Skip to main content
SpringerLink
Log in

Efficiency of temperature on Ce and La doping Cu modified IM-5 catalyst in DeNOx performance and SO2/H2O resistance

  • Published:
Research on Chemical Intermediates Aims and scope Submit manuscript

Abstract

Ce and La modified Cu/IM-5 (CuCeLa/IM-5) catalysts were prepared through ion exchange method, and they were used for NH3-SCR. The results exhibited that CuCeLa/IM-5 catalyst possessed the more excellent activity than other catalysts in the wide reaction temperature window (250–450 ℃). This was because Ce and La boosted surface acidity and redox properties, which facilitated the formation of oxygen vacancies. Meanwhile, the relationship between NOx conversion and total acid amount was not significant at low reaction temperature. Nevertheless, the relationship between acidity amount and NOx conversion was positively correlated at high reaction temperature. More than anything, CuCeLa/IM-5 had excellent water resistance and sulfur dioxide resistance.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

Availability of data and materials

All data are available and could be sent on request from the corresponding author.

References

  1. L.P. Han, S.X. Cai, M. Gao, J. Hasegawa, P.L. Wang, J.P. Zhang, L.Y. Shi, D.S. Zhang, Chem. Rev 119, 10916 (2019). https://doi.org/10.1021/acs.chemrev.9b00202

    Article  CAS  PubMed  Google Scholar 

  2. J.L. Chen, G. Peng, T.Y. Liang, W.B. Zhang, W. Zheng, H.R. Zhao, L. Guo, X.Q. Wu, Nanomaterials 10, 2170 (2020). https://doi.org/10.3390/nano10112170

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  3. H. Kubota, C. Liu, T. Amada, K. Kon, T. Toyao, Z. Maeno, K. Ueda, A. Satsuma, N. Tsunoji, T. Sano, K. Shimizu, Catal. Today 376, 73 (2021). https://doi.org/10.1016/j.cattod.2020.07.084

    Article  CAS  Google Scholar 

  4. Y.L. Shan, J.P. Du, Y.B. Yu, W.P. Shan, X.Y. Shi, H. He, Appl. Catal. B 266, 118655 (2020). https://doi.org/10.1016/j.apcatb.2020.118655

    Article  CAS  Google Scholar 

  5. K.A. Tarach, M. Jablonska, K. Pyra, M. Liebau, B. Reiprich, R. Glaser, K. Gora-Marek, Appl. Catal. B 284, 119752 (2021). https://doi.org/10.1016/j.apcatb.2020.119752

    Article  CAS  Google Scholar 

  6. P.N.R. Vennestrom, T.V.W. Janssens, A. Kustov, M. Grill, A. Puig-Molina, L.F. Lundegaard, R.R. Tiruvalam, P. Concepcion, A. Corma, J. Catal. 309, 477 (2014). https://doi.org/10.1016/j.jcat.2013.10.017

    Article  CAS  Google Scholar 

  7. Q. Liu, C. Bian, Y.F. Jin, L. Pang, Z. Chen, T. Li, Catal. Today 388, 158 (2022). https://doi.org/10.1016/j.cattod.2020.06.085

    Article  CAS  Google Scholar 

  8. B.Z. Zhu, G.B. Li, Y.L. Sun, S.L. Yin, Q.L. Fang, Z.H. Zi, Z.C. Zhu, J.X. Li, K.K. Mao, J. Braz. Chem. Soc. 29, 1680 (2018). https://doi.org/10.21577/0103-5053.20180042

    Article  CAS  Google Scholar 

  9. C. Niu, X.Y. Shi, F.D. Liu, K. Liu, L.J. Xie, Y. You, H. He, Chem. Eng. J. 294, 254 (2016). https://doi.org/10.1016/j.cej.2016.02.086

    Article  CAS  Google Scholar 

  10. G. Qi, Y. Wang, R.T. Yang, Catal. Lett. 121, 111 (2008). https://doi.org/10.1007/s10562-007-9306-3

    Article  CAS  Google Scholar 

  11. J. Deshetti, D. Devaiah, C. Anastasios, S. Mandeep, S.M. Ylias, M.L.H. Edwin, B. Vipul, B.K. Suresh, Catal. Sci. Technol. 9, 4226 (2019). https://doi.org/10.1039/D3CY00975K

    Article  Google Scholar 

  12. L. Chen, S. Ren, Y.H. Jiang, L. Liu, M.M. Wang, J. Yang, Z.C. Chen, W.Z. Liu, Q.C. Liu, Fuel 320, 123969 (2022). https://doi.org/10.1016/j.fuel.2022.123969

    Article  CAS  Google Scholar 

  13. L. Chen, S. Ren, L. Liu, B.X. Su, J. Yang, Z.C. Chen, M.M. Wang, Q.C. Liu, J. Environ. Chem. Eng. 10, 107167 (2022). https://doi.org/10.1016/j.jece.2022.107167

    Article  CAS  Google Scholar 

  14. J. Yang, Z.F. Li, C.L. Yang, Y.Y. Ma, Y.Y. Li, Q. Zhang, K. Song, J.X. Cui, J. Solid State Chem. 305, 122700 (2022). https://doi.org/10.1016/j.jssc.2021.122700

    Article  CAS  Google Scholar 

  15. B. Dou, G. Lv, C. Wang, Q. Hao, K. Hui, Chem. Eng. J. 270, 549 (2015). https://doi.org/10.1016/j.cej.2015.02.004

    Article  CAS  Google Scholar 

  16. C. Niu, X.Y. Shi, K. Liu, Y. You, S.X. Wang, H. He, Catal. Commun. 81, 20 (2016). https://doi.org/10.1016/j.catcom.2016.04.007

    Article  CAS  Google Scholar 

  17. Y. Wang, Z.Q. Li, Z.Y. Ding, N. Kang, R.R. Fan, Y. Wang, C. Zhang, X. Guo, R. Wang, Catalysts 11, 997 (2021). https://doi.org/10.3390/catal11080997

    Article  CAS  Google Scholar 

  18. A.D. Fan, Y. Jing, J.X. Guo, X.K. Shi, S.D. Yuan, J.J. Li, Fuel 310, 122237 (2022). https://doi.org/10.1016/j.fuel.2021.122237

    Article  CAS  Google Scholar 

  19. J. Fan, P. Ning, Y.C. Wang, Z.X. Song, X. Liu, H.M. Wang, J. Wang, L.Y. Wang, Q.L. Zhang, Chem. Eng. J. 369, 908 (2019). https://doi.org/10.1016/j.cej.2019.03.049

    Article  CAS  Google Scholar 

  20. L. Zhang, H.X. Qu, T.Y. Du, W.H. Ma, Q. Zhong, Chem. Eng. J. 296, 122 (2016). https://doi.org/10.1016/j.cej.2016.03.109

    Article  CAS  Google Scholar 

  21. G.L. Mu, S. Liu, Q.J. Liu, S.S. Liu, X.T. Zhang, ACS Omega 42, 37694 (2022). https://doi.org/10.1021/acsomega.2c04603

    Article  CAS  Google Scholar 

  22. J. Yang, Z. Li, J. Cui, Y. Ma, Y. Li, Q. Zhang, K. Song, C. Yang, J. Rare Earths (2022). https://doi.org/10.1016/j.jre

    Article  Google Scholar 

  23. S. Ji, Z.F. Li, K. Song, H.R. Li, Y.Y. Li, J. Yang, M.J. Li, C.L. Yang, New J. Chem. 45, 3857 (2021). https://doi.org/10.1039/d0nj05404f

    Article  CAS  Google Scholar 

  24. H.Y. Xue, X.M. Guo, T. Meng, Q.S. Guo, D.S. Mao, S. Wang, ACS Catal. 11, 7702 (2021). https://doi.org/10.1021/acscatal.1c01172

    Article  CAS  Google Scholar 

  25. A. Corma, J. Martinez-Triguero, S. Valencia, E. Benazzi, S. Lacombe, J. Catal. 206, 125 (2002). https://doi.org/10.1006/jcat.2001.3469

    Article  CAS  Google Scholar 

  26. X.R. Lou, P.F. Liu, J. Li, Z. Li, K. He, Appl. Surf. Sci. 307, 382 (2014). https://doi.org/10.1016/j.apsusc.2014.04.041

    Article  CAS  Google Scholar 

  27. A.E. Palomares, J.G. Prato, A. Corma, Ind. Eng. Chem. Res. 42, 1538 (2003). https://doi.org/10.1021/ie020345l

    Article  CAS  Google Scholar 

  28. E. Benazzi, WO98/17581, 1998-4-30

  29. A.E. Palomares, F. Marquez, S. Valencia, A. Corma, J. Mol. Catal. A Chem. 162, 175 (2000). https://doi.org/10.1016/s1381-1169(00)00288-0

    Article  CAS  Google Scholar 

  30. D. Deng, S.J. Deng, D.D. He, Z.H. Wang, Z.P. Chen, Y. Ji, G.P. Yan, G.J. Hou, L.C. Liu, H. He, J. Rare Earths 39, 969 (2021). https://doi.org/10.1016/j.jre.2020.08.016

    Article  CAS  Google Scholar 

  31. X.X. Wang, Y. Shi, S.J. Li, W. Li, Appl. Catal. B 220, 234 (2018). https://doi.org/10.1016/j.apcatb.2017.08.021

    Article  CAS  Google Scholar 

  32. C.J. Tang, H.L. Zhang, L. Dong, Catal. Sci. Technol. 6, 1248 (2016). https://doi.org/10.1039/c5cy01487e

    Article  CAS  Google Scholar 

  33. L. Lietti, J.L. Alemany, P. Forzatti, G. Busca, G. Ramis, E. Giamello, F. Bregani, Catal. Today 29, 143–148 (1996). https://doi.org/10.1016/0920-5861(95)00250-2

    Article  CAS  Google Scholar 

  34. Z.Q. Chen, L. Liu, H.X. Qu, B.J. Zhou, H.F. Xie, Q. Zhong, J. Catal. 392, 217 (2020). https://doi.org/10.1016/j.jcat.2020.10.005

    Article  CAS  Google Scholar 

  35. Q.L. Zhang, L.S. Xu, P. Ning, J.J. Gu, Q.Q. Guan, Appl. Surf. Sci. 317, 955 (2014). https://doi.org/10.1016/j.apsusc.2014.09.017

    Article  CAS  Google Scholar 

  36. Y.Y. Li, Z.P. Zhang, X.Y. Zhao, Z. Liu, T.R. Zhang, X.Y. Niu, Y.J. Zhu, Fuel 331, 125799 (2023). https://doi.org/10.1016/j.fuel.2022.125799

    Article  CAS  Google Scholar 

  37. J. Liu, J. Meeprasert, S. Namuangruk, K.W. Zha, H.R. Li, L. Huang, P. Maitarad, L.Y. Shi, D.S. Zhang, J. Phys. Chem. C 121, 4970 (2017). https://doi.org/10.1021/acs.jpcc.6b11175

    Article  CAS  Google Scholar 

  38. X.S. Liu, X.D. Wu, D. Weng, Z.C. Si, R. Ran, Catal. Today 281, 596 (2017). https://doi.org/10.1016/j.cattod.2016.05.021

    Article  CAS  Google Scholar 

  39. L. Wang, J.R. Gaudet, W. Li, D. Weng, J. Catal. 306, 68 (2013). https://doi.org/10.1016/j.jcat.2013.06.010

    Article  CAS  Google Scholar 

  40. J.W. Shi, Y. Wang, R.B. Duan, C. Gao, B.R. Wang, C. He, C.M. Niu, Catal. Sci. Technol. 9, 718 (2019). https://doi.org/10.1039/c8cy01949e

    Article  CAS  Google Scholar 

  41. J. Deshetti, D. Devaiah, C. Anastasios, V. Perala, B.K. Suresh, R.M. Benjaram, Catal. Today 356, 519 (2020). https://doi.org/10.1016/j.cattod.2020.05.047

    Article  CAS  Google Scholar 

  42. X.K. Shi, J.X. Guo, T. Shen, A.D. Fan, S.D. Yuan, J.J. Li, Chem. Eng. J. 421, 129995 (2021). https://doi.org/10.1016/j.cej.2021.129995

    Article  CAS  Google Scholar 

  43. C.R. Moreira, N. Homs, J.L.G. Fierro, M.M. Pereira, P.R. De La Piscina, Microporous Mesoporous Mater. 133, 75 (2010). https://doi.org/10.1016/j.micromeso.2010.04.017

    Article  CAS  Google Scholar 

  44. T.K. Liu, J.N. Qian, Y.Y. Yao, Z.F. Shi, L.Y. Han, C.Y. Liang, B. Li, L.H. Dong, M.G. Fan, L.L. Zhang, Mol. Catal. 430, 43 (2017). https://doi.org/10.1016/j.molcata.2016.12.009

    Article  CAS  Google Scholar 

  45. L.J. Jiang, Q.C. Liu, G.J. Ran, M. Kong, S. Ren, J. Yang, J.L. Li, Chem. Eng. J. 370, 810 (2019). https://doi.org/10.1016/j.cej.2019.03.225

    Article  CAS  Google Scholar 

Download references

Acknowledgements

This work was supported by Natural Science Foundation of Heilongjiang Province (LH2022E117) and University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province (UNPYSCT-2020069).

Funding

We would like to express our gratitude to Natural Science Foundation of Heilongjiang Province (LH2022E117) and University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province (UNPYSCT-2020069).

Author information

Authors and Affiliations

  1. College of Materials Science and Engineering, Qiqihar University, Wenhua Street 42, Qiqihar, 161006, China

    Qian Zhang, Zhifang Li, Jinxing Cui, Miao Yu, Jiao Zhao & Changlong Yang

  2. Heilongjiang Province Key Laboratory of Polymeric Composite Material, Qiqihar University, Wenhua Street 42, Qiqihar, 161006, China

    Zhifang Li, Jinxing Cui & Changlong Yang

  3. College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar, 161006, China

    Yuanyuan Ma

Authors
  1. Qian Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhifang Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jinxing Cui
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yuanyuan Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Miao Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Jiao Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Changlong Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

Conceptualization: QZ, ZL, JC, CY; Material preparation, data collection and analysis: QZ, ZL, JC, YM, MY, JZ, CY; Writing-original draft: QZ, ZL, JC, CY; Writing-review & editing: QZ, ZL, JC, YM, MY, JZ, CY. All authors read and approved the final manuscript.

Corresponding authors

Correspondence to Zhifang Li or Changlong Yang.

Ethics declarations

Conflict of interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Ethical approval

The authors declare that there are no both human and/ or animal studies in this paper.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zhang, Q., Li, Z., Cui, J. et al. Efficiency of temperature on Ce and La doping Cu modified IM-5 catalyst in DeNOx performance and SO2/H2O resistance. Res Chem Intermed 49, 4997–5013 (2023). https://doi.org/10.1007/s11164-023-05127-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11164-023-05127-y

Keywords

Search

Navigation