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Tetradentate diamido-bis-sulfide ligands on the base of o-aminobenzenethiol and their complexation with NiII, CoII, CuII chlorides in DMF solution and on the gold electrode surface

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Abstract

A series of cyclic and acyclic diamido-bis-sulfide ligands were synthesized by N-acylation of 1,2-bis(2-aminophenylthio)ethane and 1,4-bis(2-aminophenylthio)butane with acetic, malonic, and 3,3′-dithiodipropionic acid chlorides or esters. The complexation of obtained ligands with CuII, NiII, and CoII salts in solution and on the gold electrode surface was studied. The formation of complexes of these ligands with copper(II) chloride in DMF is irreversible and accompanied by deprotonation of the amide nitrogen atoms.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119992, Moscow, Russian Federation

    E. K. Beloglazkina, A. G. Majouga, F. S. Moiseev, A. A. Moiseeva & N. V. Zyk

  2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    V. V. Frolov & M. P. Egorov

Authors
  1. E. K. Beloglazkina
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  2. A. G. Majouga
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  3. F. S. Moiseev
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  4. V. V. Frolov
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  5. A. A. Moiseeva
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  6. N. V. Zyk
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  7. M. P. Egorov
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Correspondence to E. K. Beloglazkina.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1655–1660, August, 2009.

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Beloglazkina, E.K., Majouga, A.G., Moiseev, F.S. et al. Tetradentate diamido-bis-sulfide ligands on the base of o-aminobenzenethiol and their complexation with NiII, CoII, CuII chlorides in DMF solution and on the gold electrode surface. Russ Chem Bull 58, 1707–1712 (2009). https://doi.org/10.1007/s11172-009-0236-7

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  • DOI: https://doi.org/10.1007/s11172-009-0236-7

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