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Assessment of Electrochemical Characteristics of BMIMBF4 and Polymer Electrolyte Based on it

  • PHYSICS OF SEMICONDUCTORS AND DIELECTRICS
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Russian Physics Journal Aims and scope

The electrochemical properties of the BMIMBF4 ionic liquid in a PVDF-co-HFP polymer matrix are studied. The issues related to aqueous and non-aqueous electrolytes and the advantages of solid-state electrolytes and ionic liquids are discussed. The method for producing a polymer electrolyte based on PVDF-co-HFP with an introduction of BMIMBF4 and LiBF4 is described. The techniques for preparing and analyzing the samples using NMR spectroscopy, impedance spectroscopy, DSC analysis, etc. are detailed. The CV results and impedance data of BMIMBF4 are presented and discussed, which indicate a high electrochemical stability. The temperature curves of the polymer electrolyte conductivity are presented, and the activation energy of ion transfer is calculated.

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References

  1. G. Tian, Ionic Liquids for Supercapacitors, in: Sustainable Materials for Electrochemical Capacitors, Wiley (2023). https://doi.org/10.1002/9781394167104.

  2. K. Karuppasamy et al., Polymers, 12, No. 4, 918 (2020). https://doi.org/10.3390/polym12040918.

    Article  Google Scholar 

  3. C. Du et al., Ionic liquid electrolytes for graphene-based supercapacitors with an ultrahigh energy density, The Royal Society of Chemistry (2019). https://doi.org/10.1039/9781788016193-00095.

    Article  Google Scholar 

  4. I. Kim et al., Materials, 11, No. 4, 543 (2018). https://doi.org/10.3390/ma11040543.

    Article  ADS  Google Scholar 

  5. A. V. Budaev et al., Plasticheskie massy, No. 7-8, (2022). https://doi.org/10.35164/0554-2901-2022-7-8-30-32.

  6. Y. Hu et al., Chemistry – An Asian Journal, 17, No. 23, e202200794 (2022). https://doi.org/10.1002/asia.202200794.

    Article  Google Scholar 

  7. A. A. Krupina et al., Membranes, 12, No. 9, 840 (2022). https://doi.org/10.3390/membranes12090840.

    Article  Google Scholar 

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Authors and Affiliations

  1. Federal State Autonomous Educational Institution of Higher Education M. K. Ammosov North-Eastern Federal University, Yakutsk, Russia

    E. D. Vasileva & A. N. Ivanov

  2. Institute of Oil and Gas Problems of the Siberian Branch of the Russian Academy of Sciences, Yakutsk, Russia

    S. I. Sivtsev

Authors
  1. E. D. Vasileva
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  2. A. N. Ivanov
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  3. S. I. Sivtsev
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Correspondence to E. D. Vasileva.

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Vasileva, E.D., Ivanov, A.N. & Sivtsev, S.I. Assessment of Electrochemical Characteristics of BMIMBF4 and Polymer Electrolyte Based on it. Russ Phys J 67, 616–623 (2024). https://doi.org/10.1007/s11182-024-03159-4

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  • DOI: https://doi.org/10.1007/s11182-024-03159-4

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