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A novel polyoxometalate chain constructed from sandwich lanthanide-containing polyanions [Pr(PW11O39)2]11− and sodium cation linkers

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Abstract

A novel sandwich-type lanthanide polyoxometalate [(CH3)4NH]4Na3[Pr(PW11O39)2] · 12H2O (1) has been synthesized by conventional method and characterized by cyclic voltammetry, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction result reveals that the sandwich type polyanions are linked by sodium cations to form a structure of zigzag chains, and the chains are further connected into an extensive two-dimensional (2D) framework depending on hydrogen bond. The emission spectrum result shows weak photoluminescence of compound 1. The magnetic studies of compound 1 demonstrate an antiferromagnetic interaction in 1.

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References

  1. (a) Hill CL (1998) Chem Rev 98:1; (b) Pope MT, Müller A (1991) Angew Chem Int Ed 30:34–38

  2. (a) Yamase T (1998) Chem Rev 98:307–325; (b) Xu L, Zhang HY, Wang EB, Kurth DG, Li Z (2002) J Mater Chem 12:654–657; (c) Yamase T, Fukaya K, Nojiri H, Ohshima Y (2006) Inorg Chem 45:7698–7704; (d) Clemente-Juan JM, Andres H, Almenar B, Coronado E (1999) J Am Chem Soc 121:10021–10027

  3. Sadakane M, Dickman MH, Pope MT (2000) Angew Chem Int Ed 39:2914–2916

    Article  CAS  Google Scholar 

  4. Drewes D, Limanski EM, Krebs B (2004) Eur J Inorg Chem 4849–4853

  5. An HY, Xiao DR, Wang EB, Li YG, Wang XL, Xu L (2005) Eur J Inorg Chem 854–859

  6. Mialane P, Lisnard L, Mallard A, Marrot J, Antic-Fidancev E, Aschehoug P, Vivien D, Sécheresse F (2003) Inorg Chem 42:2102–2108

    Article  CAS  Google Scholar 

  7. Howell RC, Perez FG, Jain S, Horrocks WD, Rheingold AL, Francesconi LC (2001) Angew Chem Int Ed 40:4031–4033

    Article  CAS  Google Scholar 

  8. Honma N, Kusaka K, Ozeki T (2002) Chem Commun 2896–2897

  9. Chiba H, Wada A, Ozeki T (2006) J Chem Soc Dalton Trans 1213–1217

  10. Fan LH, Xu L, Gao GG, Li FY, Li ZK, Qiu YF (2006) Inorg Chem Commun 9:1308–1311

    Article  CAS  Google Scholar 

  11. Finke RG, Droege MW, Domaille PJ (1987) Inorg Chem 26:3886–3896

    Article  CAS  Google Scholar 

  12. Pope MT (1983) Heteropoly and Isopolyoxometalates. Springer, Berlin

    Google Scholar 

  13. Zhang C, Howell RC, Scotland KB, Perez FG, Todaro L, Francesconi LC (2004) Inorg Chem 43:7691–7701

    Article  CAS  Google Scholar 

  14. Copping R, Gaunt AJ, May I, Sarsfield MJ, Collison D, Helliwell M, Denniss IS, Apporley DC (2005) J Chem Soc Dalton Trans 1256–1262

  15. Krivovichev SV, Burns PC (2003) Solid State Sci 5:373

    Article  CAS  Google Scholar 

  16. Gaunt AJ, May I, Sarsfield MJ, Collision D, Helliwell M, Denniss IS (2003) J Chem Soc Dalton Trans 2767–2771

  17. Niu JY, Zhao JW, Wang JP (2004) Inorg Chem Commun 7:876–879

    Article  CAS  Google Scholar 

  18. Sadakane M, Steckhan E (1998) Chem Rev 1:219–237

    Article  Google Scholar 

  19. Yan B, Wang WJ, Song YS (2007) Spectrochimica Acta Part A 66:1115–1121

    Article  Google Scholar 

  20. Bris KL, Reber C (2006) J Alloys Compd 424:237–242

    Article  Google Scholar 

Download references

Acknowledgments

The authors are thankful for the financial supports from the National Natural Science Foundation of China (Grant No. 20671017) and the Specialized Research Fund for the Doctoral Program of Higher Education.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, 130024, P.R. China

    Li-Hua Fan, Lin Xu, Chun-Hua Zhang, Feng-Yan Li, Zhi-Kui Li & Xi-Zheng Liu

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  1. Li-Hua Fan
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  2. Lin Xu
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  3. Chun-Hua Zhang
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  4. Feng-Yan Li
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Correspondence to Lin Xu.

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Fan, LH., Xu, L., Zhang, CH. et al. A novel polyoxometalate chain constructed from sandwich lanthanide-containing polyanions [Pr(PW11O39)2]11− and sodium cation linkers. Struct Chem 18, 917–921 (2007). https://doi.org/10.1007/s11224-007-9214-6

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  • DOI: https://doi.org/10.1007/s11224-007-9214-6

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