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Coordination polymers based on CuII and MnII complexes with 2-hydroxy-3,6-di(tert-butyl)-1,4-benzoquinone

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Abstract

The reactions of MnII and CuII ions with deprotonated 2-hydroxy-3,6-di(tert-butyl)-1,4-benzoquinone (L) afford bis(chelates) ML2. In the solid phases of the compounds, the coordinated ligands L perform the bridging function leading to the formation of polymer structures: layered in MnL2 and framework in CuL2. In the coordination units ML2 the chelate fragments are in the trans and cis positions relative to one another for MnL2 and CuL2, respectively. Paramagnetism of the polymer structures MnL2 and CuL2, for which the effective magnetic moments in the high-temperature region are 5.85 and 1.91 μB, respectively, is determined by the metal ions, because the energy level of the triplet state of the coordinated L lies much higher, according to the calculated data, than that of the singlet state.

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References

  1. R. Joshi, J. P. Kamat, T. Mukherjee, Chem.-Biol. Interact., 2007, 167, 125.

    Article  CAS  Google Scholar 

  2. P. C. Lin, S. A. Li, S. O. Wang, Y. Yang, J. G. Shi, J. Nat. Prod., 2006, 69, 1629.

    Article  CAS  Google Scholar 

  3. R. H. Thomson, Naturally Occurring Quinones, 2nd ed., Academic Press, London, 1971.

    Google Scholar 

  4. R. H. Thomson, Naturally Occurring Quinones III. Recent advances, 3rd ed., Chapman and Hall, London, 1987.

    Google Scholar 

  5. R. H. Thomson, Naturally Occurring Quinones IV. Recent advances, 4th ed., Blackie, London, 1997.

    Google Scholar 

  6. H. Shigemori, T. Madono, T. Sasaki, Y. Mikami, J. Kobayashi, Tetrahedron, 1994, 50, 8347.

    Article  CAS  Google Scholar 

  7. J. Kobayashi, T. Madono, H. Shigemori, Tetrahedron, 1995, 51, 10867.

    Article  CAS  Google Scholar 

  8. S. Aoki, D. Kong, K. Matsui, R. Rachmat, M. Kobayashi, Chem. Pharm. Bull., 2004, 52, 935.

    Article  CAS  Google Scholar 

  9. Y. Takahashi, T. J. F. Kubota, J. Kobayashi, Tetrahedron, 2007, 63, 8770.

    Article  CAS  Google Scholar 

  10. I. Kubo, M. Kim, I. Ganjian, T. Kamikawa, Y. Yamagiwa, Tetrahedron, 1987, 43, 2653.

    Article  CAS  Google Scholar 

  11. S. Poigny, M. Guyot, M. Samadi, Tetrahedron, 1998, 54, 14791.

    Article  CAS  Google Scholar 

  12. C. S. P. McErlean, C. J. Moody, J. Org. Chem., 2007, 72, 10298.

    Article  CAS  Google Scholar 

  13. R. L. Danheiser, D. D. Cha, Tetrahedron Lett., 1990, 31, 1527.

    Article  CAS  Google Scholar 

  14. P. Stahl, H. Waldmann, Angew. Chem., Int. Ed. Engl., 1999, 38, 3710.

    Article  CAS  Google Scholar 

  15. A. R. MacKenzie, C. J. Moody, C. W. Rees, J. Chem. Soc., Chem. Commun., 1983, 1372.

  16. K. S. Min, A. G. DiPasqual, J. A. Golen, A. L. Rheingold, A. M. Arif, J. S. Miller, J. Am. Chem. Soc., 2007, 129, 2360.

    Article  CAS  Google Scholar 

  17. K. S. Min, A. G. DiPasqual, A. L. Rheingold, J. S. Miller, Inorg. Chem., 2007, 46, 1048.

    Article  CAS  Google Scholar 

  18. K. S. Min, K. Swierczek, A. G. DiPasqual, A. L. Rheingold, W. M. Reiff, A. M. Arif, J. S. Miller, Chem. Commun., 2008, 317.

  19. K. Yamada, H. Tanaka, S. Yagishita, K. Adachi, T. Uemura, S. Kitagawa, S. Kawata, Inorg. Chem., 2006, 45, 4322.

    Article  CAS  Google Scholar 

  20. K. Yamada, S. Yagishita, H. Tanaka, K. Tohyama, K. Adachi, S. Kaizaki, H. Kumagai, K. Inoue, R. Kitaura, H.-C. Chang, S. Kitagawa, S. Kawata, Eur. J. Chem., 2004, 10, 2647.

    Article  CAS  Google Scholar 

  21. S. Salunke-Gawalia, S. Y. Ranea, V. G. Puranikb, C. Guyard-Duhayonc, F. Varretd, Polyhedron, 2004, 23, 2541.

    Article  Google Scholar 

  22. M. P. Mulay, P. L. Garge, S. B. Padhye, R. C. Haltiwanger, L. A. deLearie, C. Pierpont, Chem. Commun., 1987, 581.

  23. M. A. Martinez, M. C. L. De Jimenez, E. E. Castellano, O. E. Piro, P. J. Aymonino, Coord. Chem. Rev., 2003, 56, 803.

    Article  CAS  Google Scholar 

  24. P. Garge, R. Chikate, S. Padhye, J.-M. Savariault, P. de Loth, J.-P. Tuchagues, Inorg. Chem., 1990, 29, 3315.

    Article  CAS  Google Scholar 

  25. N. H. Gokhale, S. B. Padhye, S. L. Croft, H. D. Kendrick, W. Davies, C. E. Anson, A. K. Powell, J. Inorg. Biochem., 2003, 95, 249.

    Article  CAS  Google Scholar 

  26. C. L. Foster, X. Liu, C. A. Kilner, M. Thornton-Pett, M. A. Halcrow, J. Chem. Soc., Dalton Trans., 2000, 4563.

  27. M. P. Bubnov, V. I. Nevodchikov, G. K. Fukin, V. K. Cherkasov, G. A. Abakumov, Inorg. Chem. Commun., 2007, 10, 989.

    Article  CAS  Google Scholar 

  28. N. A. Malysheva, A. I. Prokof’ev, S. P. Solodovnikov, N. N. Bubnov, T. I. Prokof’eva, V. B. Vol’eva, M. I. Kabachnik, Izv. Akad. Nauk SSSR, Ser. Khim., 1990, 161 [Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1990, 145].

  29. N. Yu. Kabarova, V. K. Cherkasov, L. N. Zakharov, G. A. Abakumov, Yu. T. Struchkov, L. G. Abakumova, Izv. Akad. Nauk SSSR, Ser. Khim., 1992, 2798 [Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.), 1992, 2224].

  30. A. L. Spek, J. Appl. Crystallogr., 2003, 36, 7.

    Article  CAS  Google Scholar 

  31. Cambridge Structural Database, Version 5.30, November 2008 (Update February 2009).

  32. F. Neese, ORCA — An ab Initio, Density Functional and Semiempirical Program Package, Version 2.6, Revision 35, University of Bonn, 2008.

  33. C. Adamo, M. Cossi, V. Barone, J. Mol. Struct. Theochem., 1999, 493, 145.

    Article  CAS  Google Scholar 

  34. C. A. Daul, I. Ciofini, A. Bencini, in Reviews of Modern Quantum Chemistry, part II, Ed. K. D. Sen, World Scientific, Singapore, 2002, 1247.

    Google Scholar 

  35. L. Noodleman, C. Y. Peng, D. A. Case, J. M. Mouesca, Coord. Chem. Rev., 1995, 144, 199.

    Article  CAS  Google Scholar 

  36. L. Noodleman, J. G. Norman, J. Chem. Phys., 1979, 70, 4903.

    Article  CAS  Google Scholar 

  37. A. J. H. Wachters, J. Chem. Phys., 1970, 52, 1033.

    Article  CAS  Google Scholar 

  38. A. J. H. Wachters, IBM Tech. Rept., RJ584, 1969.

  39. C. W. Bauschlicher, S. R. Langhoff, L. A. Barnes, J. Chem. Phys., 1989, 91, 2399.

    Article  CAS  Google Scholar 

  40. E. R. Davidson, D. Feller, Chem. Rev., 1986, 86, 681.

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. International Tomography Center, Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation

    E. Yu. Fursova, V. I. Ovcharenko, E. V. Gorelik, G. V. Romanenko & A. S. Bogomyakov

  2. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhnii Novgorod, Russian Federation

    V. K. Cherkasov & G. A. Abakumov

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  1. E. Yu. Fursova
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  2. V. I. Ovcharenko
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  3. E. V. Gorelik
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  4. G. V. Romanenko
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  5. A. S. Bogomyakov
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  6. V. K. Cherkasov
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  7. G. A. Abakumov
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Correspondence to E. Yu. Fursova.

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Dedicated to Academician O. N. Chupakhin on the occasion of his 75th birthday.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1110–1116, June, 2009.

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Fursova, E.Y., Ovcharenko, V.I., Gorelik, E.V. et al. Coordination polymers based on CuII and MnII complexes with 2-hydroxy-3,6-di(tert-butyl)-1,4-benzoquinone. Russ Chem Bull 58, 1139–1145 (2009). https://doi.org/10.1007/s11172-009-0148-6

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  • DOI: https://doi.org/10.1007/s11172-009-0148-6

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