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New lead(II) catecholate and o-semiquinone complexes

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Abstract

Lead(II) catecholate complexes were prepared by reduction of 3,6-di-tert-butyl-o-benzoquinone and its derivatives with lead metal in THF. The molecular structure of the (CatPb)4·(PbO)2·6C3H6O complex (Cat is the dianion of 3,6-di-tert-butylcatechol), which was synthesized by hydrolysis of lead 3,6-di-tert-butylcatecholate in acetone, was established by X-ray diffraction. A series of lead(II) o-semiquinone complexes, which were prepared by the addition of the phenoxyl radical to lead catecholates or by oxidation of the latter with mercury(II), copper(II), or silver(I) halides, were studied by the ESR method. Lead(II) mono-o-semiquinolate complexes undergo symmetrization to form stable bis-o-semiquinolates, which were isolated and characterized in individual state.

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References

  1. J. Parr, Polyhedron, 1997, 16, 551.

    Article  CAS  Google Scholar 

  2. G. A. Abakumov, Zh. Vsesoyuz. Khim. Obshch. im. D. I. Mendeleeva, 1979, 156 [Mendeleev Chem. J., 1979 (Engl.Transl.)].

  3. V. I. Nevodchikov, G. A. Abakumov, V. K. Cherkasov, and G. A. Razuvaev, J. Organomet. Chem., 1981, 214, 119.

    Article  CAS  Google Scholar 

  4. G. A. Abakumov, V. K. Cherkasov, K. G. Shalnova, I. A. Teplova, and G. A. Razuvaev, J. Organomet. Chem., 1982, 236, 333.

    Article  CAS  Google Scholar 

  5. G. A. Abakumov, A. V. Krashilina, V. K. Cherkasov, and L. N. Zakharov, Dokl. Akad. Nauk, 2003, 391, 343 [Dokl. Chem., 2003s, 391, 185 (Engl. Transl.)].

    Google Scholar 

  6. K. A. Kozhanov, M. P. Bubnov, V. K. Cherkasov, G. K. Fukin, and G. A. Abakumov, J. Chem. Soc. Dalton Trans., 2004, 2957.

  7. Z. K. Kasymbekova, A. I. Prokof’ev, N. N. Bubnov, S. P. Solodovnikov, and M. I. Kabachnik, Dokl. Akad. Nauk SSSR, 1982, 263, 352 [Dokl. Chem., 1982, 263 (Engl. Transl.)].

    CAS  Google Scholar 

  8. G. A. Abakumov, V. K. Cherkasov, A. V. Piskunov, and N. O. Druzhkov, Dokl. Akad. Nauk, 2004, 399, 353 [Dokl. Chem., 2004, 399, 223 (Engl. Transl.)].

    Google Scholar 

  9. G. A. Abakumov, V. I. Nevodchikov, V. K. Cherkasov, and G. A. Razuvaev, Dokl. Akad. Nauk SSSR, 1978, 242, 609 [Dokl. Chem., 1978, 242 (Engl. Transl.)].

    CAS  Google Scholar 

  10. S. V. Maslennikov, O. Y. Chekhonina, I. V. Spirina, A. V. Piskounov, and V. K. Cherkasov, Main Group Metal. Chem., 2001, 24, 865.

    CAS  Google Scholar 

  11. G. M. Barnard, M. A. Brown, H. E. Mabrouk, B. A. McGarvey, and D. G. Tuck, Inorg. Chim. Acta, 2003, 349, 142.

    Article  CAS  Google Scholar 

  12. C. G. Pierpont and R. M. Buchanan, Coord. Chem. Rev., 1981, 38, 45.

    Article  CAS  Google Scholar 

  13. A. V. Piskunov, S. V. Maslennikov, I. V. Spirina, and V. P. Maslennikov, Koord. Khim., 2002, 28, 861 [Russ. J. Coord. Chem., 2002, 28, 808 (Engl. Transl.)].

    Google Scholar 

  14. J. Emsley, The Elements, Clarendon press, Oxford, 1991, 251 pp.

    Google Scholar 

  15. G. A. Abakumov, V. A. Muraev, and G. A. Razuvaev, Dokl. Akad. Nauk SSSR, 1974, 217, 1083 [Dokl. Chem., 1974, 217 (Engl. Transl.)].

    Google Scholar 

  16. E. S. Klimov, G. A. Abakumov, E. N. Gladyshev, P. Ya. Bayushkin, V. A. Muravev, and G. A. Razuvaev, Dokl. Akad. Nauk SSSR, 1974, 218, 844 [Dokl. Chem., 1974, 218 (Engl. Transl.)].

    CAS  Google Scholar 

  17. N. V. Berezina, V. K. Cherkasov, and V. P. Maslennikov, Zh. Obshch. Khim., 1996, 66, 1488 [Russ. J. Gen Chem., 1996, 66, 1451 (Engl. Transl.)].

    CAS  Google Scholar 

  18. S. V. Maslennikov, E. N. Kirillov, N. V. Berezina, I. V. Spirina, and A. V. Kondin, Zh. Obshch. Khim., 1997, 67, 714 [Russ. J. Gen Chem., 1997, 67, 667 (Engl. Transl.)].

    Google Scholar 

  19. A. V. Piskunov, S. V. Maslennikov, V. K. Cherkasov, I. V. Spirina, and V. P. Maslennikov, Zh. Obshch. Khim., 2002, 72, 997 [Russ. J. Gen Chem., 2002, 72, 933 (Engl. Transl.)].

    Google Scholar 

  20. N. V. Berezina, V. K. Cherkasov, A. V. Kondin, and V. P. Maslennikov, Zh. Obshch. Khim., 1996, 66, 40 [Russ. J. Gen. Chem., 1996, 66, 35 (Engl. Transl.)].

    CAS  Google Scholar 

  21. J. H. Sharp and M. C. R. Symons, in Ions and Ion Pairs in Organic Reactions, Wiley-interscience, New York, 1972, Vol. 1, p. 178.

    Google Scholar 

  22. A. Carrington and A. D. McLachlan, Introduction to Magnetic Resonance, with Applications to Chemistry and Chemical Physics, Harper and Row, New York and London, 1967, 266 pp.

    Google Scholar 

  23. M. R. St J. Foreman, M. J. Plater, and J. M. S. Skakle, J. Chem. Soc. Dalton Trans., 2001, 1897.

  24. C. Janiak, J. Chem. Soc. Dalton Trans., 2003, 2781.

  25. W. Frank and F.-G. Wittmer, Chem. Ber., 1997, 130, 1731.

    CAS  Google Scholar 

  26. B. Tumanskii, P. Pine, Y. Apeloig, N. J. Hill, and R. West, J. Am. Chem. Soc., 2004, 126, 7786.

    Article  CAS  Google Scholar 

  27. I. L. Fedushkin, N. M. Khvoinova, A. Yu. Baurin, G. K. Fukin, V. K. Cherkasov, and M. P. Bubnov, Inorg. Chem., 2004, 43, 7807.

    Article  CAS  Google Scholar 

  28. G. A. Abakumov, V. K. Cherkasov, A. V. Piskunov, I. A. Aivaz’yan, and N. O. Druzhkov, Dokl. Akad. Nauk, 2005, 404, 496 [Dokl. Chem., 2005, 404, 189 (Engl. Transl.)].

    Google Scholar 

  29. B. Tumanskii, P. Pine, Y. Apeloig, N. J. Hill, and R. West, J. Am. Chem. Soc., 2005, 127, 8248.

    Article  CAS  Google Scholar 

  30. A. V. Piskunov, I. A. Aivaz’yan, V. K. Cherkasov, and G. A. Abakumov, J. Organomet. Chem., 2006, 691, 1531.

    Article  CAS  Google Scholar 

  31. P. Lihung, B. Twamley, and P. P. Power, Organometallics, 2000, 19, 2874.

    Article  Google Scholar 

  32. S. S. Al-Juaid, A. G. Avent, C. Eaborn, M. S. Hill, P. B. Hitchcock, D. J. Patel, and J. D. Smith, Organometallics, 2001, 20, 1223.

    Article  CAS  Google Scholar 

  33. A. J. Gordon and R. A. Ford, The Chemist’s Companion, Wiley Interscience Publication, New York, 1972, 537 pp.

    Google Scholar 

  34. V. A. Garnov, V. I. Nevodchikov, L. G. Abakumova, G. A. Abakumov, and V. K. Cherkasov, Izv. Akad. Nauk SSSR, Ser. Khim., 1987, 1863 [Bull. Acad. Sci. USSR. Div. Chem. Sci., 1987, 36, 1728 (Engl. Transl.)].

  35. V. B. Vol’eva, I. A. Novikova, E. V. Ivanova, and V. V. Ershov, Izv. Akad. Nauk SSSR, Ser. Khim., 1986, 215 [Bull. Acad. Sci. USSR. Div. Chem. Sci., 1986, 35 (Engl. Transl.)].

  36. V. A. Garnov, V. I. Nevodchikov, G. A. Abakumov, V. K. Cherkasov, L. G. Abakumova, and Yu. A. Kurskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1985, 2793 [Bull. Acad. Sci. USSR. Div. Chem. Sci., 1985, 34 (Engl. Transl.)].

  37. G. A. Abakumov, V. K. Cherkasov, V. I. Nevodchikov, N. O. Druzhkov, G. K. Fukin, Y. A. Kursky, and A. V. Piskunov, Tetrahedron Lett., 2005, 46, 4095.

    Article  CAS  Google Scholar 

  38. G. M. Sheldrick, SHELXTL v. 6.12, Structure Determination Software Suite, Bruker AXS, Madison, Wisconsin, USA, 2000.

    Google Scholar 

  39. G. M. Sheldrick, SADABS v. 2.01, Bruker/Siemens Area Detector Absorption Correction Program, Bruker AXS, Madison, Wisconsin, USA, 1998.

    Google Scholar 

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Authors and Affiliations

  1. G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 49 ul. Tropinina, 603950, Nizhny Novgorod, Russian Federation

    G. A. Abakumov, V. K. Cherkasov, A. V. Piskunov, A. V. Lado, G. K. Fukin & L. G. Abakumova

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  1. G. A. Abakumov
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  2. V. K. Cherkasov
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  3. A. V. Piskunov
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  4. A. V. Lado
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  5. G. K. Fukin
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  6. L. G. Abakumova
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1103–1111, July, 2006.

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Abakumov, G.A., Cherkasov, V.K., Piskunov, A.V. et al. New lead(II) catecholate and o-semiquinone complexes. Russ Chem Bull 55, 1146–1154 (2006). https://doi.org/10.1007/s11172-006-0391-z

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  • DOI: https://doi.org/10.1007/s11172-006-0391-z

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