Abstract
A reaction of cyclohexane-1,2-dione dioxime with diacetyl leads to tetrahydroquinoxaline 1,4-dioxide derivatives: 5-(E)-{[(E)-2-(hydroxyimino)cyclohexylidene]aminooxy}-2,3-dimethyl-5,6,7,8-tetrahydroquinoxaline 1,4-dioxide and 5,5´-(1E,1´E)-cyclohexane-1,2-diylidenebis(azan-1-yl-1-ylidene)bis(oxy)bis(2,3-dimethyl-5,6,7,8-tetrahydroquinoxaline 1,4-dioxide). Similar products were obtained in the reaction of cyclohexane-1,2-dione dioxime with cyclohexane-1,2-dione and hexane-3,4-dione.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 0432—0435, February, 2015.
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Gatilov, Y.V., Samsonov, V.A. Formation of 5,6,7,8-tetrahydroquinoxaline 1,4-dioxide derivatives in the reaction of cyclohexane-1,2-dione dioxime with 1,2-diketones. Russ Chem Bull 64, 432–435 (2015). https://doi.org/10.1007/s11172-015-0881-y
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DOI: https://doi.org/10.1007/s11172-015-0881-y