Abstract
Highly filled vulcanizates based on polyisoprene, organosilicon fillers (polymethylsilsesquioxane and MQ-copolymers), and p-quinone dioxime derivative as a rubber cross-linking agent were prepared. The properties of model rubbers are compared with those formed on the basis of the same elastomer with standard reinforcing fillers, namely, carbon black and aerosil. The effect of fillers on the thermal and mechanical properties of cross-linked objects is estimated. The presence of organosilicon compounds as fillers increases the thermal stability of the composites, and in the case of polymethylsilsesquioxane, both the strength and the tensile modulus of vulcanizates are increased in comparison with rubbers based on standard fillers.
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Funding
The work was financially supported by the Russian Foundation for Basic Research (Project No. 18-33-20247).
Fillers were synthesized under financial support by the Russian Foundation for Basic Research (Project No. 18-29-25053).
Investigation on the kinetics of swelling were performed in the frameworks of State Program of the A. V. Topchiev Institute of Petrochemical Synthesis of the Russian Academy of Sciences.
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Dedicated to Academician of the Russian Academy of Sciences O. M. Nefedov on the occasion of his 90th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2200–2207, November, 2021.
This paper does not contain descriptions of studies on animals or humans.
The authors declare no competing interests.
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Mironova, M.V., Shandryuk, G.A., Meshkov, I.B. et al. Effect of MQ-copolymer and polymethylsilsesquioxane on thermal and mechanical properties of highly filled polyisoprene. Russ Chem Bull 70, 2200–2207 (2021). https://doi.org/10.1007/s11172-021-3333-x
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DOI: https://doi.org/10.1007/s11172-021-3333-x