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Unusual case of catalysis by palladium clusters

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Abstract

An unusual for Pd catalysts dehydration of α-alkyl and α, α′-dialkylbenzyl alcohols PhCR′R″OH (R′ = H, Me, Et, Bu; R″ = H, Me) occurs in the presence of the palladium(I) cluster [Pd4(CO)4(OAc)4] (1) in an inert atmosphere to form ethers PhCR′R″-O-CR′ R″ and water. The catalyst is an intermediate of cluster 1 reduction to Pd black, while neither the starting cluster 1, nor Pd black, which is the decomposition product, are active in the catalysis of this reaction.

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation

    I. P. Stolarov, Zh. V. Dobrokhotova, N. Yu. Kozitsyna, A. E. Gekhman, M. N. Vargaftik & I. I. Moiseev

  2. G. K. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 5 prosp. Akad. Lavrent’eva, 630090, Novosibirsk, Russian Federation

    G. N. Kryukova

Authors
  1. I. P. Stolarov
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  2. Zh. V. Dobrokhotova
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  3. G. N. Kryukova
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  4. N. Yu. Kozitsyna
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  5. A. E. Gekhman
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  6. M. N. Vargaftik
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  7. I. I. Moiseev
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 788–791, March, 2005.

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Stolarov, I.P., Dobrokhotova, Z.V., Kryukova, G.N. et al. Unusual case of catalysis by palladium clusters. Russ Chem Bull 54, 803–806 (2005). https://doi.org/10.1007/s11172-005-0324-2

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  • DOI: https://doi.org/10.1007/s11172-005-0324-2

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