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A new Hg2+ colorimetric chemosensor: the synthesis of chromeno[d]pyrimidine-2,5-dione/thione derivatives using Fe3O4@SiO2@(BuSO3H)3

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Abstract

The synthesis of chromeno[d]pyrimidine-2,5-dione/thione derivatives has been described by the reaction of aryl aldehydes, urea/thiourea, and 4-hydroxycoumarin using Fe3O4@SiO2@(BuSO3H)3 as catalyst under microwave irradiation (MWI) in H2O. The sensing application of 4-(4-chlorophenyl)-3,4-dihydro-1H-chromeno[4,3-d]pyrimidine-2,5-dione 4b was examined upon addition of different cations by UV–Vis spectroscopy and exhibited excellent sensitivity towards Hg2+ ions by increasing the absorption. The UV–visible absorption spectral data showed good linearity between the UV–Vis absorption of chemosensor 4b and the concentration of Hg2+ with a detection limit of 3.76 × 10–7 M. Furthermore, the chemosensor 4b exhibited an obvious color change from white to light pink in the presence of Hg2+ in EtOH solution.

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Acknowledgements

We gratefully acknowledge the Research Council of Alzahra University’s support.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Physics and Chemistry, Alzahra University, P.O. Box 1993893973, Tehran, Iran

    Negar Jamasbi, Ghodsi Mohammadi Ziarani & Fatemeh Mohajer

  2. School of Chemistry, College of Science, University of Tehran, Tehran, Iran

    Alireza Badiei

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  1. Negar Jamasbi
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  2. Ghodsi Mohammadi Ziarani
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  3. Fatemeh Mohajer
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  4. Alireza Badiei
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Jamasbi, N., Mohammadi Ziarani, G., Mohajer, F. et al. A new Hg2+ colorimetric chemosensor: the synthesis of chromeno[d]pyrimidine-2,5-dione/thione derivatives using Fe3O4@SiO2@(BuSO3H)3. Res Chem Intermed 48, 899–909 (2022). https://doi.org/10.1007/s11164-021-04611-7

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