Abstract
A synthetic route combining the preparation of functional and nonfunctional carbosilane dendrimers has been developed. Using this route, two representative homologous series of carbosilane dendrimers have been prepared. The use of nonfunctional dendrimer derivatives ensures the possibility of performing long-term experiments both in solution and in the bulk. The intrinsic viscosity and the density of the specimens studied do not depend on the generation number. The obtained dendrimers of later generations were studied by atomic force microscopy and light scattering.
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References
D. A. Tomalia, A. M. Naylor, and W. A. Goddart, III, Angew. Chem., Int. Ed. Engl., 1990, 29, 138.
A. M. Muzafarov, E. A. Rebrov, and V. S. Papkov, Usp. Khim., 1991, 60, 1596 [Russ. Chem. Rev., 1991, 60, 807 (Engl. Transl.)].
G. R. Newkome, C. N. Moorefield, and F. Voegtle, Dendritic Molecules, VCH, Weinheim, 1996.
J.-P. Majoral and A.-M. Caminade, Chem. Rev., 1999, 99, 845.
J. M. J. Frechet and D. A. Tomalia, Dendrimers and Other Dendritic Polymers, J. Wiley and Sons, West Sussex, 2001.
V. V. Narayanan and G. R. Newkome, Top. Curr. Chem., 1998, 197, 19.
F. Zeng and S. C. Zimmerman, Chem. Rev., 1997, 97, 1681.
D. Astruc, J.-C. Blais, E. Cloutet, L. Djakovitch, S. Rigaut, J. Ruiz, V. Sartor, and C. Valerio, Top. Curr. Chem., 2000, 210, 229.
A. M. Muzafarov and E. A. Rebrov, Vysokomolekulyar. Soedineniya, Ser. C, 2000, 42, 2015 [Polym. Sci., Ser. C, 2000, 42, 55 (Engl. Transl.)].
S. C. Zimmerman and L. J. Lawless, Top. Curr. Chem., 2001, 217, 95.
A. M. Muzafarov, O. B. Gorbatsevich, E. A. Rebrov, G. M. Ignat’eva, T. B. Chenskaya, V. D. Myakushev, A. F. Bulkin, and V. S. Papkov, Vysokomolekulyar. Soedineniya, Ser. A, 1993, 35, 1867 [Polym. Sci., Ser. A, 1993, 35, 1575 (Engl. Transl.)].
L.-L. Zhou and J. Roovers, Macromolecules, 1993, 26, 963.
A. W. van der Made and P. W. N. M. van Leeuwen, J. Chem. Soc., Chem. Commun., 1992, 1400.
A. W. van der Made, P. W. N. M. van Leeuwen, J. C. de Wilde, and R. A. C. Brandes, Adv. Mater., 1993, 466.
C. Kim, K. Jeong, and I. Jung, J. Polym. Sci., Part A, 2000, 38, 2749.
C. Kim, S. Son, and B. Kim, J. Organometallic Chem., 1999, 588, 1.
N. Ouali, S. Mery, A. Skoulios, and L. Noirez, Macromolecules, 2000, 33, 6185.
S. Hecht and J. M. J. Frechet, J. Am. Chem. Soc., 1999, 121, 4084.
S. A. Ponomarenko, E. A. Rebrov, N. I. Boiko, A. M. Muzafarov, and V. P. Shibaev, Vysokomolekulyar. Soedineniya, Ser. A, 1998, 40, 1253 [Polym. Sci., Ser. A, 1998, 40, 763 (Engl. Transl.)].
C. Kim and S. Son, Organometallic, 2000, 599, 123.
C. Kim and A. Kwon, Synthesis, 1998, 105.
C. Kim, S. K. Choi, and B. Kim, Polyhedron, 2000, 19, 1031.
C. Kim and I. Jung, J. Organometallic Chem., 2000, 599, 208.
B. V. Lebedev, M V. Ryabkov, E A. Tatarinova, E. A. Rebrov, and A. M. Muzafarov, Izv. Akad. Nauk. Ser. Khim., 2003, 523 [Russ. Chem. Bull., Int. Ed., 2003, 52, 545].
N. N. Smirnova, B. V. Lebedev, N. M. Khramova, L. Ya. Tsvetkova, E A. Tatarinova, V. D. Myakushev, and A. M. Muzafarov, Zhurn. Fiz. Khim., 2004, 78, 1 [Russ. J. Phys. Chem., 2004, 78, 1196 (Engl. Transl.)].
A. I. Kuklin, A. N. Ozerin, A. Kh. Islamov, A. M. Muzafarov, V. I. Gordeliy, E. A. Rebrov, G. M. Ignat’eva, E. A. Tatarinova, R. I. Mukhamedzyanov, L. A. Ozerin, and E. Yu. Sharipov, J. Appl. Cryst., 2003, 36, 679.
A. Sagidullin, V. D. Skirda, E. A. Tatarinova, A. M. Muzafarov, M. A. Krykin, A. N. Ozerin, B. Fritzinger, and U. Scheler, Appl. Magn. Reson., 2003, 25, 129.
T. H. Mourey, S. R. Turner, M. Rubinstein, J. M. J. Frechet, C. J. Hawker, and K. L. Wooley, Macromolecules, 1992, 25, 2401.
R. L. Lescanec and M. Muthukumar, Macromolecules, 1990, 23, 2280.
S. M. Aharoni, C. R. Crosby, III, and E. K. Walsh, Macromolecules, 1982, 15, 1093.
C. Cai and Z. Y. Chen, Macromolecules, 1998, 31, 6393.
I. Bodnar, A. S. Silva, R. W. Deitcher, N. E. Weisman, Y. H. Kim, and N. J. Wagner, J. Polym. Sci., Part B: Polym. Phys., 2000, 38, 857.
P. C. Hiemenz, Polymer Chemistry, Marcel Dekker, New York, 1984, p. 594.
A. I. Kuklin, G. M. Ignat’eva, L. A. Ozerina, A. Kh. Islamov, R. I. Mukhamedzyanov, N. A. Shumilkina, V. D. Myakushev, E. Yu. Sharipov, V. I. Gordelii, A. M. Muzafarov, and A. N. Ozerin, Vysokomolekulyar. Soedineniya, Ser. A, 2002, 44, 2124 [Polym. Sci., Ser. A, 2002, 44, 1273 (Engl. Transl.)].
S. Sheiko, G. Eckert, G. Ignat’eva, A. Muzafarov, J. Spickermann, and M. Moeller, Macromol. Rapid Comm., 1996, 17, 283.
S. S. Sheiko and M. Moeller, Chem. Rev., 2001, 101, 4099.
E. V. Getmanova, A. S. Tereshchenko, G. M. Ignat’eva, E. A. Tatarinova, V. D. Myakushev, and A. M. Muzafarov, Izv. Akad. Nauk. Ser. Khim., 2004, 134 [Russ. Chem. Bull., Int. Ed., 2004, 53, 137].
N. G. Vasilenko, G. M. Ignat’eva, V. D. Myakushev, E. A. Rebrov, M. Meller, and A. M. Muzafarov, Dokl. Akad. Nauk, 2001, 377, 348 [Dokl. Chem., 2001, 377, 84 (Engl. Transl.)].
A. S. Filonov, D. Yu. Gavrilko, and I. V. Yaminskii, Programmnoe obespechenie “FemtoSkan” dlya obrabotki trekhmernykh izobrazhenii [FemtoSkan Sofrware for the Processing of Three Dimensional Images], Moscow, Tsentr perspektivnykh tekhnologii, 2001 (in Russian).
G. M. Ignat’eva, E. A. Rebrov, V. D. Myakushev, A. M. Muzafarov, M. N. Il’ina, I. I. Dubovik, and V. S. Papkov, Vysokomolekulyar. soedineniya, Ser. A, 1997, 39, 1302 [Polym. Sci., Ser. A, 1997, 39, 1302 (Engl. Transl.)].
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 11, pp. 2484–2493, November, 2004.
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Tatarinova, E.A., Rebrov, E.A., Myakushev, V.D. et al. Synthesis and study of the properties of the homologous series of polyallylcarbosilane dendrimers and their nonfunctional analogs. Russ Chem Bull 53, 2591–2600 (2004). https://doi.org/10.1007/s11172-005-0159-x
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DOI: https://doi.org/10.1007/s11172-005-0159-x