Abstract
The interaction of p-tert-butylthiacalix[4]arene with N,N-diethylchloroacetamide was studied in the presence of alkali metal carbonates in acetone. Three stereoisomers, viz., cone, partial cone, and 1,3-alternate, of the tetraamide derivative of thiacalixarene substituted at the lower rim were synthesized selectively using the template effect of alkali metal cations, as well as a complex of the 1,3-alternate stereoisomer with potassium chloride. The structures of the compounds synthesized were studied by 2D NMR spectroscopy. A high extraction ability of the compounds toward alkali metal cations was demonstrated.
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Dedicated to Academician A. L. Buchachenko on the occasion of his 70th birthday.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 2041–2049, September, 2005.
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Solovieva, S.E., Grüner, M., Omran, A.O. et al. Synthesis, structure, and complexation properties of tetraamide derivatives of thiacalix[4]arene in different conformations. Russ Chem Bull 54, 2104–2112 (2005). https://doi.org/10.1007/s11172-006-0084-7
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DOI: https://doi.org/10.1007/s11172-006-0084-7