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Ionic liquid supported on magnetic nanoparticles as a novel reusable nanocatalyst for the efficient synthesis of tetracyclic quinazoline compounds

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Abstract

A magnetic ionic liquid supported on γ-Fe2O3 nanocatalyst was synthesized successfully and characterized by Fourier transform infrared spectroscopy, vibrating sample magnetometry, thermogravimetric analysis, differential scanning calorimetry, X-ray diffraction and scanning electron microscopy. The resulting nano-Fe3O4-supported, ionic liquid was an efficient catalyst for preparation of a series of tetracyclic quinazoline compounds by three components reaction of a mixture of isatoic anhydride and amine with ninhydrin in PEG and the desired products were obtained in good to excellent yields. High efficiency, waste-free, mild reaction conditions, effortless magnetic recovery and reusability up to four continuous cycles are the noteworthy features of the currently employed heterogeneous catalytic system.

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Acknowledgements

The authors would like to thank the research facilities of Ilam University, Ilam, Iran, for the financial support of this research project.

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Authors and Affiliations

  1. Ilam University, Ilam, Islamic Republic of Iran

    Arash Ghorbani-Choghamarani, Zahra Taherinia & Mohsen Nikoorazm

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  1. Arash Ghorbani-Choghamarani
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  2. Zahra Taherinia
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  3. Mohsen Nikoorazm
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Corresponding author

Correspondence to Arash Ghorbani-Choghamarani.

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Ghorbani-Choghamarani, A., Taherinia, Z. & Nikoorazm, M. Ionic liquid supported on magnetic nanoparticles as a novel reusable nanocatalyst for the efficient synthesis of tetracyclic quinazoline compounds. Res Chem Intermed 44, 6591–6604 (2018). https://doi.org/10.1007/s11164-018-3510-1

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