https://doi.org/10.1007/s11242-013-0232-0

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