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Crystal structure and two-level supramolecular organization of glycinium triiodide

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Abstract

Glycinium triiodide was synthesized and its crystal structure was determined. The crystal structure consists of alternating asymmetric triiodide anions characterized by Raman spectroscopy and glycinium cations. The cations and anions form dimers (GlyH)2(I3)2via (N)H···O, (N)H···I, and (O)H···I hydrogen bonds. The dimers are further linked into chains by secondary I···I interactions between adjacent triiodide anions. The supramolecular structure of glycinium triiodide is discussed in comparison with polyiodides of various cations.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation

    T. A. Shestimerova, M. A. Bykov & A. V. Shevelkov

  2. Department of Chemistry, University at Albany, Albany, New York, 12222, USA

    Z. Wei & E. V. Dikarev

Authors
  1. T. A. Shestimerova
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  2. M. A. Bykov
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  3. Z. Wei
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  4. E. V. Dikarev
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  5. A. V. Shevelkov
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Corresponding authors

Correspondence to E. V. Dikarev or A. V. Shevelkov.

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Shestimerova, T.A., Bykov, M.A., Wei, Z. et al. Crystal structure and two-level supramolecular organization of glycinium triiodide. Russ Chem Bull 68, 1520–1524 (2019). https://doi.org/10.1007/s11172-019-2586-0

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  • DOI: https://doi.org/10.1007/s11172-019-2586-0

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