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Pyrano[4,3-d]pyrimidinium salts 5. Synthesis of 7-aryl-1,3-dimethyl-2,4-dioxo-1H,3H-pyrano[4,3-d]pyrimidinium salts and their reactions with nucleophiles

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Abstract

7-Arylpyrano[4,3-d]pyrimidinium salts were synthesized starting from 1,3,6-trimethyluracil. In the reactions with N-nucleophiles, these salts were found to undergo recyclization of the pyrylium ring, whereas the addition of C- and O-nucleophiles occurs at free position 5 of the system.

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Authors and Affiliations

  1. Department of Chemistry, Southern Federal University, 7 ul. Zorge, 344090, Rostov-on-Don, Russian Federation

    I. A. Gavrilenko, V. V. Kostrub & E. B. Tsupak

Authors
  1. I. A. Gavrilenko
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  2. V. V. Kostrub
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  3. E. B. Tsupak
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Correspondence to I. A. Gavrilenko.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 620—627, March, 2012.

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Gavrilenko, I.A., Kostrub, V.V. & Tsupak, E.B. Pyrano[4,3-d]pyrimidinium salts 5. Synthesis of 7-aryl-1,3-dimethyl-2,4-dioxo-1H,3H-pyrano[4,3-d]pyrimidinium salts and their reactions with nucleophiles. Russ Chem Bull 61, 623–630 (2012). https://doi.org/10.1007/s11172-012-0090-x

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  • DOI: https://doi.org/10.1007/s11172-012-0090-x

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