Skip to main content
SpringerLink
Log in

New polyethyleneimine derivatives: synthesis and applications for CO2 addition to oxiranes and for sorption of ions of high-field-strength elements

  • Full Articles
  • Published:
Russian Chemical Bulletin Aims and scope

Abstract

Modification of polyethyleneimine with dimethyl malonate and 2-chloroethanol resulted in the synthesis of insoluble macromolecular compounds, which were tested as catalysts in the addition of CO2 to oxiranes and sorption of Zr, Nb, Hf, Ta, and Th from nitric acid solutions. The obtained polymers exhibit anion exchange properties and are able to retain activity over six catalytic cycles in which they provide complete conversion in the CO2 addition to epoxides. The adsorbents also showed moderate activity towards Nb and Ta ions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. C. Calabrese, F. Giacalone, C. Aprile, Catalysts, 2019, 9, 325; DOI: https://doi.org/10.3390/catal9040325.

    Article  Google Scholar 

  2. A. J. Kamphuis, F. Picchioni, P. P. Pescarmona, Green Chem., 2019, 21, 406; DOI: https://doi.org/10.1039/C8GC03086C.

    Article  CAS  Google Scholar 

  3. L. Guo, K. J. Lamb, M. North, Green Chem., 2021, 23, 77; DOI: https://doi.org/10.1039/D0GC03465G.

    Article  CAS  Google Scholar 

  4. Y. Fan, M. Tiffner, J. Schorgenhumer, R. Robiette, M. Waser, S. R. Kass, J. Org. Chem., 2018, 83, 9991; DOI: https://doi.org/10.1021/acs.joc.8b01374.

    Article  CAS  PubMed  Google Scholar 

  5. P. Gismondi, A. Kuzmin, C. Unsworth, S. Rangan, S. Khalid, D. Saha, Langmuir, 2022, 38, 203; DOI: https://doi.org/10.1021/acs.langmuir.1c02403.

    Article  CAS  PubMed  Google Scholar 

  6. I. Anastopoulos, A. Bhatnagar, E. C. Lima, J. Mol. Liq., 2016, 221, 954; DOI: https://doi.org/10.1016/j.molliq.2016.06.076.

    Article  CAS  Google Scholar 

  7. V. Padmasubashini, D. S. R. Murty, Atomic Spectroscopy, 2011, 32, 17; DOI: https://doi.org/10.46770/AS.2011.01.003.

    Article  CAS  Google Scholar 

  8. S. E. Lyubimov, A. A. Zvinchuk, R. R. Aysin, B. Chowdhury, Russ. Chem. Bull., 2021, 70, 1533; DOI: https://doi.org/10.1007/s11172-021-3248-6.

    Article  CAS  Google Scholar 

  9. A. S. Nair, S. Cherian, N. Balachandran, U. G. Panicker, S. K. K. Sankaranarayanan, ACS Omega, 2019, 4, 13042; DOI: https://doi.org/10.1021/acsomega.9b00789.

    Article  Google Scholar 

  10. J. Nanclares, Z. S. Petrovic, I. Javni, M. Ionescu, F. Jaramillo, J. Appl. Polym. Sci., 2015, 132, 42492; DOI: https://doi.org/10.1002/app.42492.

    Article  Google Scholar 

  11. J.-Z. Hwang, S.-C. Wang, P.-C. Chen, C.-Y. Huang, J.-T. Yeh, K.-N. Chen, J. Polym. Res., 2012, 19, 9900; DOI: https://doi.org/10.1007/s10965-012-9900-y.

    Article  Google Scholar 

  12. H. Zhou, G.-X. Wang, W.-Z. Zhang, X.-B. Lu, ACS Catal., 2015, 5, 6773; DOI: https://doi.org/10.1021/acscatal.5b01409.

    Article  CAS  Google Scholar 

  13. P. A. Carvalho, J. W. Comerford, K. J. Lamb, M. North, P. S. Reiss, Adv. Synth. Catal., 2019, 361, 345; DOI: https://doi.org/10.1002/adsc.201801229.

    Article  CAS  Google Scholar 

  14. O. I. Okina, S. M. Lyapunov, A. S. Dubenskiy, K. G. Erofeeva, J. Anal. At. Spectrom., 2020, 35, 2627; DOI: https://doi.org/10.1039/d0ja00255k.

    Article  Google Scholar 

Download references

Funding

This study was performed within the state assignment of the Ministry of Science and Higher Education of Russia (No. 075-03-2023-642).

Author information

Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    S. E. Lyubimov & P. V. Cherkasova

  2. Faculty of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie gory, 119991, Moscow, Russian Federation

    Yu. A. Maksimova

  3. Geological Institute, Russian Academy of Sciences, Build. 1, 7 Pyzhevsky per., 119017, Moscow, Russian Federation

    Yu. A. Maksimova

Authors
  1. S. E. Lyubimov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. V. Cherkasova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yu. A. Maksimova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. E. Lyubimov.

Ethics declarations

Animal Testing and Ethics

No human or animal subjects were used in this research.

Conflict of Interest

The authors declare no competing interests.

Additional information

Publisher’s Note. Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, Vol. 73, No. 3, pp. 669–673, March, 2024.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lyubimov, S.E., Cherkasova, P.V. & Maksimova, Y.A. New polyethyleneimine derivatives: synthesis and applications for CO2 addition to oxiranes and for sorption of ions of high-field-strength elements. Russ Chem Bull 73, 669–673 (2024). https://doi.org/10.1007/s11172-024-4176-z

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11172-024-4176-z

Key words

Search

Navigation