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Catalytic aminomethylation of α,ω-diacetylenes with secondary diamines and aldehydes as an efficient approach to diaza alkatetraynes and tetraaza tetraacetylenic macrocycles

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Abstract

An ef cient synthesis of diazaalkatetraynes and tetraaza macroheterocycles by the Mannich aminomethylation of α,ω-di(tetra)acetylenes with secondary diamines and aldehydes using CuCl as a catalyst was developed.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    G. R. Khabibullina, F. T. Zaynullina, T. V. Tyumkina, V. M. Yanybin & A. G. Ibragimov

Authors
  1. G. R. Khabibullina
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  2. F. T. Zaynullina
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  3. T. V. Tyumkina
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  4. V. M. Yanybin
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  5. A. G. Ibragimov
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Corresponding author

Correspondence to G. R. Khabibullina.

Additional information

Based on the materials of the IV Interdisciplinary Symposium on Medical, Organic, Biological Chemistry and Pharmaceutics (MOBI-ChemPharma 2018) (September 23–26, 2018, Novyi Svet, Crimea).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1407–1413, July, 2019.

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Khabibullina, G.R., Zaynullina, F.T., Tyumkina, T.V. et al. Catalytic aminomethylation of α,ω-diacetylenes with secondary diamines and aldehydes as an efficient approach to diaza alkatetraynes and tetraaza tetraacetylenic macrocycles. Russ Chem Bull 68, 1407–1413 (2019). https://doi.org/10.1007/s11172-019-2569-1

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  • DOI: https://doi.org/10.1007/s11172-019-2569-1

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