Abstract
Reaction of 1,2-O-alkylidene-α-D-glucofuranose 3,5,6-phosphites with dicarbonylrhodium(I) acetylacetonate was studied. The structure of the reaction products is determined by the reagent ratio. At a 5:1 molar ratio, the step ligand-exchange process yields chiral complexes of the [RhL5]+acac− type. Dynamics of and anion exchange in these complexes are considered.
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Translated from Zhurnal Obshchei Khimii, Vol. 74, No. 9, 2004, pp. 1418–1421.
Original Russian Text Copyright © 2004 by A. Koroteev, Teleshov, M. Koroteev, and Nifant’ev.
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Koroteev, A.M., Teleshov, A.T., Koroteev, M.P. et al. Rhodium(I) pentasubstituted cationic complexes on the basis of 1,2-O-Alkylidene-3,5,6-O-phosphinetriyl-α-D-glucofuranose. Russ J Gen Chem 74, 1313–1316 (2004). https://doi.org/10.1007/s11176-005-0002-y
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DOI: https://doi.org/10.1007/s11176-005-0002-y