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Complex of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with copper dibromide: structure, aggregation, and biological activity

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Abstract

The aggregation and adsorption properties of a new complex of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with copper dibromide were studied by methods of conductometry, tensiometry, and dynamic light scattering. The critical micelle concentration, size of the aggregates, and adsorption characteristics at the water—air interface were determined. The antimicrobial and antifungal effects were established. The studied properties of the complex were compared with the properties of the ligand and cationic surfactants with a head group of the cyclic and acyclic types. The enhanced aggregation ability of the complex and its improved biological activity were shown.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    E. P. Zhil´tsova, M. R. Ibatullina, S. S. Lukashenko, T. N. Pashirova, A. D. Voloshina, V. V. Zobov & L. Ya. Zakharova

  2. A. M. Butlerov Chemical Institute, Kazan (Volga Region) Federal University, 18 ul. Kremlevskaya, 420008, Kazan, Russian Federation

    M. R. Ibatullina & M. P. Kutyreva

  3. E. K. Zavoisky Kazan Physical Technical Institute, Kazan Scientific Center, Russian Academy of Sciences, 10/7 ul. Sibirsky trakt, 420029, Kazan, Russian Federation

    S. A. Ziganshina

Authors
  1. E. P. Zhil´tsova
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  2. M. R. Ibatullina
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  3. S. S. Lukashenko
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  4. T. N. Pashirova
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  5. A. D. Voloshina
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  6. V. V. Zobov
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  7. S. A. Ziganshina
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  8. M. P. Kutyreva
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  9. L. Ya. Zakharova
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Corresponding author

Correspondence to E. P. Zhil´tsova.

Additional information

Dedicated to Academician of the Russian Academy of Sciences O. G. Sinyashin on the occasion of his 60th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1365–1371, May, 2016.

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Zhil´tsova, E.P., Ibatullina, M.R., Lukashenko, S.S. et al. Complex of 1-hexadecyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide with copper dibromide: structure, aggregation, and biological activity. Russ Chem Bull 65, 1365–1371 (2016). https://doi.org/10.1007/s11172-016-1463-3

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  • DOI: https://doi.org/10.1007/s11172-016-1463-3

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