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First example of [6π+2π] cycloaddition of 1,2-dienes to 1,3,5,7-cyclooctatetraene catalyzed by CoI compounds

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Abstract

A stereoselective [6π+2π] cycloaddition of 1,2-dienes to 1,3,5,7-cyclooctatetraene in the presence of a multi-component catalytic system CoI2/dppe/Zn/ZnI2, which led to the formation of substituted (E)-bicyclo[4.2.2]deca-2,4,7-trienes in 76—87% yields, was accomplished for the first time.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    V. A. D’yakonov, G. N. Kadikova, G. F. Gazizullina & U. M. Dzhemilev

Authors
  1. V. A. D’yakonov
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  2. G. N. Kadikova
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  3. G. F. Gazizullina
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  4. U. M. Dzhemilev
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Corresponding author

Correspondence to V. A. D’yakonov.

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Based on the Materials of Conference Molecular Complexity in Modern Chemistry (September 13—19, 2014, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 0200—0202, January, 2016.

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D’yakonov, V.A., Kadikova, G.N., Gazizullina, G.F. et al. First example of [6π+2π] cycloaddition of 1,2-dienes to 1,3,5,7-cyclooctatetraene catalyzed by CoI compounds. Russ Chem Bull 65, 200–202 (2016). https://doi.org/10.1007/s11172-016-1284-4

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  • DOI: https://doi.org/10.1007/s11172-016-1284-4

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