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Boron chelate complexes: X-ray and UV photoelectron spectra and electronic structure

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Abstract

Published data on the electronic structure of boron chelates are summarized for the first time. Ultraviolet photoelectron spectra of vapors, X-ray photoelectron spectra of molecular crystals, and results of modeling within the framework of the density functional theory are analyzed. Data on the effect of substituents on the electronic structure of complexes are systematized.

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  1. Far Eastern Federal University, 8 ul. Sukhanova, 690950, Vladivostok, Russian Federation

    S. A. Tikhonov & V. I. Vovna

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Based on the materials of the XXVII International Chugaev Conference on Coordination Chemistry (October 2–6, 2017; Nizhny Novgorod, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1153–1166, July, 2018.

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Tikhonov, S.A., Vovna, V.I. Boron chelate complexes: X-ray and UV photoelectron spectra and electronic structure. Russ Chem Bull 67, 1153–1166 (2018). https://doi.org/10.1007/s11172-018-2196-2

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