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Equilibrium sorption properties of cholesterol surface-imprinted Se-containing polymeric sorbents synthesized by Pickering emulsion polymerization

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Abstract

The equilibrium sorption isotherms of cholesterol on surface-imprinted Se-containing sorbents based on 2-hydroxyethyl methacrylate and ethylene glycol dimethacrylate were studied. The equilibrium sorption of cholesterol occurred on a homogeneous sorption surface of the molecularly imprinted polymer (template content 6 mol.%). The sorption surface had a higher affinity to template molecules compared to the monolayer. An increase in the amount of template introduced during modification of the polymer matrix led to an increase in the sorption surface area of solvated polymers available for cholesterol binding.

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Funding

This work was financially supported by the Russian Foundation for Basic Research (Project No. 19-33-90003).

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Correspondence to I. S. Garkushina.

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Based on the materials of the VIII All-Russia Kargin Conference “Polymers — 2020” (November 9–13, 2020, Moscow).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 244–253, February, 2022.

No human or animal subjects were used in this research.

The authors declare no competing interests.

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Osipenko, A.A., Garkushina, I.S. Equilibrium sorption properties of cholesterol surface-imprinted Se-containing polymeric sorbents synthesized by Pickering emulsion polymerization. Russ Chem Bull 71, 244–253 (2022). https://doi.org/10.1007/s11172-022-3404-7

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