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Intramolecular cyclization of 1,3-diamino-2-hydroxypropan-N,N,N´,N´-tetrakis(methylphosphonic acid) upon phosphonomethylation of 1,3-diaminopropan-2-ol

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Abstract

Phosphonomethylation of 1,3-diaminopropan-2-ol affords the mixture of 1,3-diamino-2-hydroxypropan-N,N,N´,N´-tetrakis(methylphosphonic acid) (1) with its cyclic ether, viz., [(6-[bis(phosphonomethyl)amino]methyl-2-hydroxy-2-oxido-1,4,2-oxazaphosphinan-4-yl)methyl]phosphonic acid (2), but not 1, as assumed earlier.

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Authors and Affiliations

  1. State Scientific Research Institute of Chemical Reagents and High Purity Chemical Substances, 3 ul. Bogorodsky val, 107076, Moscow, Russian Federation

    N. V. Tsirul´nikova, Ya. V. Bolt & S. K. Belus

Authors
  1. N. V. Tsirul´nikova
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  2. Ya. V. Bolt
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  3. S. K. Belus
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Correspondence to N. V. Tsirul´nikova.

Additional information

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 1200—1201, May, 2015.

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Tsirul´nikova, N.V., Bolt, Y.V. & Belus, S.K. Intramolecular cyclization of 1,3-diamino-2-hydroxypropan-N,N,N´,N´-tetrakis(methylphosphonic acid) upon phosphonomethylation of 1,3-diaminopropan-2-ol. Russ Chem Bull 64, 1200–1201 (2015). https://doi.org/10.1007/s11172-015-1001-8

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  • DOI: https://doi.org/10.1007/s11172-015-1001-8

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