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Lutetium complexes with the 1,3-diphenylcyclopentadienyl ligand. Syntheses and molecular structures of the complexes {(Ph2C5H3)Lu(C2Ph4)(THF)} and {(Ph2C5H3)LuCl2(THF)3}

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Abstract

The reaction of LuCl3(THF)3 with Na(1,3-Ph2C5H3) followed by the in situ reaction with Na2[Ph4C2] produced (1,3-Ph2C5H3)Lu(Ph4C2)(THF) (1). The structure of 1 was established by X-ray diffraction. In the crystal structure of 1, the bis-allyl η6-coordination of the tetraphenylethylene dianion to the lutetium cation was observed. The structures of (1,3-Ph2C5H3)LuCl2(THF)3 and (C5H5)LuCl2(THF)3 were determined by X-ray diffraction.

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Authors and Affiliations

  1. L. Ya. Karpov Institute of Physical Chemistry, 10 ul. Vorontsovo Pole, 105064, Moscow, Russian Federation

    D. M. Roitershtein & M. E. Minyaev

  2. Department of Chemistry and Biology, Moscow City Pedagogical University, 4 Vtoroi Sel’skokhozyaistvennyi proezd, 129226, Moscow, Russian Federation

    D. M. Roitershtein, M. E. Minyaev & A. A. Mikhailyuk

  3. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    K. A. Lyssenko & M. Yu. Antipin

  4. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    P. A. Belyakov

Authors
  1. D. M. Roitershtein
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  2. M. E. Minyaev
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  3. A. A. Mikhailyuk
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  4. K. A. Lyssenko
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  5. P. A. Belyakov
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  6. M. Yu. Antipin
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Correspondence to D. M. Roitershtein.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1912–1918, October, 2007.

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Roitershtein, D.M., Minyaev, M.E., Mikhailyuk, A.A. et al. Lutetium complexes with the 1,3-diphenylcyclopentadienyl ligand. Syntheses and molecular structures of the complexes {(Ph2C5H3)Lu(C2Ph4)(THF)} and {(Ph2C5H3)LuCl2(THF)3}. Russ Chem Bull 56, 1978–1985 (2007). https://doi.org/10.1007/s11172-007-0308-5

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  • DOI: https://doi.org/10.1007/s11172-007-0308-5

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