Skip to main content
SpringerLink
Log in

Synthesis of Sterically Hindered Secondary and Tertiary Alkyl(Aryl)Phosphines

  • Published:
Russian Journal of General Chemistry Aims and scope Submit manuscript

Abstract

Cross coupling of silylphosphines with 2-halobenzenecarboxylates or 2-halophenyl ethers, catalyzed with zero-valent palladium complexes can not be used as a procedure for preparing sterically hindered tertiary phosphines. The latter compounds can be successfully prepared by means of phosphorylation of corresponding o-lithiated derivatives.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Veits, Yu.A., Kalstedt, N.B., Foss, V.L., and Beletskaya, I.P., Zh. Org. Khim., 1998, vol. 32, no.4, pp. 559–563.

    Google Scholar 

  2. Dunina, V.V., Kuz’mina, L.G., Kazakova, M.Yu., Grishin, Yu.K., Veits, Yu.A., and Kazakova, E.I., Tetrahedron: Asymmetry, 1997, vol. 8, no.15, pp. 2537–2545.

    CAS  Google Scholar 

  3. Tunney, S.E. and Stille, J.K., J. Org. Chem., 1987, vol. 52, pp. 748–753.

    CAS  Google Scholar 

  4. Herd, O., Hesler, A., Hingst, M., Tepper, M., and Stelzer, O., J. Organomet. Chem., 1996, vol. 522, pp. 69–76.

    CAS  Google Scholar 

  5. Brauer, D.J., Hingst, M., Kottsieper, K.W., Liek, C., Nickel, T., Tepper, M., Stelzer O., and Sheldrick, W.S., J. Organomet. Chem., 2002, vol. 645, pp. 14–26.

    CAS  Google Scholar 

  6. Sakirai, H. and Shirahata, A., Synthesis, 1979, pp. 740–742.

  7. Wittig, G. and Furmann, G., Ber., 1940, vol. 37, pp. 1197–1218.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Lomonosov Moscow State University, Moscow, Russia

    Yu. A. Veits, E. A. Neganova & O. S. Vinogradova

Authors
  1. Yu. A. Veits
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Neganova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. S. Vinogradova
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

__________

Translated from Zhurnal Obshchei Khimii, Vol. 75, No. 2, 2005, pp. 239–243.

Original Russian Text Copyright © 2005 by Veits, Neganova, Vinogradova.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Veits, Y.A., Neganova, E.A. & Vinogradova, O.S. Synthesis of Sterically Hindered Secondary and Tertiary Alkyl(Aryl)Phosphines. Russ J Gen Chem 75, 212–216 (2005). https://doi.org/10.1007/s11176-005-0200-7

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11176-005-0200-7

Keywords

Search

Navigation