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Synthesis and structure of copper(II) complexes with diaminodioxime (H2L), a derivative of the monoterpenoid (+)-3-carene

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Abstract

Copper(II) compounds with the optically active diaminodioxime (H2L) derived from the monoterpenoid (+)-3-carene, Cu(H2L)(NO3)2·H2O (I), Cu(H2L)(ClO4)2·H2O (II), Cu(H2L)Br2·H2O (III), and Cu(H2L)SO4·0.5H2O (IV) with µeff equal to 1.81, 1.79, 1.71, and 1.8 µB, respectively, were prepared. Studies of the complexes by IR and EPR spectroscopy showed that I and II are mononuclear ionic complexes. Compound III apparently has polymeric structure (the CuN4Br2 coordination unit). According to EPR data, the Cu2+ ions in polycrystalline compounds III and IV undergo exchange interactions.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, 630090, Novosibirsk, Russia

    S. V. Larianov, L. I. Myachina, L. A. Sheludyakova & E. G. Boguslasvskii

  2. Vorozhtsov Institute of Organic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Tkachev & S. N. Bizyaev

Authors
  1. S. V. Larianov
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  2. L. I. Myachina
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  3. L. A. Sheludyakova
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  4. E. G. Boguslasvskii
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  5. A. V. Tkachev
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  6. S. N. Bizyaev
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Additional information

Translated from Koordinatsionnaya Khimiya, Vol. 30, No. 12, 2004, pp. 897–900.

Original Russian Text Copyright © 2004 by Larionov, Myachina, Sheludyakova, Boguslavskii, Tkachev, Bizyaev.

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Larianov, S.V., Myachina, L.I., Sheludyakova, L.A. et al. Synthesis and structure of copper(II) complexes with diaminodioxime (H2L), a derivative of the monoterpenoid (+)-3-carene. Russ J Coord Chem 30, 846–849 (2004). https://doi.org/10.1007/s11173-005-0003-8

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  • DOI: https://doi.org/10.1007/s11173-005-0003-8

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